Enhancing H2 evolution by optimizing H adatom combination and desorption over Pd nanocatalyst

Trends in the exchange current for hydrogen evolution

Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121 · see citing works

MoS ₂ Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction

Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001 · see citing works

Biomimetic Hydrogen Evolution:  MoS ₂ Nanoparticles as Catalyst for Hydrogen Evolution

Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065 · see citing works

Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces

Kitchin, J. R., Nørskov, J. K., Barteau, M. A., & Chen, J. G. (2004) · Physical Review Letters · doi:10.1103/physrevlett.93.156801 · Cited by 1,491 · see citing works

Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO

Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,379 · see citing works

Formic acid as a hydrogen source – recent developments and future trends

Grasemann, M., & Laurenczy, G. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21928j · Cited by 1,229 · see citing works

Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces

Sheng, W., Myint, M., Chen, J. G., & Yan, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00045a · Cited by 1,202 · see citing works

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

Tedsree, K., Li, T., Jones, S., Chan, C. W. A., Yu, K. M. K., Bagot, P. A. J., Marquis, E. A., Smith, G. D. W., & Tsang, S. C. E. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2011.42 · Cited by 1,150 · see citing works

Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy

Sheng, W., Zhuang, Z., Gao, M., Zheng, J., Chen, J. G., & Yan, Y. (2015) · Nature Communications · doi:10.1038/ncomms6848 · Cited by 1,136 · see citing works

Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles

Gao, D., Zhou, H., Wang, J., Miao, S., Yang, F., Wang, G., Wang, J., & Bao, X. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00046 · Cited by 1,096 · see citing works

Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications

Chen, A., & Ostrom, C. K. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00324 · Cited by 885 · see citing works

Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage

Zhu, Q.-L., & Xu, Q. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03690e · Cited by 657 · see citing works

Size effects on the hydrogen storage properties of nanostructured metal hydrides: A review

Bérubé, V., Radtke, G., Dresselhaus, M. S., & Chen, G. (2007) · International Journal of Energy Research · doi:10.1002/er.1284 · Cited by 652 · see citing works

Surface Polarization Matters: Enhancing the Hydrogen‐Evolution Reaction by Shrinking Pt Shells in Pt–Pd–Graphene Stack Structures

Bai, S., Wang, C., Deng, M., Gong, M., Bai, Y., Jiang, J., & Xiong, Y. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406468 · Cited by 517 · see citing works

A review on exergy comparison of hydrogen production methods from renewable energy sources

Koroneos, C. J., & Dimitrios, R. (2012) · Energy & Environmental Science · doi:10.1039/c2ee01098d · Cited by 471 · see citing works

B-Doped Pd Catalyst: Boosting Room-Temperature Hydrogen Production from Formic Acid–Formate Solutions

Jiang, K., Xu, K., Zou, S., & Cai, W.-B. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5008917 · Cited by 434 · see citing works

Hydrogen Evolution Over Bimetallic Systems: Understanding the Trends

Greeley, J., Nørskov, J. K., Kibler, L. A., Abdel-Aziz, A. M., & Kolb, D. M. (2006) · ChemPhysChem · doi:10.1002/cphc.200500663 · Cited by 395 · see citing works

Dissociative hydrogen adsorption on palladium requires aggregates of three or more vacancies

Mitsui, T., Rose, M. K., Fomin, E. V., Ogletree, D. F., & Salmerón, M. (2003) · Nature · doi:10.1038/nature01557 · Cited by 325 · see citing works

Evidence for ‘‘subsurface’’ hydrogen on Pd(110): An intermediate between chemisorbed and dissolved species

Behm, R. J., Penka, V., Cattania, M. G., Christmann, K., & Ertl, G. (1983) · The Journal of Chemical Physics · doi:10.1063/1.444739 · Cited by 317 · see citing works

CO2‐“Neutral” Hydrogen Storage Based on Bicarbonates and Formates

Boddien, A., Gärtner, F., Federsel, C., Sponholz, P., Mellmann, D., Jackstell, R., Junge, H., & Beller, M. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101995 · Cited by 308 · see citing works

Structure sensitivity and kinetics of ?-glucose oxidation to ?-gluconic acid over carbon-supported gold catalysts

Önal, Y. (2004) · Journal of Catalysis · doi:10.1016/j.jcat.2004.01.010 · Cited by 269 · see citing works

Layered Platinum Dichalcogenides (PtS2, PtSe2, and PtTe2) Electrocatalysis: Monotonic Dependence on the Chalcogen Size

Chia, X.-Y., Adriano, A., Lazar, P., Sofer, Z., Luxa, J., & Pumera, M. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201505402 · Cited by 264 · see citing works

Immobilizing Extremely Catalytically Active Palladium Nanoparticles to Carbon Nanospheres: A Weakly-Capping Growth Approach

