The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites
Abstract
A series of new mesoporous metal-organic frameworks (MOFs) made from extended bisbenzenetriazolate linkers exhibit coordinatively unsaturated metal sites that are responsible for high and reversible uptake of ammonia. Isostructural Mn, Co, and Ni materials adsorb 15.47, 12.00, and 12.02 mmol of NH3/g, respectively, at STP. Importantly, these near-record capacities are reversible for at least three cycles. These results demonstrate that azolate MOFs are sufficiently thermally and chemically stable to find uses in recyclable sorption, storage, and potentially separation of chemically challenging and/or corrosive gases, especially when designed to exhibit a high density of open metal sites.
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Cited by
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Metal–Organic Frameworks against Toxic Chemicals
Islamoglu, T., Chen, Z., Wasson, M. C., Buru, C. T., Kirlikovali, K. O., Afrin, U., Mian, M. R., & Farha, O. K. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00828 · Cited by 707
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Construction and application of base-stable MOFs: a critical review
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Metadata
- Authors
- Rieth, A. J., Tulchinsky, Y., & Dincă, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-07-22
- Volume
- 138
- Issue
- 30
- Pages
- 9401-9404
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2475371080
- Cited by
- 305
- References
- 26
- FWCI
- 10.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rieth, A. J., Tulchinsky, Y., & Dincă, M. (2016). High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b05723
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