The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Enhanced Stability of Cu-BTC MOF via Perfluorohexane Plasma-Enhanced Chemical Vapor Deposition
Abstract
Metal organic frameworks (MOFs) are a leading class of porous materials for a wide variety of applications, but many of them have been shown to be unstable toward water. Cu-BTC (1,3,5 benzenetricarboxylic acid, BTC) was treated with a plasma-enhanced chemical vapor deposition (PECVD) of perfluorohexane creating a hydrophobic form of Cu-BTC. It was found that the treated Cu-BTC could withstand high humidity and even submersion in water much better than unperturbed Cu-BTC. Through Monte Carlo simulations it was found that perfluorohexane sites itself in such a way within Cu-BTC as to prevent the formation of water clusters, hence preventing the decomposition of Cu-BTC by water. This PECVD of perfluorohexane could be exploited to widen the scope of practical applications of Cu-BTC and other MOFs.
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Citations
Cites
Metal-organic frameworks with high capacity and selectivity for harmful gases
Britt, D., Tranchemontagne, D., & Yaghi, O. M. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0804900105 · Cited by 958
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Competitive I2 Sorption by Cu-BTC from Humid Gas Streams
Sava, D. F., Chapman, K. W., Rodriguez, M. A., Greathouse, J. A., Crozier, P. S., Zhao, H., Chupas, P. J., & Nenoff, T. M. (2013) · Chemistry of Materials · doi:10.1021/cm401762g · Cited by 363
Deng, X., Li, R., Wu, S., Wang, L., Hu, J., Ma, J., Jiang, W., Zhang, N., Zheng, X., Gao, C., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b06239 · Cited by 322
Liao, Y.-T., Nguyen, V. C., Ishiguro, N., Young, A. P., Tsung, C.-K., & Wu, K. C.-W. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.118805 · Cited by 281
Metadata
- Authors
- Decoste, J. B., Peterson, G. W., Smith, M. W., Stone, C. A., & Willis, C. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-01-13
- Volume
- 134
- Issue
- 3
- Pages
- 1486-1489
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2321100100
- Cited by
- 273
- References
- 1
- FWCI
- 10.49
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
