The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
Abstract
Porous heterogeneous catalysts play a pivotal role in the chemical industry. Herein a new Hf-based metal-organic framework (Hf-NU-1000) incorporating Hf6 clusters is reported. It demonstrates high catalytic efficiency for the activation of epoxides, facilitating the quantitative chemical fixation of CO2 into five-membered cyclic carbonates under ambient conditions, rendering this material an excellent catalyst. As a multifunctional catalyst, Hf-NU-1000 is also efficient for other epoxide activations, leading to the regioselective and enantioretentive formation of 1,2-bifuctionalized systems via solvolytic nucleophilic ring opening.
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Cited by
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
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The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
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Metal–organic and covalent organic frameworks as single-site catalysts
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Metadata
- Authors
- Beyzavi, H., Klet, R. C., Tussupbayev, S., Borycz, J., Vermeulen, N. A., Cramer, C. J., Stoddart, J. F., Hupp, J. T., & Farha, O. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-30
- Volume
- 136
- Issue
- 45
- Pages
- 15861-15864
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2319442421
- Cited by
- 521
- References
- 30
- FWCI
- 21.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Beyzavi, H., Klet, R. C., Tussupbayev, S., Borycz, J., Vermeulen, N. A., Cramer, C. J., Stoddart, J. F., Hupp, J. T., & Farha, O. K. (2014). A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation. Journal of the American Chemical Society. https://doi.org/10.1021/ja508626n
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