The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst
Abstract
Converting CO2 into valuable compounds using sunlight as the energy input and an earth-abundant metal complex as the catalyst is an exciting challenge related to contemporary energy issues as well as to climate change. By using an inexpensive organic photosensitizer under visible-light excitation (λ > 400 nm) and a substituted iron(0) tetraphenylporphyrin as a homogeneous catalyst, we have been able to generate carbon monoxide from CO2 selectively with high turnover numbers. Sustained catalytic activity over a long time period (t > 50 h) did not lead to catalyst or sensitizer deactivation. A catalytic mechanism is proposed.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Cited by
Visible-light-driven methane formation from CO2 with a molecular iron catalyst
Rao, H., Schmidt, L. C., Bonin, J., & Robert, M. (2017) · Nature · doi:10.1038/nature23016 · Cited by 1,041
Self-citationElectro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Fang, S., Rahaman, M., Bharti, J., Reisner, E., Robert, M., Ozin, G. A., & Hu, Y. H. (2023) · Nature Reviews Methods Primers · doi:10.1038/s43586-023-00243-w · Cited by 834
Self-citationSemiconductor Quantum Dots: An Emerging Candidate for CO2 Photoreduction
Wu, H., Li, X., Tung, C., & Wu, L. (2019) · Advanced Materials · doi:10.1002/adma.201900709 · Cited by 486
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
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Metadata
- Authors
- Bonin, J., Robert, M., & Routier, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-20
- Volume
- 136
- Issue
- 48
- Pages
- 16768-16771
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2002880032
- Cited by
- 328
- References
- 2
- FWCI
- 7.97
- Type
- journal article
- Language
- en
- Open access
- closed
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