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Postsynthetic Metalation of Bipyridyl-Containing Metal–Organic Frameworks for Highly Efficient Catalytic Organic Transformations
Abstract
We have designed highly stable and recyclable single-site solid catalysts via postsynthetic metalation of the 2,2'-bipyridyl-derived metal-organic framework (MOF) of the UiO structure (bpy-UiO). The Ir-functionalized MOF (bpy-UiO-Ir) is a highly active catalyst for both borylation of aromatic C-H bonds using B2(pin)2 (pin = pinacolate) and ortho-silylation of benzylicsilyl ethers; the ortho-silylation activity of the bpy-UiO-Ir is at least 3 orders of magnitude higher than that of the homogeneous control. The Pd-functionalized MOF (bpy-UiO-Pd) catalyzes the dehydrogenation of substituted cyclohexenones to afford phenol derivatives with oxygen as the oxidant. Most impressively, the bpy-UiO-Ir was recycled and reused 20 times for the borylation reaction without loss of catalytic activity or MOF crystallinity. This work highlights the opportunity in designing highly stable and active catalysts based on MOFs containing nitrogen donor ligands for important organic transformations.
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Cites
Functional Porous Coordination Polymers
Kitagawa, S., Kitaura, R., & Noro, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300610 · Cited by 11,071
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Li, H., Eddaoudi, M., O'Keeffe, M., & Yaghi, O. M. (1999) · Nature · doi:10.1038/46248 · Cited by 8,554
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408
From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids
Moulton, B., & Zaworotko, M. J. (2001) · Chemical Reviews · doi:10.1021/cr9900432 · Cited by 6,395
Metal–Organic Frameworks in Biomedicine
Horcajada, P., Gref, R., Baati, T., Allan, P. K., Maurin, G., Couvreur, P., Férey, G., Morris, R. E., & Serre, C. (2012) · Chemical Reviews · doi:10.1021/cr200256v · Cited by 4,168
Hydrogen Storage in Metal–Organic Frameworks
Suh, M. P., Park, H. J., Prasad, T. K., & Lim, D.-W. (2012) · Chemical Reviews · doi:10.1021/cr200274s · Cited by 3,689
Enantioselective catalysis with homochiral metal–organic frameworks
Ma, L., Abney, C., & Lin, W. (2009) · Chemical Society Reviews · doi:10.1039/b807083k · Cited by 3,109
Self-citationHomochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
Yoon, M., Srirambalaji, R., & Kim, K. (2012) · Chemical Reviews · doi:10.1021/cr2003147 · Cited by 2,856
Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks
Cohen, S. M. (2012) · Chemical Reviews · doi:10.1021/cr200179u · Cited by 2,336
Synthesis and Stability of Tagged UiO-66 Zr-MOFs
Kandiah, M., Nilsen, M. H., Usseglio, S., Jakobsen, S., Olsbye, U., Tilset, M., Larabi, C., Quadrelli, E. A., Bonino, F., & Lillerud, K. P. (2010) · Chemistry of Materials · doi:10.1021/cm102601v · Cited by 2,031
Wang, C., Xie, Z., deKrafft, K. E., & Lin, W. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203564w · Cited by 1,547
Self-citationKaes, C., Katz, A., & Hosseini, M. W. (2000) · Chemical Reviews · doi:10.1021/cr990376z · Cited by 1,174
Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations
Hartwig, J. F. (2012) · Accounts of Chemical Research · doi:10.1021/ar200206a · Cited by 1,074
Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials
Wang, C., Liu, D., & Lin, W. (2013) · Journal of the American Chemical Society · doi:10.1021/ja308229p · Cited by 981
Self-citationMa, L., Falkowski, J. M., Abney, C., & Lin, W. (2010) · Nature Chemistry · doi:10.1038/nchem.738 · Cited by 889
Self-citationSong, F., Wang, C., Falkowski, J. M., Ma, L., & Lin, W. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1069773 · Cited by 673
Self-citationMetal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
Bloch, E. D., Britt, D., Lee, C., Doonan, C. J., Uribe-Romo, F. J., Furukawa, H., Long, J. R., & Yaghi, O. M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106935d · Cited by 568
Chelucci, G., & Thummel, R. P. (2002) · Chemical Reviews · doi:10.1021/cr0101914 · Cited by 536
Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols
Izawa, Y., Pun, D., & Stahl, S. S. (2011) · Science · doi:10.1126/science.1204183 · Cited by 464
Functional Mixed Metal–Organic Frameworks with Metalloligands
Das, M. C., Xiang, S., Zhang, Z., & Chen, B. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101534 · Cited by 425
Wang, C., Wang, J.-L., & Lin, W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja310074j · Cited by 342
Self-citationHeterogenization of Homogeneous Catalysts in Metal–Organic Frameworks via Cation Exchange
Genna, D. T., Wong-Foy, A. G., Matzger, A. J., & Sanford, M. S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja402577s · Cited by 299
Li, L., Tang, S., Wang, C., Lv, X., Jiang, M., Wu, H., & Zhao, X. (2014) · Chemical Communications · doi:10.1039/c3cc48275h · Cited by 278
Chiral Nanoporous Metal–Metallosalen Frameworks for Hydrolytic Kinetic Resolution of Epoxides
Zhu, C., Yuan, G., Chen, X., Yang, Z., & Cui, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302340b · Cited by 257
Assembly and Post-Modification of a Metal–Organic Nanotube for Highly Efficient Catalysis
Kong, G.-Q., Ou, S., Zou, C., & Wu, C.-D. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309158a · Cited by 245
Sigman, M. S., & Werner, E. W. (2012) · Accounts of Chemical Research · doi:10.1021/ar200236v · Cited by 221
Izawa, Y., Zheng, C., & Stahl, S. S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209457 · Cited by 149
Integration of accessible secondary metal sites into MOFs for H 2 S removal
Nickerl, G., Leistner, M., Helten, S., et al. (2014) · Inorganic Chemistry Frontiers · doi:10.1039/c3qi00093a · Cited by 99
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Fang, X., Shang, Q., Wang, Y., Jiao, L., Yao, T., Li, Y., Zhang, Q., Luo, Y., & Jiang, H. (2018) · Advanced Materials · doi:10.1002/adma.201705112 · Cited by 837
Covalent Chemistry beyond Molecules
Jiang, J., Zhao, Y., & Yaghi, O. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10666 · Cited by 448
Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol
Baek, J., Rungtaweevoranit, B., Pei, X., Park, M., Fakra, S. C., Liu, Y.-S., Matheu, R., Alshmimri, S. A., Alshehri, S., Trickett, C. A., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b11525 · Cited by 417
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
Liu, J., Goetjen, T. A., Wang, Q., Knapp, J. G., Wasson, M. C., Yang, Y., Syed, Z. H., Delferro, M., Notestein, J. M., Farha, O. K., et al. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00968k · Cited by 386
Luminescent rare-earth-based MOFs as optical sensors
Mahata, P., Mondal, S. K., Singha, D. K., & Majee, P. (2017) · Dalton Transactions · doi:10.1039/c6dt03419e · Cited by 292
Metadata
- Authors
- Manna, K., Zhang, T., & Lin, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-23
- Volume
- 136
- Issue
- 18
- Pages
- 6566-6569
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2313371282
- Cited by
- 313
- References
- 30
- FWCI
- 19.61
- Type
- journal article
- Language
- en
- Open access
- closed
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