The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Efficient Light-Driven Carbon-Free Cobalt-Based Molecular Catalyst for Water Oxidation
Abstract
The abundant-metal-based polyoxometalate complex [Co(4)(H(2)O)(2)(PW(9)O(34))(2)](10-) is a hydrolytically and oxidatively stable, homogeneous, and efficient molecular catalyst for the visible-light-driven catalytic oxidation of water. Using a sacrificial electron acceptor and photosensitizer, it exhibits a high (30%) photon-to-O(2) yield and a large turnover number (>220, limited solely by depletion of the sacrificial electron acceptor) at pH 8. The photocatalytic performance of this catalyst is superior to that of the previously reported precious-metal-based polyoxometalate water oxidation catalyst [{Ru(4)O(4)(OH)(2)(H(2)O)(4)}(γ-SiW(10)O(36))(2)](10-).
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Citations
Cites
Photosynthetic energy conversion: natural and artificial
Barber, J. (2009) · Chem. Soc. Rev. · doi:10.1039/b802262n · Cited by 1,843
Cited by
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
Polyoxometalate-Based Cobalt–Phosphate Molecular Catalysts for Visible Light-Driven Water Oxidation
Han, X.-B., Zhang, Z.-M., Zhang, T., Li, Y.-G., Lin, W., You, W., Su, Z.-M., & Wang, E.-B. (2014) · Journal of the American Chemical Society · doi:10.1021/ja412886e · Cited by 462
Leung, C.-F., Ng, S.-M., Ko, C.-C., Man, W.-L., Wu, J., Chen, L., & Lau, T.-C. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21840b · Cited by 206
Metadata
- Authors
- Huang, Z., Luo, Z., Geletii, Y. V., Vickers, J. W., Yin, Q., Wu, D., Hou, Y., Ding, Y., Song, J., Musaev, D. G., Hill, C. L., & Lian, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-01-26
- Volume
- 133
- Issue
- 7
- Pages
- 2068-2071
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2335373815
- Cited by
- 358
- References
- 1
- FWCI
- 22.46
- Type
- journal article
- Language
- en
- Open access
- closed
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