The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate
Abstract
The use of a bulky bipyridine ligand, 6,6'-dimesityl-2,2'-bipyridine (mesbpy), to enable the reduction of carbon dioxide by a Ru-based molecular electrocatalyst is reported. Under catalytic conditions, this compound exhibits turnover frequencies of 320 s(-1) and 95% Faradaic efficiency for the production of CO and H2O from CO2 in the presence of Brønsted acids [corrected]. Mechanistic electrochemical and spectroelectrochemical studies, supplemented by the direct synthesis of relevant intermediates, indicate that this behavior is the result of the cooperative redox response of the bipyridine ligand and Ru metal center at negative potentials, as well as the inhibition of Ru-Ru bond formation through steric interactions.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Cited by
Molecular polypyridine-based metal complexes as catalysts for the reduction of CO2
Elgrishi, N., Chambers, M. B., Wang, X., & Fontecave, M. (2017) · Chemical Society Reviews · doi:10.1039/c5cs00391a · Cited by 555
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Kuramochi, Y., Ishitani, O., & Ishida, H. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.023 · Cited by 325
Li, K., Li, Y., Wang, Y., Ge, J., Liu, C., & Xing, W. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00402a · Cited by 282
Metadata
- Authors
- Machan, C. W., Sampson, M. D., & Kubiak, C. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-29
- Volume
- 137
- Issue
- 26
- Pages
- 8564-8571
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2414777232
- Cited by
- 160
- References
- 2
- FWCI
- 5.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Machan, C. W., Sampson, M. D., & Kubiak, C. P. (2015). A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b03913
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
