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A Biomimetic Copper Water Oxidation Catalyst with Low Overpotential
Abstract
Simply mixing a Cu(II) salt and 6,6'-dihydroxy-2,2'-bipyridine (H2L) in a basic aqueous solution afforded a highly active water oxidation catalyst (WOC). Cyclic voltammetry of the solution at pH = 12-14 shows irreversible catalytic current with an onset potential of ~0.8 V versus NHE. Catalytic oxygen evolution takes place in controlled potential electrolysis at a relatively low overpotential of 640 mV. Experimental and computational studies suggest that the L ligand participates in electron transfer processes to facilitate the oxidation of the Cu center to lead to an active WOC with low overpotential, akin to the use of the tyrosine radical by Photosystem II to oxidize the CaMn4 center for water oxidation.
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Citations
Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Electrochemical Methods: Fundamentals and Applications
Bard, A. J., & Faulkner, L. R. (1980) · Cited by 22,435
Electrochemical Methods: Fundamentals and Applications
de Rooij, D. M. R. (2003) · Anti-Corrosion Methods and Materials · doi:10.1108/acmm.2003.12850eae.001 · Cited by 13,009
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co 2+
Kanan, M. W., & Nocera, D. G. (2008) · Science · doi:10.1126/science.1162018 · Cited by 4,122
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å
Umena, Y., Kawakami, K., Shen, J.-R., & Kamiya, N. (2011) · Nature · doi:10.1038/nature09913 · Cited by 3,913
Architecture of the Photosynthetic Oxygen-Evolving Center
Ferreira, K. N., Iverson, T. M., Maghlaoui, K., Barber, J., & Iwata, S. (2004) · Science · doi:10.1126/science.1093087 · Cited by 3,329
COOPERATION OF CHARGES IN PHOTOSYNTHETIC O2 EVOLUTION–I. A LINEAR FOUR STEP MECHANISM
KOK, B., FORBUSH, B., & McGLOIN, M. (1970) · Photochemistry and Photobiology · doi:10.1111/j.1751-1097.1970.tb06017.x · Cited by 2,114
Crystal structure of photosystem II from Synechococcus elongatus at 3.8 Å resolution
Zouni, A., Witt, H.-T., Kern, J., Fromme, P., Krauss, N., Saenger, W., & Orth, P. (2001) · Nature · doi:10.1038/35055589 · Cited by 1,947
Towards complete cofactor arrangement in the 3.0 Å resolution structure of photosystem II
Loll, B., Kern, J., Saenger, W., Zouni, A., & Biesiadka, J. (2005) · Nature · doi:10.1038/nature04224 · Cited by 1,867
Photosynthetic energy conversion: natural and artificial
Barber, J. (2009) · Chem. Soc. Rev. · doi:10.1039/b802262n · Cited by 1,843
Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts
Reece, S. Y., Hamel, J. A., Sung, K., Jarvi, T. D., Esswein, A. J., Pijpers, J. J. H., & Nocera, D. G. (2011) · Science · doi:10.1126/science.1209816 · Cited by 1,687
Water-Splitting Chemistry of Photosystem II
McEvoy, J. P., & Brudvig, G. W. (2006) · Chemical Reviews · doi:10.1021/cr0204294 · Cited by 1,550
Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution
Trotochaud, L., Ranney, J. K., Williams, K. N., & Boettcher, S. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307507a · Cited by 1,548
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
Yin, Q., Tan, J. M., Besson, C., Geletii, Y. V., Musaev, D. G., Kuznetsov, A. E., Luo, Z., Hardcastle, K. I., & Hill, C. L. (2010) · Science · doi:10.1126/science.1185372 · Cited by 1,438
A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II
Duan, L., Bozoglian, F., Mandal, S., Stewart, B., Privalov, T., Llobet, A., & Sun, L. (2012) · Nature Chemistry · doi:10.1038/nchem.1301 · Cited by 1,257
Youngblood, W. J., Lee, S.-H. A., Kobayashi, Y., Hernandez-Pagan, E. A., Hoertz, P. G., Moore, T. A., Moore, A. L., Gust, D., & Mallouk, T. E. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809108y · Cited by 896
Costentin, C., Drouet, S., Robert, M., & Savéant, J.-M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303560c · Cited by 849
Making Oxygen with Ruthenium Complexes
Concepcion, J. J., Jurss, J. W., Brennaman, M. K., Hoertz, P. G., Patrocinio, A. O. T., Murakami Iha, N. Y., Templeton, J. L., & Meyer, T. J. (2009) · Accounts of Chemical Research · doi:10.1021/ar9001526 · Cited by 821
A soluble copper–bipyridine water-oxidation electrocatalyst
Barnett, S. M., Goldberg, K. I., & Mayer, J. M. (2012) · Nature Chemistry · doi:10.1038/nchem.1350 · Cited by 797
Efficient water oxidation catalysts based on readily available iron coordination complexes
Fillol, J. L., Codolà, Z., Garcia-Bosch, I., Gómez, L., Pla, J. J., & Costas, M. (2011) · Nature Chemistry · doi:10.1038/nchem.1140 · Cited by 784
Nanostructured Cobalt Oxide Clusters in Mesoporous Silica as Efficient Oxygen‐Evolving Catalysts
Jiao, F., & Frei, H. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200805534 · Cited by 764
Electroanalytical Chemistry: A Series of Advances
(2010) · Electroanalytical chemistry, a series of advances · doi:10.1201/crcelecheadv · Cited by 740
Photocatalytic Overall Water Splitting Promoted by an α–β phase Junction on Ga2O3
Wang, X., Xu, Q., Li, M., Shen, S., Wang, X., Wang, Y., Feng, Z., Shi, J., Han, H., & Li, C. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201207554 · Cited by 652
Fast Water Oxidation Using Iron