Zhu, Q., Tsumori, N., & Xü, Q. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06707 · Cited by 245 · see citing works

Smaller is Faster and More Sensitive: The Effect of Wire Size on the Detection of Hydrogen by Single Palladium Nanowires

Yang, F., Kung, S.-C., Cheng, M. H., Hemminger, J. C., & Penner, R. M. (2010) · ACS Nano · doi:10.1021/nn101475c · Cited by 241 · see citing works

Sodium hydroxide-assisted growth of uniform Pd nanoparticles on nanoporous carbon MSC-30 for efficient and complete dehydrogenation of formic acid under ambient conditions

Zhu, Q., Tsumori, N., & Xü, Q. (2013) · Chemical Science · doi:10.1039/c3sc52448e · Cited by 241 · see citing works

Trends in Formic Acid Decomposition on Model Transition Metal Surfaces: A Density Functional Theory study

Herron, J. A., Scaranto, J., Ferrin, P. A., Li, S., & Mavrikakis, M. (2014) · ACS Catalysis · doi:10.1021/cs500737p · Cited by 231 · see citing works

Controlling Hydrogen Activation, Spillover, and Desorption with Pd–Au Single-Atom Alloys

Lucci, F. R., Darby, M. T., Mattera, M. F. G., Ivimey, C. J., Therrien, A. J., Michaelides, A., Stamatakis, M., & Sykes, E. C. H. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b02400 · Cited by 224 · see citing works

Thermodynamics of the hybrid interaction of hydrogen with palladium nanoparticles

Griessen, R., Strohfeldt, N., & Giessen, H. W. (2015) · Nature Materials · doi:10.1038/nmat4480 · Cited by 223 · see citing works

A Comparison of the Adsorption and Diffusion of Hydrogen on the {111} Surfaces of Ni, Pd, and Pt from Density Functional Theory Calculations

Watson, G. W., Wells, R. P. K., Willock, D. J., & Hutchings, G. J. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp002864c · Cited by 222 · see citing works

Hydride formation thermodynamics and hysteresis in individual Pd nanocrystals with different size and shape

Alekseeva, S., Wadell, C., Nugroho, F. A. A., Gschneidtner, T. A., Fernandez, Y. A. D., Nalin, G., Świtlik, D., Westerlund, F., Antosiewicz, T. J., Zhdanov, V. P., et al. (2015) · Nature Materials · doi:10.1038/nmat4409 · Cited by 206 · see citing works

Pd/C Synthesized with Citric Acid: An Efficient Catalyst for Hydrogen Generation from Formic Acid/Sodium Formate

Wang, Z., Yan, J., Wang, H.-L., Ping, Y., & Jiang, Q. (2012) · Scientific Reports · doi:10.1038/srep00598 · Cited by 203 · see citing works

Size Dependence of the Adsorption Energy of CO on Metal Nanoparticles: A DFT Search for the Minimum Value

Yudanov, I. V., Genest, A., Schauermann, S., Freund, H., & Rösch, N. (2012) · Nano Letters · doi:10.1021/nl300515z · Cited by 192 · see citing works

An Aqueous Rechargeable Formate‐Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis

Bi, Q., Lin, J., Liu, Y., Du, X., Wang, J., He, H., & Cao, Y. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201409500 · Cited by 183 · see citing works

Highly Efficient Hydrogen Storage System Based on Ammonium Bicarbonate/Formate Redox Equilibrium over Palladium Nanocatalysts

Su, J., Yang, L., Lu, M., & Lin, H. (2015) · ChemSusChem · doi:10.1002/cssc.201403251 · Cited by 180 · see citing works

A Study on the Formation of Palladium Hydride in a Carbon-Supported Palladium Catalyst

Nag, N. K. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp004535q · Cited by 165 · see citing works

H2 dissociative adsorption on Pd(111)

Dong, W., & Hafner, J. (1997) · Physical review. B, Condensed matter · doi:10.1103/physrevb.56.15396 · Cited by 161 · see citing works

Three-Site Model for Hydrogen Adsorption on Supported Platinum Particles: Influence of Support Ionicity and Particle Size on the Hydrogen Coverage

Oudenhuijzen, M. K., van Bokhoven, J. A., Miller, J. T., Ramaker, D. E., & Koningsberger, D. C. (2005) · Journal of the American Chemical Society · doi:10.1021/ja045286c · Cited by 155 · see citing works

Ultra-small yellow defective TiO2 nanoparticles for co-catalyst free photocatalytic hydrogen production

Wu, Q., Huang, F. H., Zhao, M., Xu, J., Zhou, J., & Wang, Y. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.004 · Cited by 154 · see citing works

Performance of shape-controlled Pd nanoparticles in the selective hydrogenation of acetylene

