Cited by 593biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisAdvanced Polymer Synthesis and Characterization

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

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Paul, Shyeni, Zhu, Yunqing, Romain, Charles, Brooks, Rachel, Saini, Prabhjot K., Williams, Charlotte K.·2015·Chemical Communications

Abstract

This feature article highlights the opportunities presented by ring-opening copolymerization (ROCOP) as a controlled route to prepare polyesters and polycarbonates.

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Crossref · 10.1039/c4cc10113h

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  • While the field of epoxide/CO2 copolymerization is quite mature, with several technologies commercialized, the progress in epoxide/cyclic anhydride copolymerization is more recent.

    “While the field of epoxide/CO2 copolymerization is quite mature, with several technologies been commercialized, the progress in epoxide/cyclic anhydride copolymerization is more recent.211,343”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [343]

  • Because of the mechanistic similarities between epoxide/CO2 copolymerization and epoxide/cyclic anhydride copolymerization, the two can be mediated by a similar array of catalysts.

    “Because of the mechanistic similarities between epoxide/CO2 copolymerization and epoxide/cyclic anhydride copolymerization, the two can be mediated by a similar array of catalysts.343”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [343]

  • The development of single-site metal complexes with ancillary ligands has largely boosted the understanding and the scope of ROCP.

    “The development of single-site metal complexes with ancillary ligands has largely boosted the understanding and the scope of ROCP.343”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [343]

  • In most cases, a nucleophilic cocatalyst is used to increase the activity of the metal complexes, the most common ones being bis(triphenylphosphine) iminium salts and 4-dimethylaminopyridine.

    “In most cases, a nucleophilic cocatalyst is used to increase the activity of the metal complexes, the most common ones being bis(triphenylphosphine) iminium salts ([PPN]X) and 4-dimethylaminopyridine (DMAP).”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [343]

  • Terpolymerization of epoxide, cyclic anhydride, and CO2 is a facile strategy for the one-pot synthesis of poly(ester-carbonate), a class of biodegradable polymers that have garnered considerable interest due to their possible superior properties than pure polyesters and polycarbonates.

    “Terpolymerization of epoxide, cyclic anhydride, and CO2 is a facile strategy for the onepot synthesis of poly(ester-carbonate), 211,343 a class of biodegradable polymers that have garnered considerable interest due to their possible superior properties than pure polyesters and polycarbonates.”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [343]

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200 of 234 shown

Cited by

Sorted by citations

Authors
Paul, S., Zhu, Y., Romain, C., Brooks, R., Saini, P. K., & Williams, C. K.
Affiliations
Imperial College London (GB)
Corresponding author
Williams, Charlotte K.
Venue
Chemical Communications
Published
2015
Volume
51
Issue
30
Pages
6459-6479
ISSN
  • 1359-7345 (ISSN-L)
  • 1364-548X
OpenAlex
W2163986861
Cited by
593
References
240
Citations by year
2026: 32 · 2025: 39 · 2024: 56 · 2023: 55 · 2022: 63 · 2021: 66 · 2020: 63 · 2019: 49 · 2018: 67 · 2017: 49 · 2016: 32 · 2015: 22
FWCI
20.45
Type
journal article
Language
en
Open access
Licence
cc-by
Locations
  • Chemical Communications (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • Spiral (Imperial College London) (submittedVersion)
Funders
Engineering and Physical Sciences Research Council (EP/K014070/1, EP/K035274/1, EP/L017393/1)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
ring-opening copolymerization, polyesters, polycarbonate, CO2 utilization, homogeneous catalysts, polymer properties

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