The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
Fast Characterization of Functionalized Silica Materials by Silicon-29 Surface-Enhanced NMR Spectroscopy Using Dynamic Nuclear Polarization
Open accessAbstract
We demonstrate fast characterization of the distribution of surface bonding modes and interactions in a series of functionalized materials via surface-enhanced nuclear magnetic resonance spectroscopy using dynamic nuclear polarization (DNP). Surface-enhanced silicon-29 DNP NMR spectra were obtained by using incipient wetness impregnation of the sample with a solution containing a polarizing radical (TOTAPOL). We identify and compare the bonding topology of functional groups in materials obtained via a sol-gel process and in materials prepared by post-grafting reactions. Furthermore, the remarkable gain in time provided by surface-enhanced silicon-29 DNP NMR spectroscopy (typically on the order of a factor 400) allows the facile acquisition of two-dimensional correlation spectra.
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Cites
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Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization
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Cited by
Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
Lilly Thankamony, A. S., Wittmann, J. J., Kaushik, M., & Corzilius, B. (2017) · Progress in Nuclear Magnetic Resonance Spectroscopy · doi:10.1016/j.pnmrs.2017.06.002 · Cited by 544
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The Comparison between Single Atom Catalysis and Surface Organometallic Catalysis
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Metadata
- Authors
- Lelli, M., Gajan, D., Lesage, A., Caporini, M. A., Vitzthum, V., Miéville, P., Héroguel, F., Rascón, F., Roussey, A., Thieuleux, C., Boualleg, M., Veyre, L., Bodenhausen, G., Coperet, C., & Emsley, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-01-31
- Volume
- 133
- Issue
- 7
- Pages
- 2104-2107
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1978812280
- Cited by
- 290
- References
- 19
- FWCI
- 12.99
- Type
- journal article
- Language
- en
- Open access
- green
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- Lelli, M., Gajan, D., Lesage, A., Caporini, M. A., Vitzthum, V., Miéville, P., Héroguel, F., Rascón, F., Roussey, A., Thieuleux, C., Boualleg, M., Veyre, L., Bodenhausen, G., Coperet, C., & Emsley, L. (2011). Fast Characterization of Functionalized Silica Materials by Silicon-29 Surface-Enhanced NMR Spectroscopy Using Dynamic Nuclear Polarization. Journal of the American Chemical Society. https://doi.org/10.1021/ja110791d
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