Kim, S. K., Kim, C., Lee, J. H., Kim, J.-Y., Lee, H., & Moon, S. H. (2013) · Journal of Catalysis · doi:10.1016/j.jcat.2013.06.018 · Cited by 151 · see citing works

A Charge/Discharge Device for Chemical Hydrogen Storage and Generation

Papp, G., Csorba, J., Laurenczy, G., & Joó, F. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201104951 · Cited by 145 · see citing works

The Size Dependence of Hydrogen Mobility and Sorption Kinetics for Carbon‐Supported MgH 2 Particles

Au, Y. S., Obbink, M. K., Srinivasan, S., Magusin, P. C. M. M., de Jong, K. P., & de Jongh, P. E. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201304060 · Cited by 135 · see citing works

Hydrogen adsorption and diffusion on Pd(111)

Mitsui, T., Rose, M. K., Fomin, E. V., Ogletree, D. F., & Salmerón, M. (2003) · Surface Science · doi:10.1016/s0039-6028(03)00822-7 · Cited by 134 · see citing works

Supported Metal Oxide Nanosystems for Hydrogen Photogeneration: Quo Vadis?

Barreca, D., Carraro, G., Gombac, V., Gasparotto, A., Maccato, C., Fornasiero, P., & Tondello, E. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201100242 · Cited by 131 · see citing works

Insights into the Preference of CO2Formation from HCOOH Decomposition on Pd Surface: A Theoretical Study

Zhang, R., Liu, H., Wang, B., & Ling, L. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp211900z · Cited by 130 · see citing works

Understanding Strain and Ligand Effects in Hydrogen Evolution over Pd(111) Surfaces

Maark, T. A., & Peterson, A. A. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp4121035 · Cited by 130 · see citing works

Hydrodeoxygenation of vanillin as a bio-oil model over carbonaceous microspheres-supported Pd catalysts in the aqueous phase and Pickering emulsions

Zhu, Z., Tan, H., Wang, J., Yu, S., & Zhou, K. (2014) · Green Chemistry · doi:10.1039/c3gc42647e · Cited by 125 · see citing works

Photocatalytic Hydrogen Evolution under Highly Basic Conditions by Using Ru Nanoparticles and 2-Phenyl-4-(1-naphthyl)quinolinium Ion

Yamada, Y., Miyahigashi, T., Kotani, H., Ohkubo, K., & Fukuzumi, S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206079e · Cited by 113 · see citing works

Characterization of Pd–Au/SiO2 Catalysts by X-ray Diffraction, Temperature-Programmed Hydride Decomposition, and Catalytic Probes

Bonarowska, M., Pielaszek, J., Juszczyk, W., & Karpiński, Z. (2000) · Journal of Catalysis · doi:10.1006/jcat.2000.2989 · Cited by 106 · see citing works

Reaction pathways derived from DFT for understanding catalytic decomposition of formic acid into hydrogen on noble metals

Hu, C., Ting, S.-W., Chan, K., & Huang, W. (2012) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2012.08.035 · Cited by 99 · see citing works

Efficient hydrogen production from formic acid using TiO 2 -supported AgPd@Pd nanocatalysts

Hattori, M., Einaga, H., Daio, T., & Tsuji, M. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06988a · Cited by 89 · see citing works

Model Approach in Heterogeneous Catalysis: Kinetics and Thermodynamics of Surface Reactions

Schauermann, S., & Freund, H. (2015) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00237 · Cited by 60 · see citing works

Hydrogen dissociative chemisorption and desorption on saturated subnano palladium clusters (Pdn, n = 2–9)

Zhou, C., Yao, S., Wu, J., Forrey, R. C., Chen, L., Tachibana, A., & Cheng, H. (2008) · Physical Chemistry Chemical Physics · doi:10.1039/b804877k · Cited by 57 · see citing works

Influence of the Work Function on Electron Transfer Processes at Metals: Application to the Hydrogen Evolution Reaction

Harinipriya, S., & Sangaranarayanan, M. V. (2002) · Langmuir · doi:10.1021/la025548t · Cited by 57 · see citing works

Adsorption and diffusion of hydrogen on Pd(211) and Pd(111): Results from first-principles electronic structure calculations

Hong, S., & Rahman, T. S. (2007) · Physical Review B · doi:10.1103/physrevb.75.155405 · Cited by 55 · see citing works

Modulating Photogenerated Electron Transfer and Hydrogen Production Rate by Controlling Surface Potential Energy on a Selectively Exposed Pt Facet on Pt/TiO2 for Enhancing Hydrogen Production

Cui, E., & Lü, G. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp4104933 · Cited by 52 · see citing works

Novel insight into the hydrogen absorption mechanism at the Pd(110) surface

Ohno, S., Wilde, M., & Fukutani, K. (2014) · The Journal of Chemical Physics · doi:10.1063/1.4869544 · Cited by 51 · see citing works

