The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
A Solution-Phase Bifunctional Catalyst for Lithium–Oxygen Batteries
Abstract
A lithium-oxygen battery would deliver the highest energy density of a rechargeable battery, but the multiphase electrochemical reaction on the air cathode has difficulty proceeding when operated with only solid catalysts. We report here the organic-electrolyte-dissolved iron phthalocyanine (FePc) as a shuttle of (O2)(-) species and electrons between the surface of the electronic conductor and the insulator Li2O2 product of discharge. The Li2O2 is observed to grow and decompose without direct contact with carbon, which greatly enhances the electrochemical performance. Our results signal that the use of molecular shuttles that are catalytically active may prove to be enablers of a practical lithium-air rechargeable battery.
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Citations
Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts
Cheng, F., & Chen, J. (2012) · Chemical Society Reviews · doi:10.1039/c1cs15228a · Cited by 2,677
A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery
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A Reversible and Higher-Rate Li-O 2 Battery
Peng, Z., Freunberger, S. A., Chen, Y., & Bruce, P. G. (2012) · Science · doi:10.1126/science.1223985 · Cited by 1,915
Multifunctional, Ultra‐Flyweight, Synergistically Assembled Carbon Aerogels
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Lu, Y.-C., Xu, Z., Gasteiger, H. A., Chen, S., Hamad-Schifferli, K., & Shao-Horn, Y. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1036572 · Cited by 1,238
Inorganic solid Li ion conductors: An overview
Knauth, P. (2009) · Solid State Ionics · doi:10.1016/j.ssi.2009.03.022 · Cited by 1,170
An improved high-performance lithium–air battery
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A review of Fe–N/C and Co–N/C catalysts for the oxygen reduction reaction
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Hierarchically Porous Graphene as a Lithium–Air Battery Electrode
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Cited by
Advances in understanding mechanisms underpinning lithium–air batteries
Aurbach, D., McCloskey, B. D., Nazar, L. F., & Bruce, P. G. (2016) · Nature Energy · doi:10.1038/nenergy.2016.128 · Cited by 1,254
Chen, P., Zhou, T., Xing, L., Xu, K., Tong, Y., Xie, H., Zhang, L., Yan, W., Chu, W., Wu, C., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201610119 · Cited by 1,085
A review of cathode materials and structures for rechargeable lithium–air batteries
Ma, Z., Yuan, X., Li, L., Ma, Z.-F., Wilkinson, D. P., Zhang, L., & Zhang, J. (2015) · Energy & Environmental Science · doi:10.1039/c5ee00838g · Cited by 485
Liu, X., Park, M., Kim, M. G., Gupta, S., Wu, G., & Cho, J. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201503612 · Cited by 429
Critical Challenges in Rechargeable Aprotic Li–O2 Batteries
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Metadata
- Authors
- Sun, D., Shen, Y., Zhang, W., Yu, L., Yi, Z., Yin, W., Wang, D., Huang, Y., Wang, J., Wang, D., & Goodenough, J. B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-12
- Volume
- 136
- Issue
- 25
- Pages
- 8941-8946
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2329533199
- Cited by
- 466
- References
- 39
- FWCI
- 29.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sun, D., Shen, Y., Zhang, W., Yu, L., Yi, Z., Yin, W., Wang, D., Huang, Y., Wang, J., Wang, D., & Goodenough, J. B. (2014). A Solution-Phase Bifunctional Catalyst for Lithium–Oxygen Batteries. Journal of the American Chemical Society. https://doi.org/10.1021/ja501877e
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