The DOI matches its Crossref record.
Coumarin-Derived Cu2+-Selective Fluorescence Sensor: Synthesis, Mechanisms, and Applications in Living Cells
Abstract
A novel coumarin-based fluorogenic probe bearing the 2-picolyl unit (1) was developed as a fluorescent chemosensor with high selectivity and suitable affinity in biological systems toward Cu(2+) over other cations tested. The fluorescence on-off mechanism was studied by femtosecond time-resolved fluorescence (TRF) upconversion technique and ab initio calculations. The receptor can be applied to the monitoring of Cu(2+) ion in aqueous solution with a pH span 4-10. To confirm the suitability of 1 for biological applications, we also employed it for the fluorescence detection of the changes of intracellular Cu(2+) in cultured cells. The results indicate that 1 should be useful for the fluorescence microscopic imaging and the study on the biological functions of Cu(2+).
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Citations
Cited by
Zhao, Y., Zhang, X.-B., Han, Z.-X., Qiao, L., Li, C.-Y., Jian, L.-X., Shen, G.-L., & Yu, R.-Q. (2009) · Analytical Chemistry · doi:10.1021/ac901127n · Cited by 455
Grover, K., Koblova, A., Pezacki, A. T., Chang, C. J., & New, E. J. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00819 · Cited by 129
Metadata
- Authors
- Jung, H. S., Kwon, P. S., Lee, J. W., Kim, J. I., Hong, C. S., Kim, J. W., Yan, S., Lee, J. Y., Lee, J. H., Joo, T., & Kim, J. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-01-21
- Volume
- 131
- Issue
- 5
- Pages
- 2008-2012
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2091360402
- Cited by
- 1,058
- References
- 0
- FWCI
- 27.59
- Type
- journal article
- Language
- en
- Open access
- closed
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