The DOI matches its Crossref record.
Sodium Alanate Nanoparticles − Linking Size to Hydrogen Storage Properties
Open accessAbstract
Important limitations in the application of light metal hydrides for hydrogen storage are slow kinetics and poor reversibility. To alleviate these problems doping and ball-milling are commonly applied, for NaAlH 4 leading to particle sizes down to 150 nm. By wet-chemical synthesis we have prepared carbon nanofiber-supported NaAlH 4 with discrete particle size ranges of 1-10 microm, 19-30 nm, and 2-10 nm. The hydrogen desorption temperatures and activation energies decreased from 186 degrees C and 116 kJ.mol (-1) for the largest particles to 70 degrees C and 58 kJ.mol (-1) for the smallest particles. In addition, decreasing particle sizes lowered the pressures needed for reloading. This reported size-performance correlation for NaAlH 4 may guide hydrogen storage research for a wide range of nanostructured light (metal) hydrides.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Advanced Materials for Energy Storage
Liu, C., Li, F., Ma, L., & Cheng, H. (2010) · Advanced Materials · doi:10.1002/adma.200903328 · Cited by 4,765
Nanomaterials for renewable energy production and storage
Chen, X., Li, C., Grätzel, M., Kostecki, R., & Mao, S. S. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35230c · Cited by 1,015
Nanoparticulate Functional Materials
Goesmann, H., & Feldmann, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200903053 · Cited by 733
Yu, X., Tang, Z., Sun, D., Ouyang, L., & Zhu, M. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.03.001 · Cited by 716
Hydrogen in magnesium: new perspectives toward functional stores
Aguey-Zinsou, K.-F., & Ares-Fernández, J.-R. (2010) · Energy & Environmental Science · doi:10.1039/b921645f · Cited by 447
Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art
Lai, Q., Paskevicius, M., Sheppard, D. A., Buckley, C. E., Thornton, A. W., Hill, M. R., Gu, Q., Mao, J., Huang, Z., Liu, H. K., et al. (2015) · ChemSusChem · doi:10.1002/cssc.201500231 · Cited by 414
High capacity hydrogen storage: Basic aspects, new developments and milestones
Pukazhselvan, D., Kumar, V., & Singh, S. K. (2012) · Nano Energy · doi:10.1016/j.nanoen.2012.05.004 · Cited by 273
Osman, A. I., Nasr, M., Eltaweil, A. S., Hosny, M., Farghali, M., Al-Fatesh, A. S., Rooney, D. W., & Abd El-Monaem, E. M. (2024) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2024.03.223 · Cited by 270
Complex hydrides for energy storage, conversion, and utilization
He, T., Cao, H., & Chen, P. (2019) · Advanced Materials · doi:10.1002/adma.201902757 · Cited by 256
Zhang, K., Ivanov, D. S., Ganeev, R. A., Boltaev, G. S., Krishnendu, P. S., Singh, S. C., Garcia, M. E., Zavestovskaya, I. N., & Guo, C. (2019) · Nanomaterials · doi:10.3390/nano9050767 · Cited by 39
Abbasi, M., & Dorranian, D. (2015) · Optics and Spectroscopy · doi:10.1134/s0030400x15030029 · Cited by 36
Metadata
- Authors
- Baldé, C. P., Hereijgers, B. P. C., Bitter, J. H., & Jong, K. P. D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-05-01
- Volume
- 130
- Issue
- 21
- Pages
- 6761-6765
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1983753725
- Cited by
- 227
- References
- 0
- FWCI
- 15.49
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
