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Nanowire-Directed Templating Synthesis of Metal–Organic Framework Nanofibers and Their Derived Porous Doped Carbon Nanofibers for Enhanced Electrocatalysis

Zhang, Wang, Wu, Zhen-Yu, Jiang, Hai-Long, Yu, Shu-Hong·2014·Journal of the American Chemical Society

Abstract

A nanowire-directed templating synthesis of metal-organic framework (MOF) nanofibers has been demonstrated, where ultrathin tellurium nanowires (TeNWs) with excellent dispersivity can act as templates for directed growth and assembly of ZIF-8 nanocrystals (one typical MOF), resulting in the formation of uniform ZIF-8 nanofibers. The as-obtained ZIF-8 nanofibers can be conveniently converted into highly porous doped carbon nanofibers by calcination. Compared with bulk porous carbon by direct carbonization of MOF crystals, these doped carbon nanofibers exhibit complex network structure, hierarchical pores, and high surface area. Further doped by phosphorus species, the co-doped carbon nanofibers exhibit excellent electrocatalytic performance for oxygen reduction reaction, even better than the benchmark Pt/C catalyst.

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Metadata

Authors
Zhang, W., Wu, Z.-Y., Jiang, H.-L., & Yu, S.-H.
Venue
Journal of the American Chemical Society
Published
2014-10-01
Volume
136
Issue
41
Pages
14385-14388
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1978477068
Cited by
627
References
0
FWCI
21.61
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Nanowire-Directed Templating Synthesis of Metal–Organic Framework Nanofibers and Their Derived Porous Doped Carbon Nanofibers for Enhanced Electrocatalysis. https://app.cochat.ai/papers/10.1021/ja5084128
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Zhang, W., Wu, Z.-Y., Jiang, H.-L., & Yu, S.-H. (2014). Nanowire-Directed Templating Synthesis of Metal–Organic Framework Nanofibers and Their Derived Porous Doped Carbon Nanofibers for Enhanced Electrocatalysis. Journal of the American Chemical Society. https://doi.org/10.1021/ja5084128

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