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A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
Abstract
Porous heterogeneous catalysts play a pivotal role in the chemical industry. Herein a new Hf-based metal-organic framework (Hf-NU-1000) incorporating Hf6 clusters is reported. It demonstrates high catalytic efficiency for the activation of epoxides, facilitating the quantitative chemical fixation of CO2 into five-membered cyclic carbonates under ambient conditions, rendering this material an excellent catalyst. As a multifunctional catalyst, Hf-NU-1000 is also efficient for other epoxide activations, leading to the regioselective and enantioretentive formation of 1,2-bifuctionalized systems via solvolytic nucleophilic ring opening.
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Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Marenich, A. V., Cramer, C. J., & Truhlar, D. G. (2009) · The Journal of Physical Chemistry B · doi:10.1021/jp810292n · Cited by 17,843
Self-citationThe Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
CRC Handbook of Chemistry and Physics
(2016) · CRC Press eBooks · doi:10.1201/9781315380476 · Cited by 13,921
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Self-citationEnantioselective catalysis with homochiral metal–organic frameworks
Ma, L., Abney, C., & Lin, W. (2009) · Chemical Society Reviews · doi:10.1039/b807083k · Cited by 3,109
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis
Liu, J., Chen, L., Cui, H., Zhang, J., Zhang, L., & Su, C.-Y. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00094c · Cited by 2,894
Feng, D., Gu, Z., Li, J., Jiang, H., Wei, Z., & Zhou, H. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201204475 · Cited by 1,978
Utilisation of CO2 as a chemical feedstock: opportunities and challenges
Aresta, M., & Dibenedetto, A. (2007) · Dalton Transactions · doi:10.1039/b700658f · Cited by 1,452
Worldwide innovations in the development of carbon capture technologies and the utilization of CO2
Markewitz, P., Kuckshinrichs, W., Leitner, W., Linssen, J., Zapp, P., Bongartz, R., Schreiber, A., & Müller, T. E. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03403d · Cited by 1,202
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
Feng, D., Chung, W.-C., Wei, Z., Gu, Z.-Y., Jiang, H.-L., Chen, Y.-P., Darensbourg, D. J., & Zhou, H.-C. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408084j · Cited by 1,126
Vermoortele, F., Bueken, B., Le Bars, G., Van de Voorde, B., Vandichel, M., Houthoofd, K., Vimont, A., Daturi, M., Waroquier, M., Van Speybroeck, V., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405078u · Cited by 1,110
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
Mondloch, J. E., Bury, W., Fairen-Jimenez, D., Kwon, S., DeMarco, E. J., Weston, M. H., Sarjeant, A. A., Nguyen, S. T., Stair, P. C., Snurr, R. Q., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4050828 · Cited by 1,008
Self-citationSynthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
Morris, W., Volosskiy, B., Demir, S., Gándara, F., McGrier, P. L., Furukawa, H., Cascio, D., Stoddart, J. F., & Yaghi, O. M. (2012) · Inorganic Chemistry · doi:10.1021/ic300825s · Cited by 906
Self-citationCapture and conversion of CO2 at ambient conditions by a conjugated microporous polymer
Xie, Y., Wang, T.-T., Liu, X.-H., Zou, K., & Deng, W.-Q. (2013) · Nature Communications · doi:10.1038/ncomms2960 · Cited by 772
Yamaguchi, K., Ebitani, K., Yoshida, T., Yoshida, H., & Kaneda, K. (1999) · Journal of the American Chemical Society · doi:10.1021/ja9902165 · Cited by 730
Mechanism of Cyclic Carbonate Synthesis from Epoxides and CO2
North, M., & Pasquale, R. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200805451 · Cited by 618
Gao, W., Chen, Y., Niu, Y., Williams, K., Cash, L., Perez, P. J., Wojtas, L., Cai, J., Chen, Y., & Ma, S. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309778 · Cited by 553
Guillerm, V., Weseliński, Ł. J., Belmabkhout, Y., Cairns, A. J., D'Elia, V., Wojtas, Ł., Adil, K., & Eddaoudi, M. (2014) · Nature Chemistry · doi:10.1038/nchem.1982 · Cited by 452
Yano, T., Matsui, H., Koike, T., Ishiguro, H., Fujihara, H., Yoshihara, M., & Maeshima, T. (1997) · Chemical Communications · doi:10.1039/a608102i · Cited by 352
Catalytic Formation of Cyclic Carbonates from Epoxides and CO2 with Chromium Metalloporphyrinates
Kruper, W. J., & Dellar, D. D. (1995) · The Journal of Organic Chemistry · doi:10.1021/jo00108a042 · Cited by 310
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
Planas, N., Mondloch, J. E., Tussupbayev, S., Borycz, J., Gagliardi, L., Hupp, J. T., Farha, O. K., & Cramer, C. J. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz501899j · Cited by 287
Self-citationCyclic Carbonate Synthesis from Supercritical Carbon Dioxide and Epoxide over Lanthanide Oxychloride
Yasuda, H., He, L.-N., & Sakakura, T. (2002) · Journal of Catalysis · doi:10.1006/jcat.2002.3662 · Cited by 242
Wang, J.-Q., Kong, D.-L., Chen, J.-Y., Cai, F., & He, L.-N. (2006) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/j.molcata.2006.01.008 · Cited by 232
YASUDA, H., HE, L., SAKAKURA, T., & HU, C. (2005) · Journal of Catalysis · doi:10.1016/j.jcat.2005.04.030 · Cited by 214
A chiral metal–organic framework for sequential asymmetric catalysis
Song, F., Wang, C., & Lin, W. (2011) · Chemical Communications · doi:10.1039/c1cc12701b · Cited by 182
Microporous organic networks bearing metal-salen species for mild CO2 fixation to cyclic carbonates
Chun, J., Kang, S., Kang, N., Lee, S. M., Kim, H. J., & Son, S. U. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta10477j · Cited by 117
Modular, Active, and Robust Lewis Acid Catalysts Supported on a Metal−Organic Framework
Tanabe, K. K., & Cohen, S. M. (2010) · Inorganic Chemistry · doi:10.1021/ic101125m · Cited by 95
Reactions of Alicyclic Epoxy Compounds with Nitrogen-Containing Nucleophiles
Kas’yan, L. I., Okovityi, S. I., & Kasyan, A. O. (2004) · Russian Journal of Organic Chemistry · doi:10.1023/b:rujo.0000034906.46654.ff · Cited by 17
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Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
Huang, Y.-B., Liang, J., Wang, X.-S., & Cao, R. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00250a · Cited by 1,908
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
Trickett, C. A., Helal, A., Al-Maythalony, B. A., Yamani, Z. H., Cordova, K. E., & Yaghi, O. M. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.45 · Cited by 1,524
Catalysis and photocatalysis by metal organic frameworks
Dhakshinamoorthy, A., Li, Z., & Garcia, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00256h · Cited by 1,505
Metal–organic and covalent organic frameworks as single-site catalysts
Rogge, S. M. J., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A. I., Sepúlveda-Escribano, A., Vimont, A., Clet, G., Bazin, P., Kapteijn, F., et al. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00033b · Cited by 1,077
Metadata
- Authors
- Beyzavi, H., Klet, R. C., Tussupbayev, S., Borycz, J., Vermeulen, N. A., Cramer, C. J., Stoddart, J. F., Hupp, J. T., & Farha, O. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-30
- Volume
- 136
- Issue
- 45
- Pages
- 15861-15864
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2319442421
- Cited by
- 521
- References
- 30
- FWCI
- 21.51
- Type
- journal article
- Language
- en
- Open access
- closed
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