The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction
Abstract
Single clusters have attracted extensive research interest in the field of catalysis. However, achieving a highly uniform dispersion of a single-cluster catalyst is challenging. In this work, for the first time, we present a versatile strategy for uniformly dispersed polyoxometalates (POMs) in covalent organic frameworks (COFs) through confining POM cluster into the regular nanopores of COF by a covalent linkage. These COF-POM composites combine the properties of light absorption, electron transfer, and suitable catalytic active sites; as a result, they exhibit outstanding catalytic activity in artificial photosynthesis: that is, CO 2 photoreduction with H 2 O as the electron donor. Among them, TCOF-MnMo 6 achieved the highest CO yield (37.25 μmol g –1 h –1 with ca. 100% selectivity) in a gas–solid reaction system. Furthermore, a mechanism study based on density functional theory (DFT) calculations demonstrated that the photoinduced electron transfer (PET) process occurs from the COF to the POM, and then CO 2 reduction and H 2 O oxidation occur on the POM and COF, respectively. This work developed a method for a uniform dispersion of POM single clusters into a COF, which also shows the potential of using COF-POM functional materials in the field of photocatalysis.
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Cites
Single-atom catalysis of CO oxidation using Pt1/FeOx
Qiao, B., Wang, A., Yang, X., Allard, L. F., Jiang, Z., Cui, Y., Liu, J., Li, J., & Zhang, T. (2011) · Nature Chemistry · doi:10.1038/nchem.1095 · Cited by 7,526
Self-citationMetal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
White, J. L., Baruch, M. F., Pander, J. E., Hu, Y., Fortmeyer, I. C., Park, J. E., Zhang, T., Liao, K., Gu, J., Yan, Y., et al. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00370 · Cited by 1,673
Covalent organic frameworks for separation applications
Wang, Z., Zhang, S., Chen, Y., Zhang, Z., & Ma, S. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00827f · Cited by 1,470
Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries
Lu, Y., & Chen, W. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15325d · Cited by 1,152
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Advanced Electrocatalysts with Single-Metal-Atom Active Sites
Wang, Y., Su, H., He, Y., Li, L., Zhu, S., Shen, H., Xie, P., Fu, X., Zhou, G., Feng, C., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00594 · Cited by 1,005
Engineering polyoxometalates with emergent properties
Miras, H. N., Yan, J., Long, D.-L., & Cronin, L. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35190k · Cited by 969
Low-dimensional catalysts for hydrogen evolution and CO2 reduction
Voiry, D., Shin, H. S., Loh, K. P., & Chhowalla, M. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-017-0105 · Cited by 848
Zhong, W., Sa, R., Li, L., He, Y., Li, L., Bi, J., Zhuang, Z., Yu, Y., & Zou, Z. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02997 · Cited by 769
Cited by
Li, Q., Jiao, Y., Tang, Y., Zhou, J., Wu, B., Jiang, B., & Fu, H. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c05234 · Cited by 339
Liu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Metadata
- Authors
- Lu, M., Zhang, M., Liu, J., Yu, T.-Y., Chang, J.-N., Shang, L.-J., Li, S.-L., & Lan, Y.-Q.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2022-01-20
- Volume
- 144
- Issue
- 4
- Pages
- 1861-1871
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W4206687824
- Cited by
- 477
- References
- 46
- FWCI
- 28.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lu, M., Zhang, M., Liu, J., Yu, T.-Y., Chang, J.-N., Shang, L.-J., Li, S.-L., & Lan, Y.-Q. (2022). Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.1c11987
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