The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups
Abstract
The elimination of specific environmental and industrial contaminants, which are hazardous at only part per million to part per billion concentrations, poses a significant technological challenge. Adsorptive materials designed for such processes must be engendered with an exceptionally high enthalpy of adsorption for the analyte of interest. Rather than relying on a single strong interaction, the use of multiple chemical interactions is an emerging strategy for achieving this requisite physical parameter. Herein, we describe an efficient, catalytic synthesis of diamondoid porous organic polymers densely functionalized with carboxylic acids. Physical parameters such as pore size distribution, application of these materials to low-pressure ammonia adsorption, and comparison with analogous materials featuring functional groups of varying acidity are presented. In particular, BPP-5, which features a multiply interpenetrated structure dominated by <6 Å pores, is shown to exhibit an uptake of 17.7 mmol/g at 1 bar, the highest capacity yet demonstrated for a readily recyclable material. A complementary framework, BPP-7, features slightly larger pore sizes, and the resulting improvement in uptake kinetics allows for efficient adsorption at low pressure (3.15 mmol/g at 480 ppm). Overall, the data strongly suggest that the spatial arrangement of acidic sites allows for cooperative behavior, which leads to enhanced NH3 adsorption.
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Citations
Cites
Metal-organic framework materials as catalysts
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The role of sulfur-containing groups in ammonia retention on activated carbons
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Chemistry of Covalent Organic Frameworks
Waller, P. J., Gándara, F., & Yaghi, O. M. (2015) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00369 · Cited by 1,897
Metal–Organic Frameworks against Toxic Chemicals
Islamoglu, T., Chen, Z., Wasson, M. C., Buru, C. T., Kirlikovali, K. O., Afrin, U., Mian, M. R., & Farha, O. K. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00828 · Cited by 707
Porous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Nonporous Adaptive Crystals of Pillararenes
Jie, K., Zhou, Y., Li, E., & Huang, F. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00255 · Cited by 533
Construction and application of base-stable MOFs: a critical review
Wang, K., Li, Y., Xie, L.-H., Li, X., & Li, J.-R. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00891a · Cited by 462
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Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
Rieth, A. J., Wright, A. M., & Dincă, M. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0140-1 · Cited by 402
Controlled Gas Uptake in Metal–Organic Frameworks with Record Ammonia Sorption
Rieth, A. J., & Dincă, M. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b00313 · Cited by 336
Rieth, A. J., Tulchinsky, Y., & Dincă, M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05723 · Cited by 305
A Crystalline Polyimide Porous Organic Framework for Selective Adsorption of Acetylene over Ethylene
Jiang, L., Tian, Y., Sun, T., Zhu, Y., Ren, H., Zou, X., Ma, Y., Meihaus, K. R., Long, J. R., & Zhu, G. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08174 · Cited by 282
Self-citationPhenol-Based Ternary Deep Eutectic Solvents for Highly Efficient and Reversible Absorption of NH3
Zhong, F.-Y., Peng, H.-L., Tao, D.-J., Wu, P.-K., Fan, J.-P., & Huang, K. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05221 · Cited by 122
Metadata
- Authors
- Van Humbeck, J. F., McDonald, T. M., Jing, X., Wiers, B. M., Zhu, G., & Long, J. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-02-04
- Volume
- 136
- Issue
- 6
- Pages
- 2432-2440
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2094617320
- Cited by
- 321
- References
- 3
- FWCI
- 8.19
- Type
- journal article
- Language
- en
- Open access
- closed
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