Electrospray: From ions in solution to ions in the gas phase, what we know now

Some Factors in the Interpretation of Protein Denaturation

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Analytical Properties of the Nanoelectrospray Ion Source

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XX. On the equilibrium of liquid conducting masses charged with electricity

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Electrospray ion source: another variation on the free-jet theme

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Molecular Beams of Macroions

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Practical implications of some recent studies in electrospray ionization fundamentals

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Electrospray interface for liquid chromatographs and mass spectrometers.

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On the evaporation of small ions from charged droplets

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Studying noncovalent protein complexes by electrospray ionization mass spectrometry

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Electrospray and Taylor-Cone theory, Dole's beam of macromolecules at last?

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The current emitted by highly conducting Taylor cones

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Electrohydrodynamic spraying functioning modes: a critical review

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From ions in solution to ions in the gas phase - the mechanism of electrospray mass spectrometry

Kebarle, P., & Tang, L. (1993) · Analytical Chemistry · doi:10.1021/ac00070a001 · Cited by 784 · see citing works

A brief overview of the present status of the mechanisms involved in electrospray mass spectrometry

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Charge and fission of droplets in electrostatic sprays

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Field induced ion evaporation from liquid surfaces at atmospheric pressure

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The Fluid Dynamics of Taylor Cones

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Investigation of intact protein complexes by mass spectrometry

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Negative ion production with the electrospray ion source

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Electrospray ionization of large multiply charged species proceeds via Dole’s charged residue mechanism

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Effect of different solution flow rates on analyte ion signals in nano-ESI MS, or: when does ESI turn into nano-ESI?

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Dependence of ion intensity in electrospray mass spectrometry on the concentration of the analytes in the electrosprayed solution

Tang, L., & Kebarle, P. (1993) · Analytical Chemistry · doi:10.1021/ac00072a020 · Cited by 508 · see citing works

Quantitative determination of noncovalent binding interactions using soft ionization mass spectrometry

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Detection of noncovalent receptor-ligand complexes by mass spectrometry

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A Predictive Model for Matrix and Analyte Effects in Electrospray Ionization of Singly-Charged Ionic Analytes

Enke, C. G. (1997) · Analytical Chemistry · doi:10.1021/ac970095w · Cited by 423 · see citing works

The stability of a horizontal fluid interface in a vertical electric field

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Nanoelectrospray—More than just a minimized-flow electrospray ionization source

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Protein Structure in Vacuo: Gas-Phase Conformations of BPTI and Cytochrome c

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The Electrohydrodynamic Atomization of Liquids

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Mechanism of electrospray mass spectrometry. Electrospray as an electrolysis cell

Blades, A. T., Ikonomou, M. G., & Kebarle, P. (1991) · Analytical Chemistry · doi:10.1021/ac00019a009 · Cited by 365 · see citing works

Relating Electrospray Ionization Response to Nonpolar Character of Small Peptides

Cech, N. B., & Enke, C. G. (2000) · Analytical Chemistry · doi:10.1021/ac9914869 · Cited by 342 · see citing works

Carbohydrate Molecular Weight Profiling, Sequence, Linkage, and Branching Data: ES-MS and CID

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Estimates of Protein Surface Areas in Solution by Electrospray Ionization Mass Spectrometry

Kaltashov, I. A., & Mohimen, A. (2005) · Analytical Chemistry · doi:10.1021/ac050511+ · Cited by 321 · see citing works

On the Equilibrium of Liquid Conducting Masses charged with Electricity

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A Quantitative Basis for a Scale of Na+ Affinities of Organic and Small Biological Molecules in the Gas Phase

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Electrified droplet fission and the Rayleigh limit

Taflin, D. C., Ward, T. L., & Davis, E. J. (1989) · Langmuir · doi:10.1021/la00086a016 · Cited by 269 · see citing works

Droplet Evaporation and Discharge Dynamics in Electrospray Ionization

SMITH, J. N. M., Flagan, R. C., & Beauchamp, J. L. (2002) · The Journal of Physical Chemistry A · doi:10.1021/jp025723e · Cited by 253 · see citing works

