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White-Light-Emitting Lanthanide Metallogels with Tunable Luminescence and Reversible Stimuli-Responsive Properties
Abstract
We have developed model light-emitting metallogels functionalized with lanthanide metal-ligand coordination complexes via a terpyridyl-end-capped four-arm poly(ethylene glycol) polymer. The optical properties of these highly luminescent polymer networks are readily modulated over a wide spectrum, including white-light emission, simply by tuning of the lanthanide metal ion stoichiometry. Furthermore, the dynamic nature of the Ln-N coordination bonding leads to a broad variety of reversible stimuli-responsive properties (mechano-, vapo-, thermo-, and chemochromism) of both sol-gel systems and solid thin films. The versatile functional performance combined with the ease of assembly suggests that this lanthanide coordination polymer design approach offers a robust pathway for future engineering of multi-stimuli-responsive polymer materials.
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Metadata
- Authors
- Chen, P., Li, Q., Grindy, S., & Holten-Andersen, N.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-31
- Volume
- 137
- Issue
- 36
- Pages
- 11590-11593
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2255373556
- Cited by
- 447
- References
- 48
- FWCI
- 17.99
- Type
- journal article
- Language
- en
- Open access
- closed
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