Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 211

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Understanding Carbon Dioxide Adsorption on Univalent Cation Forms of the Flexible Zeolite Rho at Conditions Relevant to Carbon Capture from Flue Gases

Lozinska, Magdalena M., Mangano, Enzo, Mowat, John P. S., Shepherd, Ashley M., Howe, Russell F., Thompson, Stephen P., Parker, Julia E., Brandani, Stefano, Wright, Paul A.·2012·Journal of the American Chemical Society
DOI 10.1021/ja3070864
Open this paper in CoChat — free account

Abstract

A series of univalent cation forms of zeolite Rho (M(9.8)Al(9.8)Si(38.2)O(96), M = H, Li, Na, K, NH(4), Cs) and ultrastabilized zeolite Rho (US-Rho) have been prepared. Their CO(2) adsorption behavior has been measured at 298 K and up to 1 bar and related to the structures of the dehydrated forms determined by Rietveld refinement and, for H-Rho and US-Rho, by solid state NMR. Additionally, CO(2) adsorption properties of the H-form of the silicoalumino-phosphate with the RHO topology and univalent cation forms of the zeolite ZK-5 were measured for comparison. The highest uptakes at 0.1 bar, 298 K for both Rho and ZK-5 were obtained on the Li-forms (Li-Rho, 3.4 mmol g(-1); Li-ZK-5, 4.7 mmol g(-1)). H- and US-Rho had relatively low uptakes under these conditions: extra-framework Al species do not interact strongly with CO(2). Forms of zeolite Rho in which cations occupy window sites between α-cages show hysteresis in their CO(2) isotherms, the magnitude of which (Na(+),NH(4)(+) < K(+) < Cs(+)) correlates with the tendency for cations to occupy double eight-membered ring sites rather than single eight-membered ring sites. Hysteresis is not observed for zeolites where cations do not occupy the intercage windows. In situ synchrotron X-ray diffraction of the CO(2) adsorption on Na-Rho at 298 K identifies the adsorption sites. The framework structure of Na-Rho "breathes" as CO(2) is adsorbed and desorbed and its desorption kinetics from Na-Rho at 308 K have been quantified by the Zero Length Column chromatographic technique. Na-Rho shows much higher CO(2)/C(2)H(6) selectivity than Na-ZK-5, as determined by single component adsorption, indicating that whereas CO(2) can diffuse readily through windows containing Na(+) cations, ethane cannot.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1021/ja3070864