An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory

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Electrospray mass spectrometry of poly(ethylene glycols) with molecular weights up to five million

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Pulses in Negative Point-to-Plane Corona

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Changes in bulk solution pH caused by the inherent controlled-current electrolytic process of an electrospray ion source

Berkel, G. J. V., Zhou, F., & Aronson, J. T. (1997) · International Journal of Mass Spectrometry and Ion Processes · doi:10.1016/s0168-1176(96)04476-x · Cited by 201 · see citing works

Reactions of Gaseous Molecule Ions with Gaseous Molecules. IV. Experimental Method and Results

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Experiments on the kinetics of field evaporation of small ions from droplets

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Features of the ESI mechanism that affect the observation of multiply charged noncovalent protein complexes and the determination of the association constant by the titration method

Peschke, M., Verkerk, U. H., & Kebarle, P. (2004) · Journal of the American Society for Mass Spectrometry · doi:10.1016/j.jasms.2004.05.005 · Cited by 184 · see citing works

Direct measurement of ion evaporation kinetics from electrified liquid surfaces

Gamero-Castaño, M., & de la Mora, J. F. (2000) · The Journal of Chemical Physics · doi:10.1063/1.481857 · Cited by 175 · see citing works

Method for Distinguishing Specific from Nonspecific Protein−Ligand Complexes in Nanoelectrospray Ionization Mass Spectrometry

Sun, J., Kitova, E. N., Wang, W., & Klassen, J. S. (2006) · Analytical Chemistry · doi:10.1021/ac0522005 · Cited by 160 · see citing works

FROM IONS IN SOLUTION TO IONS IN THE GAS PHASE

Kebarle, P., & Tang, L. (1993) · Analytical Chemistry · doi:10.1021/ac00070a715 · Cited by 157 · see citing works

Simple means to alleviate sensitivity loss by trifluoroacetic acid (TFA) mobile phases in the hydrophilic interaction chromatography–electrospray tandem mass spectrometric (HILIC–ESI/MS/MS) bioanalysis of basic compounds

SHOU, W., & NAIDONG, W. (2005) · Journal of Chromatography B · doi:10.1016/j.jchromb.2005.01.011 · Cited by 136 · see citing works

Electrospray mass spectrometry of methanol and water solutions suppression of electric discharge with SF6 gas

Ikonomou, M. G., Blades, A. T., & Kebarle, P. (1991) · Journal of the American Society for Mass Spectrometry · doi:10.1016/1044-0305(91)80038-9 · Cited by 134 · see citing works

Shrinking droplets in electrospray ionization and their influence on chemical equilibria

Wortmann, A., Kistler-Momotova, A., Zenobi, R., et al. (2006) · Journal of the American Society for Mass Spectrometry · doi:10.1016/j.jasms.2006.10.010 · Cited by 131 · see citing works

Flexing the Electrified Meniscus: The Birth of a Jet in Electrosprays

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Reaction Enthalpies for M+L = M+ + L, Where M+ = Na+ and K+ and L = Acetamide, N-Methylacetamide, N,N-Dimethylacetamide, Glycine, and Glycylglycine, from Determinations of the Collision-Induced Dissociation Thresholds

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Stability limit of charged drops

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Generation of Monodisperse Water Droplets from Electrosprays in a Corona-Assisted Cone-Jet Mode

Tang, K., & Gomez, A. (1995) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1995.1464 · Cited by 126 · see citing works

An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions

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Study of Homogeneously Catalyzed Ziegler–Natta Polymerization of Ethene by ESI‐MS

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Observation and implications of high mass-to-charge ratio ions from electrospray ionization mass spectrometry

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Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometric characterization of high molecular mass Starburst™ dendrimers

Pasa-Tolic, L., Anderson, G., Smith, R. D., Brothers, H. M., Spindler, R., & Tomalia, D. A. (1997) · International Journal of Mass Spectrometry and Ion Processes · doi:10.1016/s0168-1176(97)00161-4 · Cited by 113 · see citing works

Recipes for use of EHD spraying in cone-jet mode and notes on corona discharge effects

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Solvated Ion Evaporation from Charged Water Nanodroplets

