The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Identification of Cu(100)/Cu(111) Interfaces as Superior Active Sites for CO Dimerization During CO2 Electroreduction
Abstract
The electrosynthesis of valuable multicarbon chemicals using carbon dioxide (CO 2 ) as a feedstock has substantially progressed recently but still faces considerable challenges. A major difficulty lines in the sluggish kinetics of forming carbon–carbon (C–C) bonds, especially in neutral media. We report here that oxide-derived copper crystals enclosed by six {100} and eight {111} facets can reduce CO 2 to multicarbon products with a high Faradaic efficiency of 74.9 ± 1.7% at a commercially relevant current density of 300 mA cm –2 in 1 M KHCO 3 (pH ∼ 8.4). By combining the experimental and computational studies, we uncovered that Cu(100)/Cu(111) interfaces offer a favorable local electronic structure that enhances *CO adsorption and lowers C–C coupling activation energy barriers, performing superior to Cu(100) and Cu(111) surfaces, respectively. On this catalyst, no obvious degradation was observed at 300 mA cm –2 over 50 h of continuous operation.
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Cites
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
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Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Domino electroreduction of CO2 to methanol on a molecular catalyst
Wu, Y., Jiang, Z., Lu, X., Liang, Y., & Wang, H. (2019) · Nature · doi:10.1038/s41586-019-1760-8 · Cited by 1,194
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
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Cited by
Chang, B., Pang, H., Raziq, F., Wang, S., Huang, K.-W., Ye, J., & Zhang, H. (2023) · Energy & Environmental Science · doi:10.1039/d3ee00964e · Cited by 458
Engineering Cu(I)/Cu(0) interfaces for efficient ethanol production from CO2 electroreduction
Cai, R., Sun, M., Yang, F., Ju, M., Chen, Y., Gu, M. D., Huang, B., & Yang, S. (2024) · Chem · doi:10.1016/j.chempr.2023.08.027 · Cited by 142
Metadata
- Authors
- Wu, Z.-Z., Zhang, X.-L., Niu, Z.-Z., Gao, F.-Y., Yang, P.-P., Chi, L.-P., Shi, L., Wei, W.-S., Liu, R., Chen, Z., Hu, S., Zheng, X., & Gao, M.-R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-12-28
- Volume
- 144
- Issue
- 1
- Pages
- 259-269
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W4200061927
- Cited by
- 471
- References
- 9
- FWCI
- 11.98
- Type
- journal article
- Language
- en
- Open access
- closed
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