The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis
Open accessAbstract
Direct β-alkylation of saturated aldehydes has been accomplished by synergistically combining photoredox catalysis and organocatalysis. Photon-induced enamine oxidation provides an activated β-enaminyl radical intermediate, which readily combines with a wide range of Michael acceptors to produce β-alkyl aldehydes in a highly efficient manner. Furthermore, this redox-neutral, atom-economical C-H functionalization protocol can be achieved both inter- and intramolecularly. Mechanistic studies by various spectroscopic methods suggest that a reductive quenching pathway is operable.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
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Cited by
Photoredox Catalysis in Organic Chemistry
Shaw, M. H., Twilton, J., & MacMillan, D. W. C. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b01449 · Cited by 3,186
Self-citationDual Catalysis Strategies in Photochemical Synthesis
Skubi, K. L., Blum, T. R., & Yoon, T. P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00018 · Cited by 2,686
Photoredox-Catalyzed C–H Functionalization Reactions
Holmberg-Douglas, N., & Nicewicz, D. A. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00311 · Cited by 989
Organocatalysis in Inert C–H Bond Functionalization
Qin, Y., Zhu, L., & Luo, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00657 · Cited by 785
Teegardin, K., Day, J. I., Chan, J., & Weaver, J. (2016) · Organic Process Research & Development · doi:10.1021/acs.oprd.6b00101 · Cited by 593
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Lead-Halide Perovskites for Photocatalytic α-Alkylation of Aldehydes
Zhu, X., Lin, Y., Sun, Y., Beard, M. C., & Yan, Y. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08720 · Cited by 361
Katalyse von Radikalreaktionen: Konzepte aus Sicht der Radikalchemie
Studer, A., & Curran, D. P. (2016) · Angewandte Chemie · doi:10.1002/ange.201505090 · Cited by 313
Xu, J., Shanmugam, S., Fu, C., Aguey-Zinsou, K.-F., & Boyer, C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12408 · Cited by 313
Iminium and enamine catalysis in enantioselective photochemical reactions
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Metadata
- Authors
- Terrett, J. A., Clift, M. D., & MacMillan, D. W. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-29
- Volume
- 136
- Issue
- 19
- Pages
- 6858-6861
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1999257584
- Cited by
- 208
- References
- 1
- FWCI
- 11.27
- Type
- journal article
- Language
- en
- Open access
- hybrid
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