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Ion-Ion and ion-molecule reactions at the surface of proteins produced by nanospray. Information on the number of acidic residues and control of the number of ionized acidic and basic residues

Verkerk, U. H., & Kebarle, P. (2005) · Journal of the American Society for Mass Spectrometry · doi:10.1016/j.jasms.2005.03.018 · Cited by 105 · see citing works

Method for Stabilizing Protein−Ligand Complexes in Nanoelectrospray Ionization Mass Spectrometry

Sun, J., Kitova, E. N., & Klassen, J. S. (2006) · Analytical Chemistry · doi:10.1021/ac061109d · Cited by 94 · see citing works

Effect of Affinity for Droplet Surfaces on the Fraction of Analyte Molecules Charged during Electrospray Droplet Fission

Cech, N. B., & Enke, C. G. (2001) · Analytical Chemistry · doi:10.1021/ac001267j · Cited by 94 · see citing works

Binding energies and stabilities of potassium ion complexes from studies of the gas phase ion equilibriums K+ + M = K+M

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Charge Carrier Field Emission Determines the Number of Charges on Native State Proteins in Electrospray Ionization

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Mass spectrometric determination of association constants of adenylate kinase with two noncovalent inhibitors

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Negative ion electrospray mass spectrometry of nucleotides: ionization from water solution with SF6 discharge suppression

Wampler, F. M., Blades, A. T., & Kebarle, P. (1993) · Journal of the American Society for Mass Spectrometry · doi:10.1016/1044-0305(93)85050-8 · Cited by 77 · see citing works

Protein Charge-State Distributions in Electrospray-Ionization Mass Spectrometry Do Not Appear To Be Limited by the Surface Tension of the Solvent

Šamalíková, M., & Grandori, R. (2003) · Journal of the American Chemical Society · doi:10.1021/ja037000u · Cited by 73 · see citing works

Evaporation and Discharge Dynamics of Highly Charged Droplets of Heptane, Octane, andp-Xylene Generated by Electrospray Ionization

Grimm, R. L., & Beauchamp, J. L. (2002) · Analytical Chemistry · doi:10.1021/ac025889b · Cited by 67 · see citing works

Testing the role of solvent surface tension in protein ionization by electrospray

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On the conformation‐dependent neutralization theory and charging of individual proteins and their non‐covalent complexes in the gas phase

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Glycine on a Wet Pyrite Surface at Extreme Conditions

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New Methods for the Study of Biomolecular Complexes

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On the stability limit of charged droplets

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Characterization of the anthocyanins ofCatharanthus roseus (L.) G. Donin vivo andin vitro by electrospray ionization ion trap mass spectrometry

Piovan, A., Filippini, R., & Favretto, D. (1998) · Rapid Communications in Mass Spectrometry · doi:10.1002/(sici)1097-0231(19980415)12:7 · Cited by 45 · see citing works

Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry

di Lena, F., Quintanilla, E., & Chen, P. (2005) · Chemical Communications · doi:10.1039/b511997a · Cited by 36 · see citing works

Bioactive Recognition Sites May Not Be Energetically Preferred in Protein−Carbohydrate Complexes in the Gas Phase

Wang, W., Kitova, E. N., & Klassen, J. S. (2003) · Journal of the American Chemical Society · doi:10.1021/ja036998q · Cited by 34 · see citing works

Mass Spectrometric Study of the Conversion of Rhenium Diolates to Metallaoxetanes and Carbenes. Coordination Number, Polar, and Steric Effects

Zhang, X., Chen, X., & Chen, P. (2004) · Organometallics · doi:10.1021/om049737d · Cited by 29 · see citing works

Measurement of Noncovalent Complexes with High m/z by Electrospray Time-of-Flight Mass Spectrometry

Chernushevich, I. V., Ens, W., & Standing, K. G. (1998) · Springer eBooks · doi:10.1007/978-94-015-9046-4_8 · Cited by 17 · see citing works

Nanospray ‘taxation’ and how to avoid it

Chernushevich, I. V., Bahr, U., & Karas, M. (2004) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.1649 · Cited by 17 · see citing works

Native Mass Spectrometry: What is in the Name?

