Cited by 256Hydrogen Storage and MaterialsEnergetic Materials and CombustionInorganic Chemistry and Materials

Complex hydrides for energy storage, conversion, and utilization

He, Teng, Cao, Hujun, Chen, Ping·2019·Advanced Materials

Abstract

Abstract Functional materials are the key enabling factor in the development of clean energy technologies. Materials of particular interest, which are reviewed herein, are a class of hydrogenous compound having the general formula of M(XHn)m, where M is usually a metal cation and X can be Al, B, C, N, O, transition metal (TM), or a mixture of them, which sets up an iono‐covalent or covalent bonding with H. M(XHn)m is generally termed as a complex hydride by the hydrogen storage community. The rich chemistry between H and B/C/N/O/Al/TM allows complex hydrides of diverse composition and electronic configuration, and thus tunable physical and chemical properties, for applications in hydrogen storage, thermal energy storage, ion conduction in electrochemical devices, and catalysis in fuel processing. The recent progress is reviewed here and strategic approaches for the design and optimization of complex hydrides for the abovementioned applications are highlighted.

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Crossref · 10.1002/adma.201902757

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Authors
He, T., Cao, H., & Chen, P.
Affiliations
Dalian Institute of Chemical Physics (CN)
Corresponding author
Chen, Ping
Venue
Advanced Materials
Publisher
Wiley
Published
2019-11-04
Volume
31
Issue
50
Pages
e1902757-e1902757
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2983064641
Cited by
256
References
276
Citations by year
2026: 46 · 2025: 37 · 2024: 48 · 2023: 44 · 2022: 36 · 2021: 20 · 2020: 23 · 2019: 2
FWCI
1.03
Type
journal article
Language
en
Open access
closed
Locations
  • Advanced Materials (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • National Basic Research Program of China (2018YFB1502100)
  • National Natural Science Foundation of China (51671178, 51472237, 51801197, 21633011)
  • Dalian Institute of Chemical Physics (DICP ZZBS201616, DICP DCLS201701)
  • Youth Innovation Promotion Association of the Chinese Academy of Sciences (2019189, iChEM·2011)
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
  • Physical Sciences › Engineering › Mechanics of Materials › Energetic Materials and Combustion
  • Physical Sciences › Chemistry › Inorganic Chemistry › Inorganic Chemistry and Materials
Keywords
complex hydrides, hydrogen storage, thermal energy storage, ionic conduction, electrochemical devices, catalysis, fuel processing, metal hydrides, functional materials, materials design

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