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Cited by 158

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters

Open access
Bonanni, Simon, Aït-Mansour, Kamel, Harbich, Wolfgang, Brune, Harald·2012·Journal of the American Chemical Society

Abstract

The catalytic activity of deposited Pt(7) clusters has been studied as a function of the reduction state of the TiO(2)(110)-(1 × 1) support for the CO oxidation reaction. While a slightly reduced support gives rise to a high catalytic activity of the adparticles, a strongly reduced one quenches the CO oxidation. This quenching is due to thermally activated diffusion of Ti(3+) interstitials from the bulk to the surface where they deplete the oxygen adsorbed onto the clusters by the formation of TiO(x) (x ≃ 2) structures. This reaction is more rapid than the CO oxidation. The present results are of general relevance to heterogeneous catalysis on TiO(2)-supported metal clusters and for reactions involving oxygen as intermediate.

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Metadata

Authors
Bonanni, S., Aït-Mansour, K., Harbich, W., & Brune, H.
Venue
Journal of the American Chemical Society
Published
2012-02-02
Volume
134
Issue
7
Pages
3445-3450
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2003496331
Cited by
158
References
3
FWCI
7.67
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters. https://app.cochat.ai/papers/10.1021/ja2098854
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Bonanni, S., Aït-Mansour, K., Harbich, W., & Brune, H. (2012). Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters. Journal of the American Chemical Society. https://doi.org/10.1021/ja2098854

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.