Cites

3 of 3 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 3 references

Research works printed but not linked: 49

  1. Barrer R. M., 1965, Trans. Faraday Soc., 61, 948, 10.1039/tf9656100948 · DOI
  2. Pirngruber G. D., 2010, Phys. Chem. Chem. Phys., 12, 13534, 10.1039/b927476f · DOI
  3. Ridha F. N., 2009, Microporous Mesoporous Mater., 117, 497, 10.1016/j.micromeso.2008.07.034 · DOI
  4. Ridha F. N., 2009, Sep. Purif. Technol., 67, 336, 10.1016/j.seppur.2009.03.045 · DOI
  5. Ridha F. N., 2010, Microporous Mesoporous Mater., 132, 22, 10.1016/j.micromeso.2009.07.025 · DOI
  6. Hudson M. R., 2012, J. Am. Chem. Soc., 134, 1970, 10.1021/ja210580b · DOI · Paper page
  7. Robson, H. E.; Shoemaker, D. P.; Ogilvie, R. A.; Manor, P. C.InMolecular Sieves;Meier, W. M.; Uytterhoeven, J. B., Eds.American Chemical Society:Washington, DC, 1973; Adv. Chem. Ser. No. 121, p106. · DOI
  8. Parise J. B., 1984, J. Phys. Chem., 88, 2303, 10.1021/j150655a024 · DOI
  9. Araki S., 2012, Chem. Lett., 41, 125, 10.1246/cl.2012.125 · doi:10.1246/cl.2012.125
  10. Parise J. B., 1984, J. Phys. Chem., 88, 203
  11. Corbin D. R., 1990, J. Am. Chem. Soc., 112, 4821, 10.1021/ja00168a029 · DOI
  12. Fischer R. X., 1986, J. Phys. Chem., 90, 4414, 10.1021/j100409a040 · doi:10.1021/j100409a040
  13. Johnson G. M., 1999, Chem. Mater., 11, 2780, 10.1021/cm990179g · DOI
  14. Eic M., 1988, Zeolites, 8, 472, 10.1016/S0144-2449(88)80223-9 · DOI
  15. Ruthven D. M., 2008, Mol. Sieves, 7, 45, 10.1007/3829_009 · DOI
  16. Brandani S., 1995, Zeolites, 15, 624, 10.1016/0144-2449(95)00042-5 · DOI
  17. Brandani S., 1996, Adsorption, 2, 133, 10.1007/BF00127043 · DOI
  18. Lievens J. L., 1992, Zeolites, 12, 690, 10.1016/0144-2449(92)90117-8 · DOI
  19. Pulido A., 2009, J. Phys. Chem. C, 113, 2928, 10.1021/jp810038b · DOI
  20. Zukal A., 2011, Microporous Mesoporous Mater., 146, 97, 10.1016/j.micromeso.2011.03.034 · DOI
  21. Chatelain T., 1995, Microporous Mater., 4, 231, 10.1016/0927-6513(95)00009-X · DOI
  22. Araki S., 2012, J. Colloid Interface Sci., 376, 28, 10.1016/j.jcis.2012.02.038 · doi:10.1016/j.jcis.2012.02.038
  23. Su X., 2011, Microporous Mesoporous Mater., 144, 113, 10.1016/j.micromeso.2011.04.004 · DOI
  24. Langmi H. W., 2005, J. Alloys Compd., 404, 637, 10.1016/j.jallcom.2004.12.193 · DOI · Paper page
  25. Udovic T. J., 1987, J. Phys. Chem., 91, 5968, 10.1021/j100307a031 · doi:10.1021/j100307a031
  26. Fischer R. X., 1987, J. Phys. Chem., 91, 2227, 10.1021/j100293a001 · doi:10.1021/j100293a001
  27. Fischer R. X., 1988, Acta Crystallogr., 44, 321, 10.1107/S0108768188000916 · DOI
  28. Larson A. C., 1994, General Structure Analysis System (GSAS)
  29. Cartlidge S., 1984, Zeolites, 4, 218, 10.1016/0144-2449(84)90027-7 · DOI
  30. Thompson S. P., 2009, Rev. Sci. Instrum., 80, 075107, 10.1063/1.3167217 · DOI · Paper page
  31. Parker J. E., 2012, Mater. Sci. Forum, 706, 1707, 10.4028/www.scientific.net/MSF.706-709.1707 · DOI
  32. Yu Z. W., 2010, Angew. Chem., Int. Ed., 49, 8657, 10.1002/anie.201004007 · DOI
  33. Cook, M.; Conner, W. C.inProceedings of the 12th International Zeological Conference;Treacy, M. M. J.; Marcus, B. K.; Bisher, M. E.; Higgins, J. B., Eds.Materials Research Society,Warrendale, PA, 1999; p409.
  34. Vrabec J., 2001, J. Phys. Chem. B., 105, 12126, 10.1021/jp012542o · doi:10.1021/jp012542o
  35. Fischer R. X., 1989, Acta Crystallogr., 45, 983
  36. Tian P., 2011, Chem. Mater., 23, 1406, 10.1021/cm103512m · DOI
  37. McCusker L. B., 1984, Zeolites, 4, 51, 10.1016/0144-2449(84)90073-3 · DOI
  38. 10.1002/cssc.201200339 · DOI
  39. Bourrelly S., 2005, J. Am. Chem. Soc., 127, 13519, 10.1021/ja054668v · DOI · Paper page
  40. Llewellyn P. L., 2006, Angew. Chem., Int. Ed., 45, 7751, 10.1002/anie.200602278 · DOI · Paper page
  41. Coudert F. X., 2011, ChemPhysChem, 12, 247, 10.1002/cphc.201000590 · DOI
  42. Garrone E., 2002, J. Chem. Phys., 117, 10274, 10.1063/1.1519254 · DOI
  43. Galhotra P., 2009, Energy Environ. Sci., 2, 401, 10.1039/b814908a · DOI
  44. Siporin S. E., 2003, Langmuir, 19, 4707, 10.1021/la020971n · DOI
  45. Brandani S., 1998, Chem. Eng. Sci., 53, 2791, 10.1016/S0009-2509(98)00075-X · DOI
  46. Brandani S., 2000, Chem. Eng. Sci., 55, 1205, 10.1016/S0009-2509(99)00411-X · doi:10.1016/s0009-2509(99)00411-x
  47. Plant D. F., 2006, J. Phys. Chem. B, 110, 14372, 10.1021/jp062381u · DOI
  48. Ahn H., 2004, Adsorption, 10, 111, 10.1023/B:ADSO.0000039867.14756.ac · DOI
  49. Reisner B. A., 2000, Chem. Commun., 2221, 10.1039/b006929i · DOI

Cited by

See all 211

Metadata

Authors
Lozinska, M. M., Mangano, E., Mowat, J. P. S., Shepherd, A. M., Howe, R. F., Thompson, S. P., Parker, J. E., Brandani, S., & Wright, P. A.
Venue
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Published
2012-10-11
Volume
134
Issue
42
Pages
17628-17642
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
DOI
10.1021/ja3070864
OpenAlex
W2117816816
Cited by
211
References
3
FWCI
16.17
Type
journal article
Language
en
Open access
closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Understanding Carbon Dioxide Adsorption on Univalent Cation Forms of the Flexible Zeolite Rho at Conditions Relevant to Carbon Capture from Flue Gases. https://app.cochat.ai/papers/10.1021/ja3070864
The paper
Lozinska, M. M., Mangano, E., Mowat, J. P. S., Shepherd, A. M., Howe, R. F., Thompson, S. P., Parker, J. E., Brandani, S., & Wright, P. A. (2012). Understanding Carbon Dioxide Adsorption on Univalent Cation Forms of the Flexible Zeolite Rho at Conditions Relevant to Carbon Capture from Flue Gases. Journal of the American Chemical Society. https://doi.org/10.1021/ja3070864

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.