The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal–Organic Framework-177
Abstract
Metal-organic framework-177 (MOF-177) is one of the most porous materials whose structure is composed of octahedral Zn4O(-COO)6 and triangular 1,3,5-benzenetribenzoate (BTB) units to make a three-dimensional extended network based on the qom topology. This topology violates a long-standing thesis where highly symmetric building units are expected to yield highly symmetric networks. In the case of octahedron and triangle combinations, MOFs based on pyrite (pyr) and rutile (rtl) nets were expected instead of qom. In this study, we have made 24 MOF-177 structures with different functional groups on the triangular BTB linker, having one or more functionalities. We find that the position of the functional groups on the BTB unit allows the selection for a specific net (qom, pyr, and rtl), and that mixing of functionalities (-H, -NH2, and -C4H4) is an important strategy for the incorporation of a specific functionality (-NO2) into MOF-177 where otherwise incorporation of such functionality would be difficult. Such mixing of functionalities to make multivariate MOF-177 structures leads to enhancement of hydrogen uptake by 25%.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Self-citationA survey of Hammett substituent constants and resonance and field parameters
Hansch, C., Leo, A., & Taft, R. W. (1991) · Chemical Reviews · doi:10.1021/cr00002a004 · Cited by 8,651
Hybrid porous solids: past, present, future
Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822
Ultrahigh Porosity in Metal-Organic Frameworks
Furukawa, H., Ko, N., Go, Y. B., Aratani, N., Choi, S. B., Choi, E., Yazaydin, A. Ö., Snurr, R. Q., O’Keeffe, M., Kim, J., et al. (2010) · Science · doi:10.1126/science.1192160 · Cited by 3,904
Self-citationA route to high surface area, porosity and inclusion of large molecules in crystals
Materials Design and Discovery Group, Chae, H. K., Siberio-Pérez, D. Y., Kim, J., Go, Y., Eddaoudi, M., Matzger, A. J., O'Keeffe, M., & Yaghi, O. M. (2004) · Nature · doi:10.1038/nature02311 · Cited by 2,816
Self-citationThe Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
O’Keeffe, M., Peskov, M. A., Ramsden, S. J., & Yaghi, O. M. (2008) · Accounts of Chemical Research · doi:10.1021/ar800124u · Cited by 2,313
Self-citationTuning the structure and function of metal–organic frameworks via linker design
Lu, W., Wei, Z., Gu, Z.-Y., Liu, T.-F., Park, J., Park, J., Tian, J., Zhang, M., Zhang, Q., Gentle III, T., et al. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00003j · Cited by 2,252
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
Ockwig, N. W., Delgado-Friedrichs, O., O'Keeffe, M., & Yaghi, O. M. (2005) · Accounts of Chemical Research · doi:10.1021/ar020022l · Cited by 2,197
Self-citationMetal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
Farha, O. K., Eryazici, I., Jeong, N. C., Hauser, B. G., Wilmer, C. E., Sarjeant, A. A., Snurr, R. Q., Nguyen, S. T., Yazaydın, A. Ö., & Hupp, J. T. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3055639 · Cited by 1,958
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
Deng, H., Doonan, C. J., Furukawa, H., Ferreira, R. B., Towne, J., Knobler, C. B., Wang, B., & Yaghi, O. M. (2010) · Science · doi:10.1126/science.1181761 · Cited by 1,917
Self-citation
Cited by
Applications of water stable metal–organic frameworks
Wang, C., Liu, X., Keser Demir, N., Chen, J. P., & Li, K. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00362a · Cited by 1,249
Isoreticular chemistry within metal–organic frameworks for gas storage and separation
Fan, W., Zhang, X., Kang, Z., Liu, X., & Sun, D. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.213968 · Cited by 584
Optimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material
Lin, R.-B., Li, L., Wu, H., Arman, H., Li, B., Lin, R.-G., Zhou, W., & Chen, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03850 · Cited by 559
Covalent Chemistry beyond Molecules
Jiang, J., Zhao, Y., & Yaghi, O. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10666 · Cited by 448
Self-citationA reticular chemistry guide for the design of periodic solids
Jiang, H., Alezi, D., & Eddaoudi, M. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00287-y · Cited by 432
Metadata
- Authors
- Zhang, Y.-B., Furukawa, H., Ko, N., Nie, W., Park, H. J., Okajima, S., Cordova, K. E., Deng, H., Kim, J., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-17
- Volume
- 137
- Issue
- 7
- Pages
- 2641-2650
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2314441937
- Cited by
- 403
- References
- 38
- FWCI
- 21.94
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal–Organic Framework-177. https://app.cochat.ai/papers/10.1021/ja512311a
- The paper
- Zhang, Y.-B., Furukawa, H., Ko, N., Nie, W., Park, H. J., Okajima, S., Cordova, K. E., Deng, H., Kim, J., & Yaghi, O. M. (2015). Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal–Organic Framework-177. Journal of the American Chemical Society. https://doi.org/10.1021/ja512311a
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
