B-Doped Pd Catalyst: Boosting Room-Temperature Hydrogen Production from Formic Acid–Formate Solutions

Prospects of CO 2 Utilization via Direct Heterogeneous Electrochemical Reduction

Whipple, D. T., & Kenis, P. J. A. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1012627 · Cited by 1,419 · see citing works

Platinum-Based Nanostructured Materials: Synthesis, Properties, and Applications

Chen, A., & Holt-Hindle, P. (2010) · Chemical Reviews · doi:10.1021/cr9003902 · Cited by 1,390 · see citing works

Formic acid as a hydrogen source – recent developments and future trends

Grasemann, M., & Laurenczy, G. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21928j · Cited by 1,229 · see citing works

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

Tedsree, K., Li, T., Jones, S., Chan, C. W. A., Yu, K. M. K., Bagot, P. A. J., Marquis, E. A., Smith, G. D. W., & Tsang, S. C. E. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2011.42 · Cited by 1,150 · see citing works

Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives

Carenco, S., Portehault, D., Boissière, C., Mézailles, N., & Sánchez, C. (2013) · Chemical Reviews · doi:10.1021/cr400020d · Cited by 1,067 · see citing works

Liquid-phase chemical hydrogen storage materials

Yadav, M., & Xü, Q. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22937d · Cited by 842 · see citing works

Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage

Gu, X., Lu, Z., Jiang, H., Akita, T., & Xü, Q. (2011) · Journal of the American Chemical Society · doi:10.1021/ja200122f · Cited by 812 · see citing works

A Viable Hydrogen‐Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst

Fellay, C., Dyson, P. J., & Laurenczy, G. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200800320 · Cited by 623 · see citing works

The oxidation of formic acid at noble metal electrodes Part III. Intermediates and mechanism on platinum electrodes

Capon, A., & Parsons, R. (1973) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(73)80158-5 · Cited by 585 · see citing works

Electronic Structures of Pt−Co and Pt−Ru Alloys for CO-Tolerant Anode Catalysts in Polymer Electrolyte Fuel Cells Studied by EC−XPS

Wakisaka, M., Mitsui, S., Hirose, Y., Kawashima, K., Uchida, H., & Watanabe, M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0653510 · Cited by 534 · see citing works

Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions

Bi, Q., Du, X., Liu, Y., Cao, Y., He, H., & Fan, K. (2012) · Journal of the American Chemical Society · doi:10.1021/ja301696e · Cited by 440 · see citing works

Light at the interface: the potential of attenuated total reflection infrared spectroscopy for understanding heterogeneous catalysis in water

Mojet, B. L., Ebbesen, S. D., & Lefferts, L. (2010) · Chemical Society Reviews · doi:10.1039/c0cs00014k · Cited by 421 · see citing works

Pd and Pd–Ag Nanoparticles within a Macroreticular Basic Resin: An Efficient Catalyst for Hydrogen Production from Formic Acid Decomposition

Mori, K., Dojo, M., & Yamashita, H. (2013) · ACS Catalysis · doi:10.1021/cs400148n · Cited by 386 · see citing works

Monodisperse AgPd Alloy Nanoparticles and Their Superior Catalysis for the Dehydrogenation of Formic Acid

Zhang, S., Metin, Ö., Su, D., & Sun, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201300276 · Cited by 386 · see citing works

An Efficient CoAuPd/C Catalyst for Hydrogen Generation from Formic Acid at Room Temperature

Wang, Z., Yan, J., Ping, Y., Wang, H., Zheng, W., & Jiang, Q. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301009 · Cited by 369 · see citing works

Iron-Catalyzed Hydrogen Production from Formic Acid

Boddien, A., Loges, B., Gärtner, F., et al. (2010) · Journal of the American Chemical Society · doi:10.1021/ja100925n · Cited by 365 · see citing works

High-quality hydrogen from the catalyzed decomposition of formic acid by Pd–Au/C and Pd–Ag/C

Zhou, X., Huang, Y. J., Xing, W., Liu, C., Liao, J., & Lu, T. (2008) · Chemical Communications · doi:10.1039/b803661f · Cited by 355 · see citing works

Formic Acid Dehydrogenation on Au‐Based Catalysts at Near‐Ambient Temperatures

Ojeda, M., & Iglesia, E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200805723 · Cited by 318 · see citing works

Importance of Acid–Base Equilibrium in Electrocatalytic Oxidation of Formic Acid on Platinum

Joo, J., Uchida, T., Cuesta, Á., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403578s · Cited by 270 · see citing works

Formic Acid Oxidation at Pt/H2O Interface from Periodic DFT Calculations Integrated with a Continuum Solvation Model