Preparation, characterization and performance of Pd/SiO2 catalyst for benzene catalytic hydrogenation

Boudjahem, A., Redjel, A., & Mokrane, T. (2011) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2011.11.038 · Cited by 50 · see citing works

Simultaneous Production of CH 4 and H 2 from Photocatalytic Reforming of Glucose Aqueous Solution on Sulfated Pd-TiO 2 Catalysts

Vaiano, V., Iervolino, G., Sarno, G., Sannino, D., Rizzo, L., Murcia, J. J., Hidalgo, M. C., & Navío, J. A. (2015) · Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles · doi:10.2516/ogst/2014062 · Cited by 42 · see citing works

A Viable Hydrogen Storage and Release System Based on Cesium Formate and Bicarbonate Salts: Mechanistic Insights into the Hydrogen Release Step

Sordakis, K., Dalebrook, A. F., & Laurenczy, G. (2015) · ChemCatChem · doi:10.1002/cctc.201500359 · Cited by 42 · see citing works

Pd/polyaniline(SiO2) a novel catalyst for the hydrogenation of 2-ethylanthraquinone

Drelinkiewicz, A., Waksmundzka-Góra, A., Makowski, W., & Stejskal, J. (2005) · Catalysis Communications · doi:10.1016/j.catcom.2005.02.009 · Cited by 40 · see citing works

Alkene hydrogenation on metal surfaces: Why and when are Pd overlayers more efficient catalysts than bulk Pd?

Valcárcel, A., Morfin, F., & Piccolo, L. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2009.02.023 · Cited by 40 · see citing works

DFT study on the adsorption and dissociation of H2 on Pdn (n=4, 6, 13, 19, 55) clusters

Liu, X., Tian, D., & Meng, C. (2014) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2014.09.078 · Cited by 39 · see citing works

Palladium-catalyzed selective hydrogenation of nitroarenes: Influence of platinum and iron on activity, particle morphology and formation of β-palladium hydride

Möbus, K., Grünewald, E., Wieland, S. D., Parker, S. F., & Albers, P. (2013) · Journal of Catalysis · doi:10.1016/j.jcat.2013.11.019 · Cited by 34 · see citing works

Role of nano in catalysis: Palladium catalyzed hydrogen desorption from nanosized magnesium hydride

Xie, W., West, D. J., Sun, Y., & Zhang, S. (2013) · Nano Energy · doi:10.1016/j.nanoen.2012.12.010 · Cited by 30 · see citing works

Uptake, transport, and release of hydrogen from Pd(100)

Michalak, W. D., Miller, J. B., Alfonso, D. R., & Gellman, A. J. (2011) · Surface Science · doi:10.1016/j.susc.2011.08.022 · Cited by 22 · see citing works

Hydrogen adsorption and dissociation on Pd19 cluster using density functional calculations

Zhao, Y. H., & Tian, D. (2012) · Computational and Theoretical Chemistry · doi:10.1016/j.comptc.2012.03.017 · Cited by 20 · see citing works

Energetics and dynamics of hydrogen adsorption, desorption and migration on a carbon-supported palladium cluster

Mushrif, S. H., Rey, A. D., & Peslherbe, G. H. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm01559h · Cited by 16 · see citing works

Sequential H2 Chemisorption and H Desorption on Icosahedral Pt13 and Pd13 Clusters: A Density Functional Theory Study

Zhou, C., Yao, S., Wu, J., Chen, L., Forrey, R. R., & Cheng, H. (2009) · Journal of Computational and Theoretical Nanoscience · doi:10.1166/jctn.2009.1181 · Cited by 14 · see citing works

Local and Extended Structures of d -(−)-Tartaric Acid on Pd(111)

Mahapatra, M., & Tysoe, W. T. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b11881 · Cited by 6 · see citing works

Towards Designing Stable Pd‐Based Membranes for Hydrogen Gas Separation: A Statistical Thermodynamics Approach

Nanu, D. E., & Böttger, A. (2008) · Advanced Functional Materials · doi:10.1002/adfm.200700501 · Cited by 5 · see citing works

Formic Acid-Based Liquid Organic Hydrogen Carrier System with Heterogeneous Catalysts

Zhong, H., Iguchi, M., Chatterjee, M., Himeda, Y., Xu, Q., & Kawanami, H. (2018) · Advanced Sustainable Systems · doi:10.1002/adsu.201700161 · Cited by 209 · see citing works

Understanding the effect of Pd size on formic acid dehydrogenation via size-controlled Pd/C catalysts prepared by NaBH4 treatment

Kim, Y., & Kim, D. H. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.12.008 · Cited by 168 · see citing works

Interstitial Hydrogen Atom Modulation to Boost Hydrogen Evolution in Pd-Based Alloy Nanoparticles

