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Interaction of Curved and Flat Molecular Surfaces. The Structures of Crystalline Compounds Composed of Fullerene (C60, C60O, C70, and C120O) and Metal Octaethylporphyrin Units
Abstract
Solutions of C 60, C 60 O, or C 70 and metal complexes of octaethylporphyrin (OEPH 2 ) yield crystals that contain both the fullerene and the porphyrin. The structures of C 60 ·2Co II (OEP)·CHCl 3, C 60 ·2Zn II (OEP)·CHCl 3, and C 60 O·2Co II (OEP)·CHCl 3 are isomorphous and contain an ordered C 60 cage surrounded by two M II (OEP) units. Although there is no covalent bond between the fullerene and porphyrin components, the separation between these units is shorter than normal van der Waals contact. Crystals of C 70 ·Co II (OEP)·C 6 H 6 ·CHCl 3, C 70 ·Ni II (OEP)·C 6 H 6 ·CHCl 3, and C 70 ·Cu II (OEP)·C 6 H 6 ·CHCl 3 are also isomorphous with an ordered fullerene, but have only one porphyrin/fullerene contact. Crystalline C 60 ·ClFe III (OEP)·CHCl 3 lacks the close face-to-face porphyrin/porphyrin contact that is common to all of the other structures reported here but retains the intimate contact between the porphyrin and the fullerene. In (C 120 O)·Co II (OEP)·0.6C 6 H 6 ·0.4CHCl 3 the fullerene dimer is enclosed by two Co II (OEP) moieties. Unfortunately disorder in the fullerene portion obscures details of the geometry of the bridging region between the fullerenes.
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Cited by
Popov, A. A., Yang, S., & Dunsch, L. (2013) · Chemical Reviews · doi:10.1021/cr300297r · Cited by 1,256
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Selective Supramolecular Porphyrin/Fullerene Interactions1
Boyd, P. D. W., Hodgson, M. C., Rickard, C. E. F., Oliver, A. G., Chaker, L., Brothers, P. J., Bolskar, R. D., Tham, F. S., & Reed, C. A. (1999) · Journal of the American Chemical Society · doi:10.1021/ja992165h · Cited by 358
Umeyama, T., Takamatsu, T., Tezuka, N., Matano, Y., Araki, Y., Wada, T., Yoshikawa, O., Sagawa, T., Yoshikawa, S., & Imahori, H. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp902001z · Cited by 119
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Luechai, A., Gasiorowski, J., Petsom, A., Neugebauer, H., Sariciftci, N. S., & Thamyongkit, P. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm33840h · Cited by 30
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Metadata
- Authors
- Olmstead, M. M., Costa, D. A., Maitra, K., Noll, B. C., Phillips, S. L., Van Calcar, P. M., & Balch, A. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-07-20
- Volume
- 121
- Issue
- 30
- Pages
- 7090-7097
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2048508129
- Cited by
- 371
- References
- 0
- FWCI
- 12.28
- Type
- journal article
- Language
- en
- Open access
- closed
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