Wang, H.-F., & Liu, Z. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp9059888 · Cited by 251 · see citing works

From HCOOH to CO at Pd Electrodes: A Surface-Enhanced Infrared Spectroscopy Study

Wang, J., Zhang, H.-X., Jiang, K. P., & Cai, W. (2011) · Journal of the American Chemical Society · doi:10.1021/ja205747j · Cited by 251 · see citing works

Sodium hydroxide-assisted growth of uniform Pd nanoparticles on nanoporous carbon MSC-30 for efficient and complete dehydrogenation of formic acid under ambient conditions

Zhu, Q., Tsumori, N., & Xü, Q. (2013) · Chemical Science · doi:10.1039/c3sc52448e · Cited by 241 · see citing works

Novel PdAu@Au/C Core−Shell Catalyst: Superior Activity and Selectivity in Formic Acid Decomposition for Hydrogen Generation

Huang, Y. J., Zhou, X., Yin, M., et al. (2010) · Chemistry of Materials · doi:10.1021/cm101285f · Cited by 240 · see citing works

Selective Formic Acid Decomposition for High‐Pressure Hydrogen Generation: A Mechanistic Study

Fellay, C., Yan, N., Dyson, P. J., et al. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200801824 · Cited by 238 · see citing works

Monodisperse gold–palladium alloy nanoparticles and their composition-controlled catalysis in formic acid dehydrogenation under mild conditions

Metin, Ö., Sun, X., & Sun, S. (2012) · Nanoscale · doi:10.1039/c2nr33637e · Cited by 224 · see citing works

Theoretical Elucidation of the Competitive Electro-oxidation Mechanisms of Formic Acid on Pt(111)

Gao, W., Keith, J. A., Anton, J., & Jacob, T. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1083317 · Cited by 224 · see citing works

Mechanism of the Electrocatalytic Oxidation of Formic Acid on Metals

Cuesta, Á., Cabello, G., Osawa, M., et al. (2012) · ACS Catalysis · doi:10.1021/cs200661z · Cited by 218 · see citing works

Pd/C Synthesized with Citric Acid: An Efficient Catalyst for Hydrogen Generation from Formic Acid/Sodium Formate

Wang, Z., Yan, J., Wang, H.-L., Ping, Y., & Jiang, Q. (2012) · Scientific Reports · doi:10.1038/srep00598 · Cited by 203 · see citing works

Amine-Functionalized MIL-125 with Imbedded Palladium Nanoparticles as an Efficient Catalyst for Dehydrogenation of Formic Acid at Ambient Temperature

Martis, M., Mori, K., Fujiwara, K., Ahn, W., & Yamashita, H. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp4069027 · Cited by 196 · see citing works

Boron-Doped Palladium Nanoparticles on Carbon Black as a Superior Catalyst for Formic Acid Electro-oxidation

Wang, J., Kang, Y., Yang, H. X., & Cai, W. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp900349g · Cited by 170 · see citing works

Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support

Solymosi, F., Koós, Á., Liliom, N., et al. (2011) · Journal of Catalysis · doi:10.1016/j.jcat.2011.01.023 · Cited by 134 · see citing works

Ag0.1-Pd0.9/rGO: an efficient catalyst for hydrogen generation from formic acid/sodium formate

Ping, Y., Yan, J., Wang, Z., Wang, H.-L., & Jiang, Q. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta12724a · Cited by 131 · see citing works

Prominent Electronic and Geometric Modifications of Palladium Nanoparticles by Polymer Stabilizers for Hydrogen Production under Ambient Conditions

Jones, S., Qu, J., Tedsree, K., et al. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201206035 · Cited by 131 · see citing works

Available hydrogen from formic acid decomposed by rare earth elements promoted Pd‐Au/C catalysts at low temperature

Zhou, X., Huang, Y. J., Liu, C., et al. (2010) · ChemSusChem · doi:10.1002/cssc.201000199 · Cited by 114 · see citing works

Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium

Bulushev, D. A., Jia, L., Beloshapkin, S. A., et al. (2012) · Chemical Communications · doi:10.1039/c2cc31027a · Cited by 109 · see citing works

Combined Surface-Enhanced Infrared Spectroscopy and First-Principles Study on Electro-Oxidation of Formic Acid at Sb-Modified Pt Electrodes

Peng, B., Wang, H.-F., Liu, Z., & Cai, W. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp910497n · Cited by 94 · see citing works

In situ spectroscopic investigation of CO accumulation and poisoning on Pd black surfaces in concentrated HCOOH

Zhang, H.-X., Wang, S.-H., Jiang, K. P., et al. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.10.033 · Cited by 92 · see citing works

Low activation energy dehydrogenation of aqueous formic acid on platinum–ruthenium–bismuth oxide at near ambient temperature and pressure

