The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
Engineering a homogeneous alloy-oxide interface derived from metal-organic frameworks for selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
Abstract
Abstract The selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) is an important biomass conversion reaction. However, the multiple intermediates of the reaction make the catalyst design challenging. We engineered an active and selective catalyst with an active interface between Au-Pd alloy nanoparticles (NPs) and cobalt oxide supports via calcination of a composite of NPs encapsulated in metal-organic frameworks (MOFs). The catalyst shows an effective HMF-to-FDCA oxidation with total conversion and 95 % yield by 10 % hydrogen peroxide solution at 90 °C in one hour under atmospheric pressure. The mechanistic study shows that the engineered interface promotes the formation of hydroperoxyl radicals and dioxygen molecules, which accelerate the oxidation of reactive intermediates to FDCA. This work demonstrates the advantage of using MOF composites as a precursor to generate complex but active interfaces with a strong interaction between the metal and metal oxides.
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Cites
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Cited by
Li, Y., Zhu, C., Jiang, J., Yang, Z., Feng, W., Li, L., Guo, Y., & Hu, J. (2021) · Bioresource Technology · doi:10.1016/j.biortech.2020.124163 · Cited by 42
Zhao, Z.-T., Ding, J., Pang, J.-W., Bao, M.-Y., Luo, G., Wang, B.-Y., Liu, B.-F., Zhang, L.-Y., Ren, N.-Q., & Yang, S.-S. (2025) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2025.2484892 · Cited by 20
Metadata
- Authors
- Liao, Y.-T., Nguyen, V. C., Ishiguro, N., Young, A. P., Tsung, C.-K., & Wu, K. C.-W.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2020-08
- Volume
- 270
- Pages
- 118805
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W3010283641
- Cited by
- 281
- References
- 46
- FWCI
- 17.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Liao, Y.-T., Nguyen, V. C., Ishiguro, N., Young, A. P., Tsung, C.-K., & Wu, K. C.-W. (2020). Engineering a homogeneous alloy-oxide interface derived from metal-organic frameworks for selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2020.118805
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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