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Tuning the Relative Concentration Ratio of Bulk Defects to Surface Defects in TiO2 Nanocrystals Leads to High Photocatalytic Efficiency

Kong, Ming, Li, Yuanzhi, Chen, Xiong, Tian, Tingting, Fang, Pengfei, Zheng, Feng, Zhao, Xiujian·2011·Journal of the American Chemical Society

Abstract

TiO(2) nanocrystals with tunable bulk/surface defects were synthesized and characterized with TEM, XRD, BET, positron annihilation, and photocurrent measurements. The effect of defects on photocatalytic activity was studied. It was found for the first time that decreasing the relative concentration ratio of bulk defects to surface defects in TiO(2) nanocrystals could significantly improve the separation efficiency of photogenerated electrons and holes, thus significantly enhancing the photocatalytic efficiency.

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Metadata

Authors
Kong, M., Li, Y., Chen, X., Tian, T., Fang, P., Zheng, F., & Zhao, X.
Venue
Journal of the American Chemical Society
Published
2011-09-22
Volume
133
Issue
41
Pages
16414-16417
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2334650844
Cited by
1,111
References
2
FWCI
18.91
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Tuning the Relative Concentration Ratio of Bulk Defects to Surface Defects in TiO2 Nanocrystals Leads to High Photocatalytic Efficiency. https://app.cochat.ai/papers/10.1021/ja207826q
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Kong, M., Li, Y., Chen, X., Tian, T., Fang, P., Zheng, F., & Zhao, X. (2011). Tuning the Relative Concentration Ratio of Bulk Defects to Surface Defects in TiO2 Nanocrystals Leads to High Photocatalytic Efficiency. Journal of the American Chemical Society. https://doi.org/10.1021/ja207826q

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