Ting, S.-W., Cheng, S., Tsang, K.-Y., et al. (2009) · Chemical Communications · doi:10.1039/b916507j · Cited by 84 · see citing works

A Novel Example of Molecular Hydrogen Generation from Formic Acid at Visible-Light-Responsive Photocatalyst

Kakuta, S., & Abe, T. (2009) · ACS Applied Materials & Interfaces · doi:10.1021/am900707e · Cited by 61 · see citing works

Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway

Min, X., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511890h · Cited by 541 · see citing works

Boosting Formate Production in Electrocatalytic CO ₂ Reduction over Wide Potential Window on Pd Surfaces

Jiang, B., Zhang, X.-G., Jiang, K., Wu, D.-Y., & Cai, W.-B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12506 · Cited by 402 · see citing works

Subnanometric Hybrid Pd-M(OH)2, M = Ni, Co, Clusters in Zeolites as Highly Efficient Nanocatalysts for Hydrogen Generation

Sun, Q., Wang, N., Bing, Q., Si, R., Liu, J., Bai, R., Zhang, P., Jia, M., & Yu, J. (2017) · Chem · doi:10.1016/j.chempr.2017.07.001 · Cited by 303 · see citing works

Interstitial boron-triggered electron-deficient Os aerogels for enhanced pH-universal hydrogen evolution

Li, Y., Peng, C.-K., Hu, H., Chen, S.-Y., Choi, J.-H., Lin, Y.-G., & Lee, J.-M. (2022) · Nature Communications · doi:10.1038/s41467-022-28805-8 · Cited by 291 · see citing works

Tandem Nitrogen Functionalization of Porous Carbon: Toward Immobilizing Highly Active Palladium Nanoclusters for Dehydrogenation of Formic Acid

Li, Z., Yang, X., Tsumori, N., Liu, Z., Himeda, Y., Autrey, T., & Xu, Q. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00053 · Cited by 216 · see citing works

Formic Acid-Based Liquid Organic Hydrogen Carrier System with Heterogeneous Catalysts

Zhong, H., Iguchi, M., Chatterjee, M., Himeda, Y., Xu, Q., & Kawanami, H. (2018) · Advanced Sustainable Systems · doi:10.1002/adsu.201700161 · Cited by 209 · see citing works

Nanoceria supported palladium(0) nanoparticles: Superb catalyst in dehydrogenation of formic acid at room temperature

Akbayrak, S., Tonbul, Y., & Özkar, S. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.01.063 · Cited by 134 · see citing works

Controllable Increase of Boron Content in B-Pd Interstitial Nanoalloy To Boost the Oxygen Reduction Activity of Palladium

Li, J., Chen, J., Wang, Q., Cai, W.-B., & Chen, S. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b03732 · Cited by 112 · see citing works

Enhancing H2 evolution by optimizing H adatom combination and desorption over Pd nanocatalyst

Wang, J., Tan, H., Jiang, D., & Zhou, K. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.02.001 · Cited by 54 · see citing works

Dehydrogenation of Formic Acid at Room Temperature: Boosting Palladium Nanoparticle Efficiency by Coupling with Pyridinic-Nitrogen-Doped Carbon

Bi, Q., Lin, J., Liu, Y., He, H., Huang, F., & Cao, Y. (2016) · Angewandte Chemie · doi:10.1002/ange.201605961 · Cited by 44 · see citing works

Photooxidation of Formic Acid vs Formate and Ethanol vs Ethoxy on TiO2 and Effect of Adsorbed Water on the Rates of Formate and Formic Acid Photooxidation

Liao, L.-F., Wu, W.-C., Chen, C., et al. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp003541j · Cited by 147 · see citing works

Formic acid–Formate blended solution: A new fuel system with high oxidation activity

Gao, Y., Tan, C. H., Li, Y., Guo, J., & Zhang, S. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.11.077 · Cited by 39 · see citing works

Adsorption of Formate and Its Role as Intermediate in Formic Acid Oxidation on Platinum Electrodes

Grozovski, V., Vidal‐Iglesias, F. J., Herrero, E., et al. (2011) · ChemPhysChem · doi:10.1002/cphc.201100257 · Cited by 85 · see citing works

CO2 hydrogenation to formic acid on Ni(110)

Peng, G., Sibener, S. J., Schatz, G. C., & Mavrikakis, M. (2012) · Surface Science · doi:10.1016/j.susc.2012.02.027 · Cited by 100 · see citing works

Formic acid oxidation on platinum: a simple mechanistic study

Schwarz, K., Sundararaman, R., Moffat, T. P., et al. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03045e · Cited by 70 · see citing works