The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
pH-Dependent Hydrogen and Water Binding Energies on Platinum Surfaces as Directly Probed through Surface-Enhanced Infrared Absorption Spectroscopy
Abstract
The origins of the pH-dependent kinetics of hydrogen evolution and oxidation reactions on Pt surfaces are unsolved dilemmas that have lasted for over half a century. In this study, surface-enhanced infrared absorption spectroscopy is applied to directly monitor the vibrational behaviors of adsorbed hydrogen atoms and interfacial water molecules on Pt surfaces in a wide pH window from 1.1 to 12.9. For the first time, we successfully measure the pH-dependent changes of hydrogen and water binding strength according to their vibrational wavenumbers, which are both monotonously weakened as the solution pH increases. Their changes are the net results of altered electrochemical interface environments and are important contributions to the pH-dependent hydrogen reaction kinetics. Our results add significant new insights into the role of interfacial environments on electrocatalysis.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes
Sheng, W., Gasteiger, H. A., & Shao-Horn, Y. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3483106 · Cited by 1,829
Crabtree, G. W., Dresselhaus, M. S., & Buchanan, M. V. (2004) · Physics Today · doi:10.1063/1.1878333 · Cited by 1,610
Sheng, W., Zhuang, Z., Gao, M., Zheng, J., Chen, J. G., & Yan, Y. (2015) · Nature Communications · doi:10.1038/ncomms6848 · Cited by 1,136
Cited by
Li, P., Jiang, Y., Hu, Y., Men, Y., Liu, Y., Cai, W., & Chen, S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00846-8 · Cited by 852
Hu, Q., Gao, K., Wang, X., Zheng, H., Cao, J., Mi, L., Huo, Q., Yang, H., Liu, J., & He, C. (2022) · Nature Communications · doi:10.1038/s41467-022-31660-2 · Cited by 744
The Sabatier Principle in Electrocatalysis: Basics, Limitations, and Extensions
Ooka, H., Huang, J., & Exner, K. S. (2021) · Frontiers in Energy Research · doi:10.3389/fenrg.2021.654460 · Cited by 600
Chen, X., Wang, X.-T., Le, J.-B., Li, S.-M., Wang, X., Zhang, Y.-J., Radjenovic, P., Zhao, Y., Wang, Y.-H., Lin, X.-M., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-41030-1 · Cited by 600
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X., Yan, Z., Potsi, G., Selhorst, R., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 544
Metadata
- Authors
- Zhu, S., Qin, X., Yao, Y., & Shao, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-04-19
- Volume
- 142
- Issue
- 19
- Pages
- 8748-8754
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3016764069
- Cited by
- 368
- References
- 4
- FWCI
- 6.12
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: pH-Dependent Hydrogen and Water Binding Energies on Platinum Surfaces as Directly Probed through Surface-Enhanced Infrared Absorption Spectroscopy. https://app.cochat.ai/papers/10.1021/jacs.0c01104
- The paper
- Zhu, S., Qin, X., Yao, Y., & Shao, M. (2020). pH-Dependent Hydrogen and Water Binding Energies on Platinum Surfaces as Directly Probed through Surface-Enhanced Infrared Absorption Spectroscopy. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c01104
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