Fan, J., Cui, X., Yu, S., Gu, L., Zhang, Q., Meng, F., Peng, Z., Ma, L., Ma, J.-Y., Qi, K., et al. (2019) · ACS Nano · doi:10.1021/acsnano.9b05615 · Cited by 102 · see citing works

Mechanistic insights on aqueous formic acid dehydrogenation over Pd/C catalyst for efficient hydrogen production

Kim, Y., Kim, S., Ham, H. C., & Kim, D. H. (2020) · Journal of Catalysis · doi:10.1016/j.jcat.2020.06.033 · Cited by 93 · see citing works

Ultrafine Pd nanoparticles on amine-functionalized carbon nanotubes for hydrogen production from formic acid

Kim, Y., Lee, H., Yang, S., Lee, J., Kim, H. J., Hwang, S., Jeon, S. W., & Kim, D. H. (2021) · Journal of Catalysis · doi:10.1016/j.jcat.2021.10.007 · Cited by 67 · see citing works

Fe2P nanoparticles as highly efficient freestanding co-catalyst for photocatalytic hydrogen evolution

Pan, Z., Wang, R., Li, J., Iqbal, S., Liu, W., & Zhou, K. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.09.128 · Cited by 60 · see citing works

Hydrogen production from formic acid dehydrogenation over a Pd supported on N-doped mesoporous carbon catalyst: A role of nitrogen dopant

Kim, Y., & Kim, D. H. (2020) · Applied Catalysis A General · doi:10.1016/j.apcata.2020.117887 · Cited by 49 · see citing works

Size-Dependent Catalytic Cyclohexane Dehydrogenation with Platinum Nanoparticles on Nitrogen-Doped Carbon

Wang, J., Liu, H., Fan, S., Li, W., Li, Z., Yun, H., Xu, X., Guo, A., & Wang, Z. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c03085 · Cited by 48 · see citing works

Ultrafine PdAg alloy nanoparticles anchored on NH2-functionalized 2D/2D TiO2 nanosheet/rGO composite as efficient and reusable catalyst for hydrogen release from additive-free formic acid at room temperature

Zhao, X. M., Dai, P., Xu, D., Tao, X., Liu, X., & Ge, Q. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.11.018 · Cited by 48 · see citing works

Pd/UIO-66/sepiolite: Toward highly efficient dual-supported Pd-based catalyst for dehydrogenation of formic acid at room temperature

Zou, L., Chen, M., Zhang, Q., Mao, Q., Huang, Y., & Liang, Z. (2020) · Journal of Catalysis · doi:10.1016/j.jcat.2020.05.010 · Cited by 46 · see citing works

Space-Confined Carbon-Doped Pd Nanoparticles as a Highly Efficient Catalyst for Selective Phenol Hydrogenation

Yu, Q., Zhou, J. W., Wang, W., Li, D., Sun, X., & Wang, G. (2023) · ACS Catalysis · doi:10.1021/acscatal.2c05245 · Cited by 45 · see citing works

Pd–Co nanoalloys nested on CuO nanosheets for efficient electrocatalytic N 2 reduction and room-temperature Suzuki–Miyaura coupling reaction

Fu, W., Cao, Y., Feng, Q., Smith, W. R., Dong, P. T., Ye, M., & Shen, J. (2018) · Nanoscale · doi:10.1039/c8nr08724e · Cited by 45 · see citing works

Amine-functionalized sepiolite: Toward highly efficient palladium nanocatalyst for dehydrogenation of additive-free formic acid

Zhang, Q., Zhu, Z., Zhang, X., Li, P., Huang, Y., Luo, X. Y., & Liang, Z. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.04.266 · Cited by 44 · see citing works

Electroplating of surfactant-modified tin catalyst over a nickel foam electrode (Sn/Ni) for selective N2 yield from nitrate reduction as affected by Sn(200) and Sn(101) crystal facets

Shih, Y., & Wu, Z.-L. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119784 · Cited by 41 · see citing works

Nano PdFe Alloy Assembled Film as a Highly Efficient Electrocatalyst toward Hydrogen Evolution in Both Acid and Alkaline Solutions

Chen, H., Yuan, M.-X., Zhai, C., Tan, L., Cong, N., Han, J.-J., Fang, H., Zhou, X.-R., Ren, Z.-D., & Zhu, Y.-C. (2020) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c01410 · Cited by 28 · see citing works

Formate/bicarbonate interconversion for safe hydrogen storage: A review

Calabrese, M., Russo, D., Benedetto, A. D., Marotta, R., & Andreozzi, R. (2022) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2022.113102 · Cited by 39 · see citing works

Releasing Hydrogen at High Pressures from Liquid Carriers: Aspects for the H2Delivery to Fueling Stations

Müller, K., Brooks, K., & Autrey, T. S. (2018) · Energy & Fuels · doi:10.1021/acs.energyfuels.8b01724 · Cited by 37 · see citing works

