The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Circularly Polarized Luminescence by Visible-Light Absorption in a Chiral O-BODIPY Dye: Unprecedented Design of CPL Organic Molecules from Achiral Chromophores
Open accessAbstract
Circularly polarized luminescence (CPL) in simple (small, nonaggregated, nonpolymeric) O-BODIPYs (R)-1 and (S)-1 by irradiation with visible light is first detected as proof of the ability of a new structural design to achieve CPL from inherently achiral monochromophore systems in simple organic molecules. The measured level of CPL (|g(lum)|) in solution falls into the usual range of that obtained from other simple organic molecules (10(-5)-10(-2) range), but the latter having more complex architectures since axially chiral chromophores or multichromophore systems are usually required. The new design is based on chirally perturbing the acting achiral chromophore by orthogonally tethering a single axially chiral 1,1'-binaphtyl moiety to it. The latter does not participate as a chromophore in the light-absorption/emission phenomenon. This simple design opens up new perspectives for the future development of new small-sized CPL organic dyes (e.g., those based on other highly luminescent achiral chromophores and/or chirally perturbing moieties), as well as for the improvement of the CPL properties of the organic molecules spanning their use in photonic applications.
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Cites
BODIPY Dyes and Their Derivatives: Syntheses and Spectroscopic Properties
Loudet, A., & Burgess, K. (2007) · Chemical Reviews · doi:10.1021/cr078381n · Cited by 5,238
BODIPY dyes in photodynamic therapy
Kamkaew, A., Lim, S. H., Lee, H. B., Kiew, L. V., Chung, L. Y., & Burgess, K. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35216h · Cited by 2,104
Absolute Asymmetric Synthesis: The Origin, Control, and Amplification of Chirality
Feringa, B. L., & van Delden, R. A. (1999) · Angewandte Chemie International Edition · doi:10.1002/(sici)1521-3773(19991203)38:23<3418::aid-anie3418>3.0.co;2-v
Cited by
Recent Progress on Circularly Polarized Luminescent Materials for Organic Optoelectronic Devices
Han, J., Guo, S., Lu, H., Liu, S., Zhao, Q., & Huang, W. (2018) · Advanced Optical Materials · doi:10.1002/adom.201800538 · Cited by 757
Tanaka, H., Inoue, Y., & Mori, T. (2018) · ChemPhotoChem · doi:10.1002/cptc.201800015 · Cited by 729
Synthesis of BODIPY dyes through postfunctionalization of the boron dipyrromethene core
Boens, N., Verbelen, B., Ortiz, M. J., Jiao, L., & Dehaen, W. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213024 · Cited by 396
Self-citationNovel properties and applications of carbon nanodots
Xiao, L., & Sun, H. (2018) · Nanoscale Horizons · doi:10.1039/c8nh00106e · Cited by 359
Xiong, J.-B., Feng, H.-T., Sun, J.-P., Xie, W.-Z., Yang, D., Liu, M., & Zheng, Y.-S. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07087 · Cited by 286
Metadata
- Authors
- Sánchez-Carnerero, E. M., Moreno, F., Maroto, B. L., Agarrabeitia, A. R., Ortiz, M. J., Vo, B. G., Muller, G., & Moya, S. D. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-02-21
- Volume
- 136
- Issue
- 9
- Pages
- 3346-3349
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2039204500
- Cited by
- 410
- References
- 3
- FWCI
- 15.19
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Sánchez-Carnerero, E. M., Moreno, F., Maroto, B. L., Agarrabeitia, A. R., Ortiz, M. J., Vo, B. G., Muller, G., & Moya, S. D. L. (2014). Circularly Polarized Luminescence by Visible-Light Absorption in a Chiral O-BODIPY Dye: Unprecedented Design of CPL Organic Molecules from Achiral Chromophores. Journal of the American Chemical Society. https://doi.org/10.1021/ja412294s
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