The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Controlled Gas Uptake in Metal–Organic Frameworks with Record Ammonia Sorption
Abstract
Ammonia is a vital commodity in our food supply chain, but its toxicity and corrosiveness require advanced protection and mitigation. These needs are not met efficiently by current materials, which suffer from either low capacity or low affinity for NH 3 . Here, we report that a series of microporous triazolate metal–organic frameworks containing open metal sites exhibit record static and dynamic ammonia capacities. Under equilibrium conditions at 1 bar, the materials adsorb up to 19.79 mmol NH 3 g –1, more than twice the capacity of activated carbon, the industry standard. Under conditions relevant to personal protection equipment, capacities reach 8.56 mmol g –1, 27% greater than the previous best material. Structure–function relationships and kinetic analyses of NH 3 uptake in isostructural micro- and mesoporous materials made from Co, Ni, and Cu reveal stability trends that are in line with the water substitution rates in simple metal–aquo complexes. Altogether, these results provide clear, intuitive descriptors that govern the static and dynamic uptake, kinetics, and stability of MOF sorbents for strongly interacting gases.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Barrett, E. P., Joyner, L. G., & Halenda, P. P. (1951) · Journal of the American Chemical Society · doi:10.1021/ja01145a126 · Cited by 13,172
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., & Margiolaki, I. (2005) · Science · doi:10.1126/science.1116275 · Cited by 5,430
Managing nitrogen for sustainable development.
Zhang, X., Davidson, E. A., Mauzerall, D. L., Searchinger, T. D., Dumas, P., & Shen, Y. (2015) · Nature · doi:10.1038/nature15743 · Cited by 3,054
Large-Pore Apertures in a Series of Metal-Organic Frameworks
Deng, H., Grunder, S., Cordova, K. E., Valente, C., Furukawa, H., Hmadeh, M., Gándara, F., Whalley, A. C., Liu, Z., Asahina, S., et al. (2012) · Science · doi:10.1126/science.1220131 · Cited by 2,126
Kruk, M., Jaroniec, M., & Sayari, A. (1997) · Langmuir · doi:10.1021/la970776m · Cited by 1,428
Exceptional ammonia uptake by a covalent organic framework
Doonan, C. J., Tranchemontagne, D. J., Glover, T. G., Hunt, J. R., & Yaghi, O. M. (2010) · Nature Chemistry · doi:10.1038/nchem.548 · Cited by 999
Metal-organic frameworks with high capacity and selectivity for harmful gases
Britt, D., Tranchemontagne, D., & Yaghi, O. M. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0804900105 · Cited by 958
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
Kim, M., Cahill, J. F., Fei, H., Prather, K. A., & Cohen, S. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3079219 · Cited by 809
Dietzel, P. D. C., Panella, B., Hirscher, M., Blom, R., & Fjellvåg, H. (2006) · Chemical Communications · doi:10.1039/b515434k · Cited by 659
MOF-74 building unit has a direct impact on toxic gas adsorption
Grant Glover, T., Peterson, G. W., Schindler, B. J., Britt, D., & Yaghi, O. (2011) · Chemical Engineering Science · doi:10.1016/j.ces.2010.10.002 · Cited by 617
Cited by
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
Rieth, A. J., Wright, A. M., & Dincă, M. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0140-1 · Cited by 402
Self-citationRole of hydrogen bonding in the capture and storage of ammonia in zeolites
Matito-Martos, I., Martin-Calvo, A., Ania, C. O., Parra, J. B., Vicent-Luna, J. M., & Calero, S. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.124062 · Cited by 68
Metadata
- Authors
- Rieth, A. J., & Dincă, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-02-09
- Volume
- 140
- Issue
- 9
- Pages
- 3461-3466
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2788765414
- Cited by
- 336
- References
- 42
- FWCI
- 13.53
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Controlled Gas Uptake in Metal–Organic Frameworks with Record Ammonia Sorption. https://app.cochat.ai/papers/10.1021/jacs.8b00313
- The paper
- Rieth, A. J., & Dincă, M. (2018). Controlled Gas Uptake in Metal–Organic Frameworks with Record Ammonia Sorption. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b00313
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
