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Superprotonic Conductivity in a Highly Oriented Crystalline Metal–Organic Framework Nanofilm
Abstract
The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.
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Cites
On the development of proton conducting materials for technological applications
Kreuer, K. D. (1997) · Solid State Ionics · doi:10.1016/s0167-2738(97)00082-9 · Cited by 1,036
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Metadata
- Authors
- Xu, G., Otsubo, K., Yamada, T., Sakaida, S., & Kitagawa, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-09
- Volume
- 135
- Issue
- 20
- Pages
- 7438-7441
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2102160831
- Cited by
- 354
- References
- 1
- FWCI
- 12.88
- Type
- journal article
- Language
- en
- Open access
- closed
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