The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
A Quantitative Basis for a Scale of Na+ Affinities of Organic and Small Biological Molecules in the Gas Phase
Abstract
High-pressure mass spectrometric experiments and ab initio calculations have been carried out in order to establish a series of accurate gas-phase sodium ion affinities of organic molecules with a wide variety of functional groups. Ab initio calculations have also been performed on the sodium complexes of three amino acids: serine, cysteine, and proline. A systematic critical evaluation of experimental and computational literature results shows that a significant number require revision. Based on comparisons with accurate experimental measurements, the ab initio procedure used is shown to yield sodium ion affinities with an accuracy of ca. 1 kcal·mol - 1 . This enables the construction of the first reliable table of gas-phase Na + affinities for organic and small biological molecules.
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Ma, J. C., & Dougherty, D. A. (1997) · Chemical Reviews · doi:10.1021/cr9603744 · Cited by 3,477
Dzidic, I., & Kebarle, P. (1970) · The Journal of Physical Chemistry · doi:10.1021/j100702a013 · Cited by 710
Principles of bioinorganic chemistry
Vella, F. (1995) · Biochemical Education · doi:10.1016/0307-4412(95)90685-1 · Cited by 693
Mecozzi, S., West, A. P., & Dougherty, D. A. (1996) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.93.20.10566 · Cited by 592
Cation-Water Interactions: The M+(H2O)n Clusters for Alkali Metals, M = Li, Na, K, Rb, and Cs
Glendening, E. D., & Feller, D. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100010a015 · Cited by 259
Ab Initio Studies of Amino Acid Conformations. 1. The Conformers of Alanine, Serine, and Cysteine
Gronert, S., & O'Hair, R. A. J. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00112a022 · Cited by 213
Marinelli, P. J., & Squires, R. R. (1989) · Journal of the American Chemical Society · doi:10.1021/ja00193a052 · Cited by 208
Kim, J., Lee, S., Cho, S. J., Mhin, B. J., & Kim, K. S. (1995) · The Journal of Chemical Physics · doi:10.1063/1.469199 · Cited by 178
Cerda, B. A., Hoyau, S., Ohanessian, G., & Wesdemiotis, C. (1998) · Journal of the American Chemical Society · doi:10.1021/ja972417j · Cited by 172
Self-citationHashimoto, K., & Morokuma, K. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00104a024 · Cited by 147
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Kebarle, P., & Verkerk, U. H. (2009) · Mass Spectrometry Reviews · doi:10.1002/mas.20247 · Cited by 905
Wechselwirkungen mit aromatischen Ringen in chemischen und biologischen Erkennungsprozessen
Meyer, E. A., Castellano, R. K., & Diederich, F. (2003) · Angewandte Chemie · doi:10.1002/ange.200390290 · Cited by 552
Ion Solvation Thermodynamics from Simulation with a Polarizable Force Field
Grossfield, A., Ren, P., & Ponder, J. W. (2003) · Journal of the American Chemical Society · doi:10.1021/ja037005r · Cited by 525
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Knochenmuss, R., & Zenobi, R. (2003) · Chemical Reviews · doi:10.1021/cr0103773 · Cited by 520
Electronic properties, hydrogen bonding, stacking, and cation binding of DNA and RNA bases
?poner, J., Leszczynski, J., & Hobza, P. (2001) · Biopolymers · doi:10.1002/1097-0282(2001)61:1<3::aid-bip10048>3.0.co;2-4 · Cited by 431
Metadata
- Authors
- Hoyau, S., Norrman, K., McMahon, T. B., & Ohanessian, G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-09-01
- Volume
- 121
- Issue
- 38
- Pages
- 8864-8875
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2012652677
- Cited by
- 273
- References
- 14
- FWCI
- 16.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hoyau, S., Norrman, K., McMahon, T. B., & Ohanessian, G. (1999). A Quantitative Basis for a Scale of Na+ Affinities of Organic and Small Biological Molecules in the Gas Phase. Journal of the American Chemical Society. https://doi.org/10.1021/ja9841198
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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