The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
High-Nuclearity 3d–4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets
Abstract
Four 52-metal-ion 3d-4f cluster complexes featuring a common core of Ln(42)M(10) (Ln = Gd(3+), Dy(3+); M = Co(2+/3+), Ni(2+)) were obtained through self-assembly of the metal ions templated by mixed anions (ClO(4)(-) and CO(3)(2-)). Magnetic studies revealed that the Gd(42)Co(10) and Gd(42)Ni(10) clusters exhibit the largest magnetocaloric effect (MCE) among any known 3d-4f complexes. Replacement of Gd(3+) ions with anisotropic Dy(3+) ions caused significant changes in the magnetic behavior of the clusters; both Dy(42)Co(10) and Dy(42)Ni(10) displayed slow relaxation of the magnetization.
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Cites
Magnetic bistability in a metal-ion cluster
Sessoli, R., Gatteschi, D., Caneschi, A., & Novak, M. A. (1993) · Nature · doi:10.1038/365141a0 · Cited by 4,307
Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials
Gatteschi, D., & Sessoli, R. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200390099 · Cited by 2,808
Strategies towards single molecule magnets based on lanthanide ions
Sessoli, R., & Powell, A. K. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2008.12.014 · Cited by 1,502
Liu, W., & Thorp, H. H. (1993) · Inorganic Chemistry · doi:10.1021/ic00071a023 · Cited by 792
Recipes for enhanced molecular cooling
Evangelisti, M., & Brechin, E. K. (2010) · Dalton Transactions · doi:10.1039/b926030g · Cited by 463
Co–Ln Mixed-Metal Phosphonate Grids and Cages as Molecular Magnetic Refrigerants
Zheng, Y.-Z., Evangelisti, M., Tuna, F., & Winpenny, R. E. P. (2012) · Journal of the American Chemical Society · doi:10.1021/ja208367k · Cited by 380
Self-citationMagnetothermal properties of molecule-based materials
Evangelisti, M., Luis, F., de Jongh, L. J., & Affronte, M. (2006) · Journal of Materials Chemistry · doi:10.1039/b603738k · Cited by 315
Cryogenic Magnetocaloric Effect in a Ferromagnetic Molecular Dimer
Evangelisti, M., Roubeau, O., Palacios, E., Camón, A., Hooper, T. N., Brechin, E. K., & Alonso, J. J. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102640 · Cited by 315
Large Magnetocaloric Effect in a Wells–Dawson Type {Ni6Gd6P6} Cage
Zheng, Y., Evangelisti, M., & Winpenny, R. E. P. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201008074 · Cited by 299
Self-citationCo–Gd phosphonate complexes as magnetic refrigerants
Zheng, Y.-Z., Evangelisti, M., & Winpenny, R. E. P. (2011) · Chem. Sci. · doi:10.1039/c0sc00371a · Cited by 248
Self-citationMixed-Valent Mn Supertetrahedra and Planar Discs as Enhanced Magnetic Coolers
Manoli, M., Collins, A., Parsons, S., Candini, A., Evangelisti, M., & Brechin, E. K. (2008) · Journal of the American Chemical Society · doi:10.1021/ja802829d · Cited by 234
CO2 Fixation by Copper(II) Complexes of a Terpyridinophane Aza Receptor
García‐España, E., Gaviña, P., Latorre, J., Soriano, C., & Verdejo, B. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039577h · Cited by 97
Cited by
Molecule-based magnetic coolers
Zheng, Y.-Z., Zhou, G.-J., Zheng, Z., & Winpenny, R. E. P. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60337g · Cited by 578
Self-citationMachine learning guided design of single-molecule magnets for magnetocaloric applications
Holleis, L., Shivaram, B. S., & Balachandran, P. V. (2019) · Applied Physics Letters · doi:10.1063/1.5094553 · Cited by 29
Metadata
- Authors
- Peng, J.-B., Zhang, Q.-C., Kong, X.-J., Zheng, Y.-Z., Ren, Y.-P., Long, L.-S., Huang, R.-B., Zheng, L.-S., & Zheng, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-02-09
- Volume
- 134
- Issue
- 7
- Pages
- 3314-3317
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2319257958
- Cited by
- 469
- References
- 12
- FWCI
- 17.85
- Type
- journal article
- Language
- en
- Open access
- closed
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