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Ordered Mesoporous Cobalt Oxide as Highly Efficient Oxygen Evolution Catalyst
Abstract
Oxygen evolution from water by use of earth-abundant element-based catalysts is crucial for mass solar fuel production. In this report, a mesoporous cobalt oxide with an ultrahigh surface area (up to 250 m(2)·g(-1)) has been fabricated through Mg substitution in the mesoporous Co3O4 spinel, followed by a Mg-selective leaching process. Approximately a third of Mg cations were removed in the leaching process, resulting in a highly porous cobalt oxide with a significant amount of defects in the spinel structure. The activated mesoporous cobalt oxide exhibited high oxygen evolution activities in both the visible-light-driven [Ru(bpy)3](2+)-persulfate system and the Ce(4+)/Ce(3+) chemical water oxidation system. Under a strong acidic environment, a high turnover frequency (TOF) of ~2.2 × 10(-3) s(-1) per Co atom was achieved, which is more than twice the TOF of traditional hard-templated, mesoporous Co3O4.
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Cites
ATHENA,ARTEMIS,HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT
Ravel, B., & Newville, M. (2005) · Journal of Synchrotron Radiation · doi:10.1107/s0909049505012719 · Cited by 16,965
Grätzel, M. (2001) · Nature · doi:10.1038/35104607 · Cited by 12,687
Heterogeneous photocatalyst materials for water splitting
Kudo, A., & Miseki, Y. (2009) · Chem. Soc. Rev. · doi:10.1039/b800489g · Cited by 10,585
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co 2+
Kanan, M. W., & Nocera, D. G. (2008) · Science · doi:10.1126/science.1162018 · Cited by 4,122
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1998) · Nature · doi:10.1038/24132 · Cited by 2,493
Synthesis and Applications of Supramolecular-Templated Mesoporous Materials
Ying, J. Y., Mehnert, C. P., & Wong, M. S. (1999) · Angewandte Chemie International Edition · doi:10.1002/(sici)1521-3773(19990115)38:1/2<56::aid-anie56>3.0.co;2-e · Cited by 2,030
Lessons from nature about solar light harvesting
Scholes, G. D., Fleming, G. R., Olaya-Castro, A., & van Grondelle, R. (2011) · Nature Chemistry · doi:10.1038/nchem.1145 · Cited by 1,915
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation
Gorlin, Y., & Jaramillo, T. F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104587v · Cited by 1,566
High-Flux Solar-Driven Thermochemical Dissociation of CO 2 and H 2 O Using Nonstoichiometric Ceria
Chueh, W. C., Falter, C., Abbott, M., Scipio, D., Furler, P., Haile, S. M., & Steinfeld, A. (2010) · Science · doi:10.1126/science.1197834 · Cited by 1,511
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
Yin, Q., Tan, J. M., Besson, C., Geletii, Y. V., Musaev, D. G., Kuznetsov, A. E., Luo, Z., Hardcastle, K. I., & Hill, C. L. (2010) · Science · doi:10.1126/science.1185372 · Cited by 1,438
Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials
Lu, A. ‐., & Schüth, F. (2006) · Advanced Materials · doi:10.1002/adma.200600148 · Cited by 1,321
Nanostructured Cobalt Oxide Clusters in Mesoporous Silica as Efficient Oxygen‐Evolving Catalysts
Jiao, F., & Frei, H. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200805534 · Cited by 764
Self-citationCobalt–phosphate oxygen-evolving compound
Kanan, M. W., Surendranath, Y., & Nocera, D. G. (2009) · Chem. Soc. Rev. · doi:10.1039/b802885k · Cited by 740
Kanan, M. W., Yano, J., Surendranath, Y., Dincă, M., Yachandra, V. K., & Nocera, D. G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1023767 · Cited by 711
Water Oxidation Electrocatalyzed by an Efficient Mn3O4/CoSe2Nanocomposite
Gao, M.-R., Xu, Y.-F., Jiang, J., Zheng, Y.-R., & Yu, S.-H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja211526y · Cited by 681
Metal oxides as heterogeneous catalysts for oxygen evolution under photochemical conditions
Harriman, A., Pickering, I. J., Thomas, J. M., & Christensen, P. A. (1988) · Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases · doi:10.1039/f19888402795 · Cited by 537
Nanostructured cobalt and manganese oxide clusters as efficient water oxidation catalysts
Jiao, F., & Frei, H. (2010) · Energy & Environmental Science · doi:10.1039/c002074e · Cited by 518
Self-citationSynthesis of replica mesostructures by the nanocasting strategy
Yang, H., & Zhao, D. (2005) · Journal of Materials Chemistry · doi:10.1039/b414402c · Cited by 504
Plasmon Enhanced Solar-to-Fuel Energy Conversion
Thomann, I., Pinaud, B. A., Chen, Z., Clemens, B. M., Jaramillo, T. F., & Brongersma, M. L. (2011) · Nano Letters · doi:10.1021/nl201908s · Cited by 496
Calcium Manganese(III) Oxides (CaMn2O4⋅x H2O) as Biomimetic Oxygen‐Evolving Catalysts
Najafpour, M. M., Ehrenberg, T., Wiechen, M., & Kurz, P. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200906745 · Cited by 496
Tian, B., Liu, X., Yang, H., Xie, S., Yu, C., Tu, B., & Zhao, D. (2003) · Advanced Materials · doi:10.1002/adma.200305211 · Cited by 426
Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II
Liu, F., Concepcion, J. J., Jurss, J. W., Cardolaccia, T., Templeton, J. L., & Meyer, T. J. (2008) · Inorganic Chemistry · doi:10.1021/ic701249s · Cited by 419
Ordered Mesoporous Fe2O3 with Crystalline Walls
