The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Lead-Halide Perovskites for Photocatalytic α-Alkylation of Aldehydes
Open accessAbstract
Cost-effective and efficient photocatalysis are highly desirable in chemical synthesis. Here we demonstrate that readily prepared suspensions of APbBr 3 (A = Cs or methylammonium (MA)) type perovskite colloids (ca. 2–100 nm) can selectively photocatalyze carbon–carbon bond formation reactions, i.e., α-alkylations. Specifically, we demonstrate α-alkylation of aldehydes with a turnover number (TON) of over 52,000 under visible light illumination. Hybrid organic/inorganic perovskites are revolutionizing photovoltaic research and are now impacting other research fields, but their exploration in organic synthesis is rare. Our low-cost, easy-to-process, highly efficient and bandedge-tunable perovskite photocatalyst is expected to bring new insights in chemical synthesis.
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Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3
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Low-temperature solution-processed wavelength-tunable perovskites for lasing
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Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes
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Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
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Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
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Self-citationSolution-processed hybrid perovskite photodetectors with high detectivity
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Cited by
Lead halide perovskites for photocatalytic organic synthesis
Zhu, X., Lin, Y., San Martin, J., Sun, Y., Zhu, D., & Yan, Y. (2019) · Nature Communications · doi:10.1038/s41467-019-10634-x · Cited by 455
Self-citationHeterogeneous Photocatalysis in Organic Synthesis
Gisbertz, S., & Pieber, B. (2020) · ChemPhotoChem · doi:10.1002/cptc.202000014 · Cited by 312
Dai, Y., Poidevin, C., Ochoa‐Hernández, C., Auer, A. A., & Tüysüz, H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201915034 · Cited by 269
Gao, S., Wang, B., Chen, F., He, G., Zhang, T., Li, L., Li, J., Zhou, Y., Feng, B., Mei, D., et al. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202319996 · Cited by 55
Metadata
- Authors
- Zhu, X., Lin, Y., Sun, Y., Beard, M. C., & Yan, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-01-02
- Volume
- 141
- Issue
- 2
- Pages
- 733-738
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2908179434
- Cited by
- 361
- References
- 41
- FWCI
- 17.89
- Type
- journal article
- Language
- en
- Open access
- green
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