Development of an Autothermal Formate-Based Hydrogen Generator: From Optimization of Formate Dehydrogenation Conditions to Thermal Integration with Fuel Cells

Hwang, Y. J., Kwon, Y., Kim, Y., Sohn, H., Nam, S. W., Kim, J., Autrey, T. S., Yoon, C. W., Jo, Y. S., & Jeong, H. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c02775 · Cited by 36 · see citing works

Synergetic coupling of Pd nanoparticles and amorphous MoS toward highly efficient electrocatalytic hydrogen evolution reactions

Liu, X.-Y., Gao, S.-Y., Yang, P., Wang, B., Ou, J., Liu, Z.-Q., & Wang, Y. (2018) · Applied Materials Today · doi:10.1016/j.apmt.2018.09.001 · Cited by 32 · see citing works

One-pot conversion of dimethyl terephthalate to 1,4-cyclohexanedimethanol

Xiao, X., Xin, H., Qi, Y., Zhao, C., Wu, P., & Li, X. (2022) · Applied Catalysis A General · doi:10.1016/j.apcata.2022.118510 · Cited by 34 · see citing works

Effect of Cu-ZSM-5 catalysts with different CuO particle size on selective catalytic oxidation of N,N-Dimethylformamide

Xin, X., Li, N., Liu, D., Cheng, J., & Hao, Z. (2022) · Frontiers of Environmental Science & Engineering · doi:10.1007/s11783-022-1557-0 · Cited by 33 · see citing works

Synthesis of ultrafine low loading Pd–Cu alloy catalysts supported on graphene with excellent electrocatalytic performance for formic acid oxidation

Wang, H., Chen, H., Wang, H., Ou, C., Li, R., & Liu, H. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.02.019 · Cited by 33 · see citing works

Synergetic effect between MoS2 and N, S- doped reduced graphene oxide supported palladium nanoparticles for hydrogen evolution reaction

Woldetinsay, M., Soreta, T. R., Femi, O. E., & Maiyalagan, T. (2020) · Materials Chemistry and Physics · doi:10.1016/j.matchemphys.2020.123106 · Cited by 33 · see citing works

Modified cellulose nanocrystals immobilized AuPd nanoalloy for formic acid dehydrogenation

Shen, J., Liang, Y., Wang, C., & Zhu, Y. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.144640 · Cited by 31 · see citing works

Palladium Supported on Porous Chitosan–Graphene Oxide Aerogels as Highly Efficient Catalysts for Hydrogen Generation from Formate

Anouar, A., Katir, N., El Kadib, A., Primo, A., & García, H. (2019) · Molecules · doi:10.3390/molecules24183290 · Cited by 30 · see citing works

PdO/Pd 0 /TiO 2 Nanocatalysts Engineered by Flame Spray Pyrolysis: Study of the Synergy of PdO/Pd 0 on H 2 Production by HCOOH Dehydrogenation and the Deactivation Mechanism

Deligiannakis, Y. G., Tsikourkitoudi, V. P., Stathi, P., Wegner, K., Papavasiliou, J., & Louloudi, M. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c02399 · Cited by 29 · see citing works

Study of Non-Noble-Metal-Based Metal–Nitrogen–Carbon Catalysts for Formic Acid Dehydrogenation

Zhang, Q., Mao, Q., Zhou, Y., Zou, L., Zhu, D., Huang, Y., Gao, H., Luo, X. Y., Mao, Y., & Liang, Z. (2022) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c08630 · Cited by 28 · see citing works

Experimental and Theoretical Studies of Ultrafine Pd-Based Biochar Catalyst for Dehydrogenation of Formic Acid and Application of In Situ Hydrogenation

Zou, L., Liu, Q., Zhu, D., Huang, Y., Mao, Y., Luo, X. Y., & Liang, Z. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c00343 · Cited by 28 · see citing works

The rare earth doped Mg2Ni (0 1 0) surface enhances hydrogen storage

Gao, S., Zhang, S., Li, Y., Hu, R., Heng, Z., Shi, X., Jin, P., & Shui, J. (2022) · Applied Surface Science · doi:10.1016/j.apsusc.2022.156243 · Cited by 25 · see citing works

Hydrogen Production via Cerium-Promoted Dehydrogenation of Formic Acid Catalyzed by Carbon-Supported Palladium Nanoparticles

Kim, Y., Jang, G. H., & Kim, D. H. (2023) · ACS Applied Nano Materials · doi:10.1021/acsanm.3c00668 · Cited by 23 · see citing works

Using earth abundant materials for long duration energy storage: electro-chemical and thermo-chemical cycling of bicarbonate/formate

Gutiérrez, O. Y., Grubel, K., Kothandaraman, J., Lopez‐Ruiz, J. A., Brooks, K., Bowden, M., & Autrey, T. S. (2023) · Green Chemistry · doi:10.1039/d3gc00219e · Cited by 22 · see citing works

