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Self-crosslinking for dimensionally stable and solvent-resistant quaternary phosphonium based hydroxide exchange membranes
Abstract
A simple self-crosslinking strategy, without the needs of a separate crosslinker or a catalyst, is reported here. The crosslinking drastically lowers the water swelling ratio (e.g., 5-10 folds reduction) and provides excellent solvent-resistance. The self-crosslinked membrane (DCL: 5.3%) shows the highest IEC-normalized hydroxide conductivity among all crosslinked HEMs reported.
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Cited by
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Bipolar membranes: A review on principles, latest developments, and applications
Pärnamäe, R., Mareev, S., Nikonenko, V., Melnikov, S., Sheldeshov, N., Zabolotskii, V., Hamelers, H. V. M., & Tedesco, M. (2021) · Journal of Membrane Science · doi:10.1016/j.memsci.2020.118538 · Cited by 610
Noonan, K. J. T., Hugar, K. M., Kostalik, H. A., Lobkovsky, E. B., Abruña, H. D., & Coates, G. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307466s · Cited by 490
Alkaline-stable anion exchange membranes: A review of synthetic approaches
You, W., Noonan, K. J. T., & Coates, G. W. (2020) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2019.101177 · Cited by 389
Metadata
- Authors
- Gu, S., Cai, R., & Yan, Y.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 47
- Issue
- 10
- Pages
- 2856
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2098382497
- Cited by
- 264
- References
- 0
- FWCI
- 17.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Self-crosslinking for dimensionally stable and solvent-resistant quaternary phosphonium based hydroxide exchange membranes. https://app.cochat.ai/papers/10.1039/c0cc04335d
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- Gu, S., Cai, R., & Yan, Y. (2011). Self-crosslinking for dimensionally stable and solvent-resistant quaternary phosphonium based hydroxide exchange membranes. Chemical Communications. https://doi.org/10.1039/c0cc04335d
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
