The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Electrochemical (De)Lithiation of 1D Sulfur Chains in Li–S Batteries: A Model System Study
Abstract
In contrast to the extensive studies of the electrochemical behavior of conventional cyclic S8 molecules in Li-S batteries, there has been hardly any investigation of the electrochemistry of S chains. Here we use S chains encapsulated in single- and double-walled carbon nanotubes as a model system and report the electrochemical behavior of 1D S chains in Li-S batteries. An electrochemical test shows that S chains have high electrochemical activity during lithiation and extinctive electrochemistry compared with conventional S8. The confined steric effect provides Li(+) solid-phase diffusion access to insert/egress reactions with S chains. During lithiation, the long S chains spontaneously become short chains, which show higher discharge plateaus and better kinetics. The unique electrochemistry of S chains supplements the existing knowledge of the S cathode mechanism and provides avenues for rational design of S cathode materials in Li-S batteries.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Cited by
Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries
Peng, H., Huang, J., Cheng, X., & Zhang, Q. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700260 · Cited by 1,746
Bao, W., Liu, L., Wang, C., Choi, S., Wang, D., & Wang, G. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702485 · Cited by 745
Carbon materials for Li–S batteries: Functional evolution and performance improvement
Liang, J., Sun, Z.-H., Li, F., & Cheng, H.-M. (2016) · Energy Storage Materials · doi:10.1016/j.ensm.2015.09.007 · Cited by 593
Metal–Sulfur Battery Cathodes Based on PAN–Sulfur Composites
Wei, S., Ma, L., Hendrickson, K. E., Tu, Z., & Archer, L. A. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08113 · Cited by 579
Li, J.-Y., Xu, Q., Li, G., Yin, Y.-X., Wan, L.-J., & Guo, Y.-G. (2017) · Materials Chemistry Frontiers · doi:10.1039/c6qm00302h · Cited by 384
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Metadata
- Authors
- Yang, C.-P., Yin, Y.-X., Guo, Y.-G., & Wan, L.-J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-09
- Volume
- 137
- Issue
- 6
- Pages
- 2215-2218
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1976453341
- Cited by
- 226
- References
- 1
- FWCI
- 16.04
- Type
- journal article
- Language
- en
- Open access
- closed
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