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High-Flux Solar-Driven Thermochemical Dissociation of CO 2 and H 2 O Using Nonstoichiometric Ceria
Abstract
Fuel from Heat: Plants grow by using energy from the Sun to convert carbon dioxide into sugar-based polymers and aromatics. These compounds in turn can be stripped of their oxygen, either through millennia of underground degradation to yield fossil fuels, or through a rather more rapid process of dissolution, fermentation, and hydrogenation to yield biofuels. Can we use sunlight to turn CO 2 into hydrocarbon fuel without relying on the intervening steps of plant growth and breakdown? Chueh et al. (p. 1797 ) demonstrate one possible approach, in which concentrated sunlight heats cerium oxide to a sufficiently high temperature (∼1500°C) to liberate some oxygen from its lattice. The material then readily strips O atoms from either water or CO 2 , yielding hydrogen or CO, which can then be combined to form fuels.
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Cites
Hori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401
Cited by
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Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
A review of energy storage types, applications and recent developments
Koohi-Fayegh, S., & Rosen, M. A. (2020) · Journal of Energy Storage · doi:10.1016/j.est.2019.101047 · Cited by 2,009
A Review of Direct Z‐Scheme Photocatalysts
Low, J., Jiang, C., Cheng, B., Wageh, S., Al‐Ghamdi, A. A., & Yu, J. (2017) · Small Methods · doi:10.1002/smtd.201700080 · Cited by 1,381
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Metadata
- Authors
- Chueh, W. C., Falter, C., Abbott, M., Scipio, D., Furler, P., Haile, S. M., & Steinfeld, A.
- Venue
- Science
- Published
- 2010-12-24
- Volume
- 330
- Issue
- 6012
- Pages
- 1797-1801
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1984020769
- Cited by
- 1,511
- References
- 1
- FWCI
- 32.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chueh, W. C., Falter, C., Abbott, M., Scipio, D., Furler, P., Haile, S. M., & Steinfeld, A. (2010). High-Flux Solar-Driven Thermochemical Dissociation of CO 2 and H 2 O Using Nonstoichiometric Ceria. Science. https://doi.org/10.1126/science.1197834
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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