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Efficient Visible-Light Photocatalytic Water Splitting by Minute Amounts of Gold Supported on Nanoparticulate CeO2 Obtained by a Biopolymer Templating Method
Open accessAbstract
When irradiated with visible light (λ > 400 nm) 1 wt % gold-supported ceria nanoparticles generate oxygen from water (10.5 μmol·h(-1)) more efficiently than the standard WO(3) (1.7 μmol·h(-1)) even under UV irradiation (9.5 μmol·h(-1)). This remarkable photocatalytic activity arises from a novel preparation method to reduce the particle size of ceria (5 nm) by means of electrostatic binding of Ce(4+) to alginate gel, subsequent supercritical CO(2) drying, and calcination. The low loading of Au is crucial for the observed high catalytic activity.
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Citations
Cites
Supported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
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Cited by
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy
Linic, S., Christopher, P., & Ingram, D. B. (2011) · Nature Materials · doi:10.1038/nmat3151 · Cited by 4,852
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
Clavero, C. (2014) · Nature Photonics · doi:10.1038/nphoton.2013.238 · Cited by 2,762
Li, C., Li, Q., Kaneti, Y. V., Hou, D., Yamauchi, Y., & Mai, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00021c · Cited by 513
Photocatalytic reduction of CO2 for fuel production: Possibilities and challenges
Corma, A., & Garcia, H. (2013) · Journal of Catalysis · doi:10.1016/j.jcat.2013.06.008 · Cited by 377
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Metadata
- Authors
- Primo, A., Marino, T., Corma, A., Molinari, R., & García, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-20
- Volume
- 133
- Issue
- 18
- Pages
- 6930-6933
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2034054062
- Cited by
- 453
- References
- 1
- FWCI
- 17.60
- Type
- journal article
- Language
- en
- Open access
- green
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- Primo, A., Marino, T., Corma, A., Molinari, R., & García, H. (2011). Efficient Visible-Light Photocatalytic Water Splitting by Minute Amounts of Gold Supported on Nanoparticulate CeO2 Obtained by a Biopolymer Templating Method. Journal of the American Chemical Society. https://doi.org/10.1021/ja2011498
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