Synthesis of Quasi‐Bilayer Subnano Metal‐Oxide Interfacial Cluster Catalysts for Advanced Catalysis

Chen, S., Li, H., Sun, Z., Cao, L., Ying, W., Shi, X., Liu, W., Gu, J., Zheng, X., Zhu, J., et al. (2020) · Small · doi:10.1002/smll.202005571 · Cited by 16 · see citing works

Research Requirements to Move the Bar forward Using Aqueous Formate Salts as H2 Carriers for Energy Storage Applications

Grubel, K., Su, J., Kothandaraman, J., Brooks, K., Somorjai, G. A., & Autrey, T. S. (2020) · Journal of Energy and Power Technology · doi:10.21926/jept.2004016 · Cited by 14 · see citing works

Facile construction of a highly dispersed PdCo nanocatalyst supported on NH2-UiO-66-derived N/O co-doped carbon for hydrogen evolution from formic acid

Deng, M., Ma, J., Yang, C., Cao, T., Yao, M., Liu, F., Chen, H., & Wang, X. (2022) · Materials Today Chemistry · doi:10.1016/j.mtchem.2022.101001 · Cited by 13 · see citing works

Cuboidal Cu 2 O nanoparticles dispersed granular Mn 0. 05 Cd 0 . 95 S form a p‐n heterojunction for efficient photocatalytic hydrogen evolution

Wang, X., Cao, Y., & Jin, Z. (2021) · International Journal of Energy Research · doi:10.1002/er.6769 · Cited by 12 · see citing works

Modulation of the superficial electronic structure via metal–support interaction for H 2 evolution over Pd catalysts

Wang, J., Cheng, D., Gao, M., Li, Q., Xin, Y., Zhang, N., Zhang, Z., Yu, X., Zhao, Z., & Zhou, K. (2021) · Chemical Science · doi:10.1039/d0sc06795d · Cited by 10 · see citing works

Support-Dependent Formic Acid Dehydrogenation over Pd-Supported Catalysts Induced by Hydrogen Spillover

Kim, Y., & Kim, D. H. (2025) · Energy & Fuels · doi:10.1021/acs.energyfuels.5c03193 · Cited by 9 · see citing works

Elucidating the alloying effect of PdAg/CNT catalysts on formic acid dehydrogenation with kinetic isotope effect

Kim, Y., & Kim, D. H. (2023) · Molecular Catalysis · doi:10.1016/j.mcat.2023.113343 · Cited by 9 · see citing works

Dissecting the role of hydrogen pumping by rhenium oxide in enhancing the dehydrogenation of perhydro-dibenzyltoluene on Pt/Al2O3

Jang, J., Lee, M., Lee, S.-H., Jeong, E., Park, T. I., & Lee, K. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.164863 · Cited by 8 · see citing works

Enhanced Lewis acid-base synergistic photocatalyst for selective benzimidazole synthesis coupled with hydrogen evolution

Chen, X., Guo, H., Hu, Z., Dong, L., Shen, J., Zhu, Y., & Li, C. (2025) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2025.125982 · Cited by 8 · see citing works

Atomic {Pdn+-X} States at Nanointerfaces: Implications in Energy-Related Catalysis

Stathi, P., Solakidou, M., Zindrou, A., Belles, L., & Deligiannakis, Y. G. (2023) · Energies · doi:10.3390/en16020913 · Cited by 7 · see citing works

Cellulose nanocrystals supported ternary alloy nanoclusters catalysts for efficient hydrogen production from formic acid

Chen, K., Liang, Y., Hu, Z., & Shen, J. (2023) · Molecular Catalysis · doi:10.1016/j.mcat.2023.113742 · Cited by 6 · see citing works

The Golden Atomic Ratio in Binary Nanoalloys for Enhanced CO 2 Electroreduction: Dual-Metal Synergy of AgPd

Lü, G., Liu, S., Tang, Y., Yu, M., Wang, Z., Sui, P., Fu, X., Sun, Y., Liu, S., & Luo, J. (2025) · ACS Catalysis · doi:10.1021/acscatal.5c04933 · Cited by 4 · see citing works

Pd nanoparticles on functionalized carbon nanotubes for enhanced formic acid hydrogen production under ambient conditions

Yao, J., Zhao, Y., Liu, J., Chen, G., Yan, B., Cheng, Z., Qi, J., & Wang, L. (2024) · Surfaces and Interfaces · doi:10.1016/j.surfin.2024.104833 · Cited by 4 · see citing works

Direct synthesis of H 2 O 2 over Pd–M@HCS (M = Sn, Fe, Co, or Ni): effects of non-noble metal M on the electronic state and particle size of Pd

