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Covalent Attachment of Catalyst Molecules to Conductive Diamond: CO2 Reduction Using “Smart” Electrodes
Abstract
We report here covalent attachment of a catalytically active cobalt complex onto boron-doped, p-type conductive diamond. Peripheral acetylene groups were appended on a cobalt porphyrin complex, and azide-alkyne cycloaddition was used for covalent linking to a diamond surface decorated with alkyl azides. The functionalized surface was characterized by X-ray photoelectron spectroscopy and Fourier transform IR spectroscopy, and the catalytic activity was characterized using cyclic voltammetry and FTIR. The catalyst-modified diamond surfaces were used as "smart" electrodes exhibiting good stability and electrocatalytic activity for electrochemical reduction of CO(2) to CO in acetonitrile solution.
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Cited by
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Zhang, L., Zhao, Z., & Gong, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612214 · Cited by 1,048
Self-citationElectro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Conductive diamond: synthesis, properties, and electrochemical applications
Yang, N., Yu, S., Macpherson, J. V., Einaga, Y., Zhao, H., Zhao, G., Swain, G. M., & Jiang, X. (2019) · Chemical Society Reviews · doi:10.1039/c7cs00757d · Cited by 522
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts
Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452
Metadata
- Authors
- Yao, S. A., Ruther, R. E., Zhang, L., Franking, R. A., Hamers, R. J., & Berry, J. F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-09-13
- Volume
- 134
- Issue
- 38
- Pages
- 15632-15635
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2324731555
- Cited by
- 197
- References
- 0
- FWCI
- 5.22
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yao, S. A., Ruther, R. E., Zhang, L., Franking, R. A., Hamers, R. J., & Berry, J. F. (2012). Covalent Attachment of Catalyst Molecules to Conductive Diamond: CO2 Reduction Using “Smart” Electrodes. Journal of the American Chemical Society. https://doi.org/10.1021/ja304783j
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