The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Efficient Light-Driven Carbon-Free Cobalt-Based Molecular Catalyst for Water Oxidation
Abstract
The abundant-metal-based polyoxometalate complex [Co(4)(H(2)O)(2)(PW(9)O(34))(2)](10-) is a hydrolytically and oxidatively stable, homogeneous, and efficient molecular catalyst for the visible-light-driven catalytic oxidation of water. Using a sacrificial electron acceptor and photosensitizer, it exhibits a high (30%) photon-to-O(2) yield and a large turnover number (>220, limited solely by depletion of the sacrificial electron acceptor) at pH 8. The photocatalytic performance of this catalyst is superior to that of the previously reported precious-metal-based polyoxometalate water oxidation catalyst [{Ru(4)O(4)(OH)(2)(H(2)O)(4)}(γ-SiW(10)O(36))(2)](10-).
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Citations
Cites
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Cited by
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
Recent advances on polyoxometalate-based molecular and composite materials
Song, Y.-F., & Tsunashima, R. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35143a · Cited by 909
Efficient water oxidation catalysts based on readily available iron coordination complexes
Fillol, J. L., Codolà, Z., Garcia-Bosch, I., Gómez, L., Pla, J. J., & Costas, M. (2011) · Nature Chemistry · doi:10.1038/nchem.1140 · Cited by 784
Polyoxometalate-Based Cobalt–Phosphate Molecular Catalysts for Visible Light-Driven Water Oxidation
Han, X.-B., Zhang, Z.-M., Zhang, T., Li, Y.-G., Lin, W., You, W., Su, Z.-M., & Wang, E.-B. (2014) · Journal of the American Chemical Society · doi:10.1021/ja412886e · Cited by 462
Heterogeneous Molecular Systems for Photocatalytic CO2 Reduction with Water Oxidation
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Water oxidation catalysts based on abundant 1st row transition metals
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Light-driven water oxidation for solar fuels
Young, K. J., Martini, L. A., Milot, R. L., Snoeberger, R. C., Batista, V. S., Schmuttenmaer, C. A., Crabtree, R. H., & Brudvig, G. W. (2012) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.03.031 · Cited by 364
Tetrametallic molecular catalysts for photochemical water oxidation
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Self-citationLei, J., Fan, X.-X., Liu, T., Xu, P., Hou, Q., Li, K., Yuan, R.-M., Zheng, M.-S., Dong, Q.-F., & Chen, J.-J. (2022) · Nature Communications · doi:10.1038/s41467-021-27866-5 · Cited by 308
An Exceptionally Fast Homogeneous Carbon-Free Cobalt-Based Water Oxidation Catalyst
Lv, H., Song, J., Geletii, Y. V., Vickers, J. W., Sumliner, J. M., Musaev, D. G., Kögerler, P., Zhuk, P. F., Bacsa, J., Zhu, G., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5045488 · Cited by 288
Self-citationWater oxidation using earth-abundant transition metal catalysts: opportunities and challenges
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Metadata
- Authors
- Huang, Z., Luo, Z., Geletii, Y. V., Vickers, J. W., Yin, Q., Wu, D., Hou, Y., Ding, Y., Song, J., Musaev, D. G., Hill, C. L., & Lian, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-01-26
- Volume
- 133
- Issue
- 7
- Pages
- 2068-2071
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2335373815
- Cited by
- 358
- References
- 1
- FWCI
- 22.46
- Type
- journal article
- Language
- en
- Open access
- closed
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