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Phosphonium-Functionalized Polyethylene: A New Class of Base-Stable Alkaline Anion Exchange Membranes

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Noonan, Kevin J. T., Hugar, Kristina M., Kostalik, Henry A., Lobkovsky, Emil B., Abruña, Héctor D., Coates, Geoffrey W.·2012·Journal of the American Chemical Society

DOI 10.1021/ja307466s

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Abstract

A tetrakis(dialkylamino)phosphonium cation was evaluated as a functional group for alkaline anion exchange membranes (AAEMs). The base stability of [P(N(Me)Cy)(4)](+) was directly compared to that of [BnNMe(3)](+) in 1 M NaOD/CD(3)OD. The high base stability of [P(N(Me)Cy)(4)](+) relative to [BnNMe(3)](+) inspired the preparation of AAEM materials composed of phosphonium units attached to polyethylene. The AAEMs (hydroxide conductivity of 22 ± 1 mS cm(-1) at 22 °C) were prepared using ring-opening metathesis polymerization, and their stabilities were evaluated in 15 M KOH at 22 °C and in 1 M KOH at 80 °C.

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Authors: Noonan, K. J. T., Hugar, K. M., Kostalik, H. A., Lobkovsky, E. B., Abruña, H. D., & Coates, G. W.
Venue: Journal of the American Chemical Society
Publisher: American Chemical Society (ACS)
Published: 2012-10-26
Volume: 134
Issue: 44
Pages: 18161-18164
ISSN: 0002-7863 (ISSN-L)
1520-5126
DOI: 10.1021/ja307466s
OpenAlex: W2234890344
Cited by: 490
References: 58
FWCI: 17.50
Type: journal article
Language: en
Open access: hybrid

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Phosphonium-Functionalized Polyethylene: A New Class of Base-Stable Alkaline Anion Exchange Membranes

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