Jiao, F., Harrison, A., Jumas, J.-C., Chadwick, A. V., Kockelmann, W., & Bruce, P. G. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0584774 · Cited by 392
Self-citationWang, D., Li, R., Zhu, J., Shi, J., Han, J., Zong, X., & Li, C. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp210584b · Cited by 379
A Co4O4 “Cubane” Water Oxidation Catalyst Inspired by Photosynthesis
McCool, N. S., Robinson, D. M., Sheats, J. E., & Dismukes, G. C. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203877y · Cited by 353
The Nature of Lithium Battery Materials under Oxygen Evolution Reaction Conditions
Lee, S. W., Carlton, C., Risch, M., Surendranath, Y., Chen, S., Furutsuki, S., Yamada, A., Nocera, D. G., & Shao-Horn, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307814j · Cited by 316
Pinaud, B. A., Chen, Z., Abram, D. N., & Jaramillo, T. F. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp200015p · Cited by 294
Iyer, A., Del-Pilar, J., King’ondu, C. K., Kissel, E., Garces, H. F., Huang, H., El-Sawy, A. M., Dutta, P. K., & Suib, S. L. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp2120737 · Cited by 287
Robinson, D. M., Go, Y. B., Greenblatt, M., & Dismukes, G. C. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1055615 · Cited by 286
Hara, M., Waraksa, C. C., Lean, J. T., Lewis, B. A., & Mallouk, T. E. (2000) · The Journal of Physical Chemistry A · doi:10.1021/jp000321x · Cited by 277
Synthesis of Nanowire and Mesoporous Low‐Temperature LiCoO2 by a Post‐Templating Reaction
Jiao, F., Shaju, K. M., & Bruce, P. G. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200501663 · Cited by 274
Self-citationPhotocatalytic water oxidation with suspended alpha-Fe2O3 particles-effects of nanoscaling
Townsend, T. K., Sabio, E. M., Browning, N. D., & Osterloh, F. E. (2011) · Energy & Environmental Science · doi:10.1039/c1ee02110a · Cited by 234
In Pursuit of Water Oxidation Catalysts for Solar Fuel Production
Hurst, J. K. (2010) · Science · doi:10.1126/science.1187721 · Cited by 228
Nanostructured MnO2: an efficient and robust water oxidation catalyst
Boppana, V. B. R., & Jiao, F. (2011) · Chemical Communications · doi:10.1039/c1cc12258d · Cited by 193
Self-citationWater oxidation catalyzed by dimeric μ-oxo bridged ruthenium diimine complexes
Hurst, J. K. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.06.017 · Cited by 188
McAlpin, J. G., Stich, T. A., Ohlin, C. A., Surendranath, Y., Nocera, D. G., Casey, W. H., & Britt, R. D. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202320q · Cited by 166
Structural Requirements in Lithium Cobalt Oxides for the Catalytic Oxidation of Water
Gardner, G. P., Go, Y. B., Robinson, D. M., Smith, P. F., Hadermann, J., Abakumov, A., Greenblatt, M., & Dismukes, G. C. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107625 · Cited by 161
Towards practical implementation
Dahl, S., & Chorkendorff, I. (2012) · Nature Materials · doi:10.1038/nmat3233 · Cited by 141
Photochemical water oxidation with visible light using a cobalt containing catalyst
Shevchenko, D. V., Anderlund, M. F., Thapper, A., & Styring, S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00585a · Cited by 124
LaCoO3 acting as an efficient and robust catalyst for photocatalytic water oxidation with persulfate
Yamada, Y., Yano, K., Hong, D., & Fukuzumi, S. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp00022a · Cited by 118
Light-driven wateroxidation with a molecular tetra-cobalt(iii) cubanecluster
Ganga, G. L., Puntoriero, F., Campagna, S., Bazzan, I., Berardi, S., Bonchio, M., Sartorel, A., Natali, M., & Scandola, F. (2011) · Faraday Discussions · doi:10.1039/c1fd00093d · Cited by 112
A Mechanistic Study of Oxygen Evolution on Li‐Doped Co3 O 4
Rasiyah, P., & Tseung, A. C. C. (1983) · Journal of The Electrochemical Society · doi:10.1149/1.2119712 · Cited by 110
Effect of the Support on the Photocatalytic Water Oxidation Activity of Cobalt Oxide Nanoclusters
Yusuf, S., & Jiao, F. (2012) · ACS Catalysis · doi:10.1021/cs300581k · Cited by 97
Self-citationShedding Light on Solar Fuel Efficiencies
Hammarström, L., Winkler, J. R., Gray, H. B., & Styring, S. (2011) · Science · doi:10.1126/science.333.6040.288-a · Cited by 32
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Recent Progress in Cobalt‐Based Heterogeneous Catalysts for Electrochemical Water Splitting
Wang, J., Cui, W., Liu, Q., Xing, Z., Asiri, A. M., & Sun, X. (2016) · Advanced Materials · doi:10.1002/adma.201502696 · Cited by 2,446
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Engineering heterogeneous semiconductors for solar water splitting
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., & Chen, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04461d · Cited by 1,888
Transition‐Metal (Co, Ni, and Fe)‐Based Electrocatalysts for the Water Oxidation Reaction
Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Bao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502226 · Cited by 1,428
Metadata
- Authors
- Rosen, J., Hutchings, G. S., & Jiao, F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-03-12
- Volume
- 135
- Issue
- 11
- Pages
- 4516-4521
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974569397
- Cited by
- 419
- References
- 46
- FWCI
- 18.39
- Type
- journal article
- Language
- en
- Open access
- closed
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