Ellis, W. C., McDaniel, N. D., Bernhard, S., & Collins, T. J. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104766z · Cited by 621
McDaniel, N. D., Coughlin, F. J., Tinker, L. L., & Bernhard, S. (2008) · Journal of the American Chemical Society · doi:10.1021/ja074478f · Cited by 610
Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation
Hull, J. F., Balcells, D., Blakemore, J. D., Incarvito, C. D., Eisenstein, O., Brudvig, G. W., & Crabtree, R. H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja901270f · Cited by 594
Wilson, A. D., Newell, R. H., McNevin, M. J., Muckerman, J. T., Rakowski DuBois, M., & DuBois, D. L. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056442y · Cited by 575
Development of Bioinspired Mn4O4−Cubane Water Oxidation Catalysts: Lessons from Photosynthesis
Dismukes, G. C., Brimblecombe, R., Felton, G. A. N., Pryadun, R. S., Sheats, J. E., Spiccia, L., & Swiegers, G. F. (2009) · Accounts of Chemical Research · doi:10.1021/ar900249x · Cited by 549
Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells
Swierk, J. R., & Mallouk, T. E. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35246j · Cited by 534
Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles
Dogutan, D. K., McGuire, R., & Nocera, D. G. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202138m · Cited by 525
Cox, N., Pantazis, D. A., Neese, F., & Lubitz, W. (2013) · Accounts of Chemical Research · doi:10.1021/ar3003249 · Cited by 501
Electrocatalytic Water Oxidation with a Copper(II) Polypeptide Complex
Zhang, M.-T., Chen, Z., Kang, P., & Meyer, T. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja3097515 · Cited by 476
Zhang, F., Yamakata, A., Maeda, K., Moriya, Y., Takata, T., Kubota, J., Teshima, K., Oishi, S., & Domen, K. (2012) · Journal of the American Chemical Society · doi:10.1021/ja301726c · Cited by 415
Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex
Wasylenko, D. J., Ganesamoorthy, C., Borau-Garcia, J., & Berlinguette, C. P. (2011) · Chemical Communications · doi:10.1039/c0cc05522k · Cited by 380
Wang, C., Wang, J.-L., & Lin, W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja310074j · Cited by 342
Self-citationEisenberg, R., & Gray, H. B. (2008) · Inorganic Chemistry · doi:10.1021/ic800155g · Cited by 320
Ohno, T., Bai, L., Hisatomi, T., Maeda, K., & Domen, K. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302479f · Cited by 316
Copper(II) Catalysis of Water Oxidation
Chen, Z., & Meyer, T. J. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207215 · Cited by 295
Hara, M., Waraksa, C. C., Lean, J. T., Lewis, B. A., & Mallouk, T. E. (2000) · The Journal of Physical Chemistry A · doi:10.1021/jp000321x · Cited by 277
Wang, W.-H., Hull, J. F., Muckerman, J. T., Fujita, E., & Himeda, Y. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21888g · Cited by 256
Alternating electron and proton transfer steps in photosynthetic water oxidation
Klauss, A., Haumann, M., & Dau, H. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1206266109 · Cited by 202
Kolthoff, I. M., & Tomsicek, W. J. (1935) · The Journal of Physical Chemistry · doi:10.1021/j150367a004 · Cited by 197
Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand
Ringenberg, M. R., Kokatam, S. L., Heiden, Z. M., & Rauchfuss, T. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja076801k · Cited by 193
Catalytic proton reduction with transition metal complexes of the redox-active ligand bpy2PYMe
Nippe, M., Khnayzer, R. S., Panetier, J. A., Zee, D. Z., Olaiya, B. S., Head-Gordon, M., Chang, C. J., Castellano, F. N., & Long, J. R. (2013) · Chemical Science · doi:10.1039/c3sc51660a · Cited by 188
Catalytic and Surface‐Electrocatalytic Water Oxidation by Redox Mediator–Catalyst Assemblies
Concepcion, J. J., Jurss, J. W., Hoertz, P. G., & Meyer, T. J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200901279 · Cited by 161
Catalytic and Surface‐Electrocatalytic Water Oxidation by Redox Mediator–Catalyst Assemblies
Concepcion, J. J., Jurss, J. W., Hoertz, P. G., & Meyer, T. J. (2009) · Angewandte Chemie · doi:10.1002/ange.200901279 · Cited by 158
The Cu(II)-2,2′-bipyridine system revisited
Garribba, E., Micera, G., Sanna, D., & Strinna-Erre, L. (2000) · Inorganica Chimica Acta · doi:10.1016/s0020-1693(99)00508-3 · Cited by 117
Kärkäs, M. D., Åkermark, T., Johnston, E. V., Karim, S. R., Laine, T. M., Lee, B., Åkermark, T., Privalov, T., & Åkermark, B. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201205018 · Cited by 101
Marenich, A. V., Majumdar, A., Lenz, M., Cramer, C. J., & Truhlar, D. G. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201206012 · Cited by 67
Hydrolytic reactions of copper(II) bipyridine complexes
Fábián, I. (1989) · Inorganic Chemistry · doi:10.1021/ic00319a011 · Cited by 28
Cited by
Chang, J., Xiao, Y., Xiao, M., Ge, J., Liu, C., & Xing, W. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02076 · Cited by 478
Metadata
- Authors
- Zhang, T., Wang, C., Liu, S., Wang, J.-L., & Lin, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-20
- Volume
- 136
- Issue
- 1
- Pages
- 273-281
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2335483813
- Cited by
- 389
- References
- 50
- FWCI
- 14.43
- Type
- journal article
- Language
- en
- Open access
- closed
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