Wu, Q., Zhou, S., Fu, C., Zhang, J., Chen, B., Pan, H., & Lin, Q. (2022) · New Journal of Chemistry · doi:10.1039/d2nj01074g · Cited by 3 · see citing works

Preparation of Bi-functional hydrogen production/storage catalyst with Constructing Pd nanoparticles and amino functionalities on layered double hydroxide

Zou, L., Xiao, X., Zhong, X., Xiao, J., Huang, Y., & Liang, Z. (2025) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2025.150137 · Cited by 2 · see citing works

Hydrogen Production via Potassium Formate Hydrolysis on Metal–Organic Framework Supported Pd‐Based Catalysts

Li, K., Cai, T., Li, J., Dlamini, M. W., Sun, Z., & Sun, Z. (2025) · Energy Technology · doi:10.1002/ente.202500403 · Cited by 1 · see citing works

Water-Promoted Molar-Level Photocatalysis and Spontaneous Product Separation with Near-Unity Quantum Efficiency

Lu, Y., Luo, R., Leng, X., Huang, Y., Jiang, W., Besenbacher, F., Li, Y., Yin, W., & Su, R. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.5c15003 · Cited by 1 · see citing works

A Mesoporous Zirconium-Isophthalate Multifunctional PlatformPreprint

Wang, S., Chen, L., Wahiduzzaman, M., Tissot, A., Zhou, L., Ibarra, I. A., Gutiérrez‐Alejandre, A., Lee, J. S., Chang, J., Liu, Z., et al. (2020) · ChemRxiv · doi:10.26434/chemrxiv.12661310 · Cited by 1 · see citing works

Advances in Theoretical Studies on Solid Catalysts for Renewable Energy Production

Añez, R., & Sierraalta, A. (2017) · Advances in chemical and materials engineering book series · doi:10.4018/978-1-5225-3903-2.ch001

Synthesis, characterization and electrocatalytic study of Pd supported on CeO2–N, S-rGO composite towards hydrogen and oxygen evolution reaction

Woldetinsay, M., Soreta, T. R., Palani, K., Maiyalagan, T., & Femi, O. E. (2021) · Journal of Materials Science Materials in Electronics · doi:10.1007/s10854-021-05853-2

Recent Progress on Layered Double Hydroxides‐Based Nanomaterials for Solar Energy Conversion

Bai, S., Ning, C., Shen, T., & Song, Y. (2023) · doi:10.1002/9783527837991.ch16

Enhanced Hydrogen Production from Formic Acid Dehydrogenation Over B-Doped Carbon Nanotubes-Based Pd Nanoparticles Under Ambient ConditionsPreprint

Yao, J., Zhao, Y., Liu, J., Chen, G., Yan, B., Cheng, Z., & Qi, J. (2023) · SSRN Electronic Journal · doi:10.2139/ssrn.4583469

Solvent-Free Dehydrogenation of Decahydroquinoline over Palladium Nanoparticles Supported on Modified Ceria-Based Structures

Kirichenko, O. A., Shuvalova, E. V., Редина, Е. А., Ivanova, I. I., Kapustin, G. I., & Kustov, L. M. (2026) · Catalysts · doi:10.3390/catal16090835

Hydrogen Evolution at a Single Supported Nanoparticle: A Kinetic Model

Eikerling, M. H., Meier, J., & Stimming, U. (2003) · Zeitschrift für Physikalische Chemie · doi:10.1524/zpch.217.4.395.20386 · Cited by 55 · see citing works

Atomic layer deposition of Pd nanoparticles and single atoms on self-supported carbon monolithic catalysts synergistically boosts the hydrogen evolution reaction

Zhang, B., Song, X., Wang, Z., Xu, B., Ye, W., Zhang, L., Lin, H., Ji, T., Lu, X., & Zhu, J. (2024) · Journal of Materials Chemistry A · doi:10.1039/d4ta04359f · Cited by 14 · see citing works

Hydrogen Production from Formic Acid Decomposition - Identification of Active Sites in Pd-based CatalystsPreprint

Surana, M., Javiya, R., & Sampath, A. (2026) · SSRN Electronic Journal · doi:10.2139/ssrn.7371645

Synergistic catalysis of Pd–Ni(OH)2 hybrid anchored on porous carbon for hydrogen evolution from the dehydrogenation of formic acid

Dong, Y., Chen, Q., Qiu, C., Ma, X., Wang, Y., Sun, T., & Fan, G. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.03.016 · Cited by 27 · see citing works

Mechanistic Analysis-Guided Pd-Based Catalysts for Efficient Hydrogen Production from Formic Acid Dehydrogenation

Qin, X., Li, H., Xie, S., Li, K., Jiang, T., Ma, X., Jiang, K. P., Zhang, Q., Terasaki, O., Wu, Z., et al. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c00225 · Cited by 148 · see citing works