The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Amine-Assisted Synthesis of Concave Polyhedral Platinum Nanocrystals Having {411} High-Index Facets
Abstract
High-index surfaces of a face-centered cubic metal (e.g., Pd, Pt) have a high density of low-coordinated surface atoms and therefore possess enhanced catalysis activity in comparison with low-index faces. However, because of their high surface energy, the challenge of chemically preparing metal nanocrystals having high-index facets remains. We demonstrate in this work that introducing amines as the surface controller allows concave Pt nanocrystals having {411} high-index facets to be prepared through a facile wet-chemical route. The as-prepared Pt nanocrystals display a unique octapod morphology with {411} facets. The presence of high-index {411} exposed facets endows the concave Pt nanocrystals with excellent electrocatalytic activity in the oxidation of both formic acid and ethanol.
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Cites
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
Nanostructures in Biodiagnostics
Rosi, N. L., & Mirkin, C. A. (2005) · Chemical Reviews · doi:10.1021/cr030067f · Cited by 4,603
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Freestanding palladium nanosheets with plasmonic and catalytic properties
Huang, X., Tang, S., Mu, X., Dai, Y., Chen, G., Zhou, Z., Ruan, F., Yang, Z., & Zheng, N. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2010.235 · Cited by 1,602
Self-citationWang, C., Daimon, H., Onodera, T., Koda, T., & Sun, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200800073 · Cited by 849
Mechanism of catalysis of hydrocarbon reactions by platinum surfaces
Somorjai, G. A., & Blakely, D. W. (1975) · Nature · doi:10.1038/258580a0 · Cited by 357
Controlled Formation of Concave Tetrahedral/Trigonal Bipyramidal Palladium Nanocrystals
Huang, X., Tang, S., Zhang, H., Zhou, Z., & Zheng, N. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9059409 · Cited by 242
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Cited by
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156
High-Index Faceted Noble Metal Nanocrystals
Quan, Z., Wang, Y., & Fang, J. (2013) · Accounts of Chemical Research · doi:10.1021/ar200293n · Cited by 582
Li, Y., Li, Y., Zhu, E., McLouth, T., Chiu, C.-Y., Huang, X., & Huang, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3031449 · Cited by 490
Self-citationSmall Adsorbate‐Assisted Shape Control of Pd and Pt Nanocrystals
Chen, M., Wu, B., Yang, J., & Zheng, N. (2012) · Advanced Materials · doi:10.1002/adma.201104145 · Cited by 441
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Metadata
- Authors
- Huang, X., Zhao, Z., Fan, J., Tan, Y., & Zheng, N.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-15
- Volume
- 133
- Issue
- 13
- Pages
- 4718-4721
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974697112
- Cited by
- 516
- References
- 7
- FWCI
- 23.25
- Type
- journal article
- Language
- en
- Open access
- closed
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