Leney, A. C., & Heck, A. J. R. (2017) · Journal of the American Society for Mass Spectrometry · doi:10.1007/s13361-016-1545-3 · Cited by 602 · see citing works

High-Resolution Native Mass Spectrometry

Tamara, S., den Boer, M. A., & Heck, A. J. R. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00212 · Cited by 511 · see citing works

Recent advances on ionic liquid uses in separation techniques

Berthod, A., Ruiz-Ángel, M. J., & Carda-Broch, S. (2018) · Journal of Chromatography A · doi:10.1016/j.chroma.2017.09.044 · Cited by 293 · see citing works

Target-oriented analysis of gaseous, liquid and solid chemical systems by mass spectrometry, nuclear magnetic resonance spectroscopy and electron microscopy

Kachala, V. V., Khemchyan, L. L., Kashin, A. S., Orlov, N. V., Grachev, A. A., Zalesskiy, S. S., & Ananikov, V. P. (2013) · Russian Chemical Reviews · doi:10.1070/rc2013v082n07abeh004413 · Cited by 262 · see citing works

Addressing a Common Misconception: Ammonium Acetate as Neutral pH “Buffer” for Native Electrospray Mass Spectrometry

Konermann, L. (2017) · Journal of the American Society for Mass Spectrometry · doi:10.1007/s13361-017-1739-3 · Cited by 243 · see citing works

Accelerated Hantzsch electrospray synthesis with temporal control of reaction intermediates

Bain, R. M., Pulliam, C. J., & Cooks, R. G. (2015) · Chemical Science · doi:10.1039/c4sc02436b · Cited by 230 · see citing works

Recent trends of capillary electrophoresis‐mass spectrometry in proteomics research

Gomes, F. P., & Yates, J. R. (2019) · Mass Spectrometry Reviews · doi:10.1002/mas.21599 · Cited by 112 · see citing works

Effects of Ammonium Bicarbonate on the Electrospray Mass Spectra of Proteins: Evidence for Bubble-Induced Unfolding

Hedges, J. B., Vahidi, S., Yue, X., & Konermann, L. (2013) · Analytical Chemistry · doi:10.1021/ac401020s · Cited by 109 · see citing works

From QCEIMS to QCxMS: A Tool to Routinely Calculate CID Mass Spectra Using Molecular Dynamics

Koopman, J., & Grimme, S. (2021) · Journal of the American Society for Mass Spectrometry · doi:10.1021/jasms.1c00098 · Cited by 80 · see citing works

Effect of an Electrospray-Generated Ionomer Morphology on Polymer Electrolyte Fuel Cell Performance

Cho, S., Tamoto, K., & Uchida, M. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c02337 · Cited by 24 · see citing works

Suppression of Protein Structural Perturbations in Native Electrospray Ionization during the Final Evaporation Stages Revealed by Molecular Dynamics Simulations

Luan, M., Hou, Z., & Huang, G. (2021) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.1c09130 · Cited by 11 · see citing works

Electro-kinetic assisted electrospray ionization for enhanced complex sample analysis

Zhang, Z., He, M., Liu, L., et al. (2016) · Talanta · doi:10.1016/j.talanta.2016.11.029 · Cited by 11 · see citing works

Pneumatically assisted electrospray-ion mobility spectrometry for quantitative analysis of intact proteins

Arabzadeh, N., & Khayamian, T. (2012) · Talanta · doi:10.1016/j.talanta.2012.05.015 · Cited by 7 · see citing works

Achieving Augmented Limits of Detection for Peptides with Hydrophobic Alkyl Tags

Frahm, J. L., Bori, I. D., Comins, D. L., et al. (2007) · Analytical Chemistry · doi:10.1021/ac070558q · Cited by 47 · see citing works

Analytical Characterization of the Electrospray Ion Source in the Nanoflow Regime

Marginean, I., Kelly, R., Prior, D. C., Lamarche, B. L., Tang, K., & Smith, R. D. (2008) · Analytical Chemistry · doi:10.1021/ac800683s · Cited by 96 · see citing works