Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 538

The DOI matches its Crossref record.

In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries

Nelson, Johanna, Misra, Sumohan, Yang, Yuan, Jackson, Ariel, Liu, Yijin, Wang, Hailiang, Dai, Hongjie, Andrews, Joy C., Cui, Yi, Toney, Michael F.·2012·Journal of the American Chemical Society
DOI 10.1021/ja2121926
Open this paper in CoChat — free account

Abstract

Rechargeable lithium-sulfur (Li-S) batteries hold great potential for high-performance energy storage systems because they have a high theoretical specific energy, low cost, and are eco-friendly. However, the structural and morphological changes during electrochemical reactions are still not well understood. In this Article, these changes in Li-S batteries are studied in operando by X-ray diffraction and transmission X-ray microscopy. We show recrystallization of sulfur by the end of the charge cycle is dependent on the preparation technique of the sulfur cathode. On the other hand, it was found that crystalline Li(2)S does not form at the end of discharge for all sulfur cathodes studied. Furthermore, during cycling the bulk of soluble polysulfides remains trapped within the cathode matrix. Our results differ from previous ex situ results. This highlights the importance of in operando studies and suggests possible strategies to improve cycle life.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1021/ja2121926

Cites

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

No references could be resolved yet.

Research works printed but not linked: 37

  1. Whittingham M. S., 2004, Chem. Rev., 104, 4271, 10.1021/cr020731c · DOI · Paper page
  2. Ellis B. L., 2010, Chem. Mater., 22, 691, 10.1021/cm902696j · DOI · Paper page
  3. Hassoun J., 2011, J. Power Sources, 196, 343, 10.1016/j.jpowsour.2010.06.093 · DOI
  4. Yang Y., 2010, Nano Lett., 10, 1486, 10.1021/nl100504q · DOI · Paper page
  5. Yang Y., 2011, ACS Nano, 5, 9187, 10.1021/nn203436j · DOI · Paper page
  6. Mikhaylik Y. V., 2004, J. Electrochem. Soc., 151, A1969, 10.1149/1.1806394 · DOI · Paper page
  7. Choi J.-W., 2008, J. Power Sources, 183, 441, 10.1016/j.jpowsour.2008.05.038 · doi:10.1016/j.jpowsour.2008.05.038
  8. Wang Y., 2009, Electrochim. Acta, 54, 4062, 10.1016/j.electacta.2009.02.039 · doi:10.1016/j.electacta.2009.02.039
  9. Lee Y. M., 2003, J. Power Sources, 119, 964, 10.1016/S0378-7753(03)00300-8 · DOI · Paper page
  10. Choi Y.-J., 2008, J. Power Sources, 184, 548, 10.1016/j.jpowsour.2008.02.053 · DOI
  11. Ryu H.-S., 2006, J. Power Sources, 153, 360, 10.1016/j.jpowsour.2005.05.037 · DOI
  12. Yuan L. X., 2006, Electrochem. Commun., 8, 610, 10.1016/j.elecom.2006.02.007 · DOI · Paper page
  13. Choi J.-W., 2007, Electrochim. Acta, 52, 2075, 10.1016/j.electacta.2006.08.016 · DOI · Paper page
  14. Jeong S. S., 2007, J. Power Sources, 174, 745, 10.1016/j.jpowsour.2007.06.108 · DOI
  15. Shin J. H., 2008, J. Power Sources, 177, 537, 10.1016/j.jpowsour.2007.11.043 · doi:10.1016/j.jpowsour.2007.11.043
  16. Ji X., 2009, Nat. Mater., 8, 500, 10.1038/nmat2460 · DOI · Paper page
  17. Lai C., 2009, J. Phys. Chem. C, 113, 4712, 10.1021/jp809473e · DOI · Paper page
  18. Liang C., 2009, Chem. Mater., 21, 4724, 10.1021/cm902050j · DOI · Paper page
  19. Jayaprakash N., 2011, Angew. Chem., Int. Ed., 50, 5904, 10.1002/anie.201100637 · DOI · Paper page
  20. Cao Y., 2011, Phys. Chem. Chem. Phys., 13, 7660, 10.1039/c0cp02477e · DOI · Paper page
  21. Li X., 2011, J. Mater. Chem., 21, 16603, 10.1039/c1jm12979a · DOI · Paper page
  22. Wang H., 2011, Nano Lett., 11, 2644, 10.1021/nl200658a · DOI · Paper page
  23. Wang J.-Z., 2011, J. Power Sources, 196, 7030, 10.1016/j.jpowsour.2010.09.106 · DOI · Paper page
  24. Zheng G., 2011, Nano Lett., 11, 10
  25. Cheon S.-E., 2003, J. Electrochem. Soc., 150, A796, 10.1149/1.1571532 · DOI · Paper page
  26. Ryu H.-S., 2009, J. Power Sources, 189, 1179, 10.1016/j.jpowsour.2008.12.073 · DOI
  27. Yuan L., 2009, J. Power Sources, 189, 127, 10.1016/j.jpowsour.2008.10.033 · DOI · Paper page
  28. Elazari R., 2010, J. Electrochem. Soc., 157, A1131, 10.1149/1.3479828 · DOI
  29. Shearing P. R., 2010, Electrochem. Commun., 12, 374, 10.1016/j.elecom.2009.12.038 · DOI · Paper page
  30. Meirer F., 2011, J. Synchrotron Radiat., 18, 773, 10.1107/S0909049511019364 · DOI
  31. Chao S.-C., 2010, Electrochem. Commun., 12, 234, 10.1016/j.elecom.2009.12.002 · DOI
  32. Huang J. Y., 2010, Science, 330, 1515, 10.1126/science.1195628 · DOI · Paper page
  33. Roisnel T., 2000, Proc. Seventh EPDIC, 118
  34. Rodriguez-Carvajal J., 1993, Physica B, 192, 55, 10.1016/0921-4526(93)90108-I · DOI · Paper page
  35. Andrews J. C., 2010, Microsc. Microanal., 16, 327, 10.1017/S1431927610000231 · DOI
  36. Liu Y., 2011, Opt. Express, 19, 540, 10.1364/OE.19.000540 · doi:10.1364/oe.19.000540
  37. Liu Y., 2012, J. Synchrotron Radiat., 19, 281, 10.1107/S0909049511049144 · DOI · Paper page

Cited by

See all 538

Metadata

Authors
Nelson, J., Misra, S., Yang, Y., Jackson, A., Liu, Y., Wang, H., Dai, H., Andrews, J. C., Cui, Y., & Toney, M. F.
Venue
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Published
2012-03-30
Volume
134
Issue
14
Pages
6337-6343
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
DOI
10.1021/ja2121926
OpenAlex
W2110826247
Cited by
538
References
0
FWCI
33.78
Type
journal article
Language
en
Open access
closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries. https://app.cochat.ai/papers/10.1021/ja2121926
The paper
Nelson, J., Misra, S., Yang, Y., Jackson, A., Liu, Y., Wang, H., Dai, H., Andrews, J. C., Cui, Y., & Toney, M. F. (2012). In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries. Journal of the American Chemical Society. https://doi.org/10.1021/ja2121926

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.