The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement
Abstract
The widespread implementation of high-energy-density lithium metal batteries has long been fettered by lithium dendrite-related failure. Here we report a new strategy to address the issue of dendrite growth by a polyimide-coating layer with vertical nanoscale channels of high aspect ratio. Smooth, granular lithium metal was deposited on the modified electrode instead of typical filamentary growths. In a comparison with the bare planar electrode, the modified electrode achieved greatly enhanced Coulombic efficiency and longer cycle life. Homogeneous Li + flux distribution above the modified electrode from the nanochannel confinement can account for a uniform Li nucleation and a nondendrite growth. We also demonstrated that the polyimide coating with microscale pores loses the confinement effects and fails to suppress lithium dendrites. This strategy of spatially defined lithium growth in vertical-aligned nanochannels provides a novel approach and a significant step toward stabilizing Li metal anodes.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Issues and challenges facing rechargeable lithium batteries
Tarascon, J.-M., & Armand, M. (2001) · Nature · doi:10.1038/35104644 · Cited by 21,130
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
High-performance lithium battery anodes using silicon nanowires
Chan, C. K., Peng, H., Liu, G., McIlwrath, K., Zhang, X. F., Huggins, R. A., & Cui, Y. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2007.411 · Cited by 6,683
Self-citationA lithium superionic conductor
Kamaya, N., Homma, K., Yamakawa, Y., Hirayama, M., Kanno, R., Yonemura, M., Kamiyama, T., Kato, Y., Hama, S., Kawamoto, K., et al. (2011) · Nature Materials · doi:10.1038/nmat3066 · Cited by 4,978
Lithium metal anodes for rechargeable batteries
Xu, W., Wang, J., Ding, F., Chen, X., Nasybulin, E., Zhang, Y., & Zhang, J.-G. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee40795k · Cited by 4,704
Nanocomposite polymer electrolytes for lithium batteries
Croce, F., Appetecchi, G. B., Persi, L., & Scrosati, B. (1998) · Nature · doi:10.1038/28818 · Cited by 3,205
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth
Yan, K., Lu, Z., Lee, H.-W., Xiong, F., Hsu, P.-C., Li, Y., Zhao, J., Chu, S., & Cui, Y. (2016) · Nature Energy · doi:10.1038/nenergy.2016.10 · Cited by 2,116
Self-citationDendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
Ding, F., Xu, W., Graff, G. L., Zhang, J., Sushko, M. L., Chen, X., Shao, Y., Engelhard, M. H., Nie, Z., Xiao, J., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja312241y · Cited by 2,107
Nanostructured sulfur cathodes
Yang, Y., Zheng, G., & Cui, Y. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35256g · Cited by 1,947
Self-citationLin, D., Liu, Y., Liang, Z., Lee, H.-W., Sun, J., Wang, H., Yan, K., Xie, J., & Cui, Y. (2016) · Nature Nanotechnology · doi:10.1038/nnano.2016.32 · Cited by 1,798
Self-citationDesign principles for electrolytes and interfaces for stable lithium-metal batteries
Tikekar, M. D., Choudhury, S., Tu, Z., & Archer, L. A. (2016) · Nature Energy · doi:10.1038/nenergy.2016.114 · Cited by 1,765
Interconnected hollow carbon nanospheres for stable lithium metal anodes
Zheng, G., Lee, S. W., Liang, Z., Lee, H.-W., Yan, K., Yao, H., Wang, H., Li, W., Chu, S., & Cui, Y. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.152 · Cited by 1,764
Self-citationPromises and challenges of nanomaterials for lithium-based rechargeable batteries
Sun, Y., Liu, N., & Cui, Y. (2016) · Nature Energy · doi:10.1038/nenergy.2016.71 · Cited by 1,703
Self-citationUllmann's Encyclopedia of Industrial Chemistry.
Speight, J. G. (1999) · Petroleum Science and Technology · doi:10.1080/10916469908949727 · Cited by 1,654
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
Lu, Y., Tu, Z., & Archer, L. A. (2014) · Nature Materials · doi:10.1038/nmat4041 · Cited by 1,592
Transition of lithium growth mechanisms in liquid electrolytes
Bai, P., Li, J., Brushett, F. R., & Bazant, M. Z. (2016) · Energy & Environmental Science · doi:10.1039/c6ee01674j · Cited by 1,591
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
Li, W., Yao, H., Yan, K., Zheng, G., Liang, Z., Chiang, Y.-M., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8436 · Cited by 1,540
Self-citationElectrochemical aspects of the generation of ramified metallic electrodeposits
Chazalviel, J.-N. (1990) · Physical Review A · doi:10.1103/physreva.42.7355 · Cited by 1,402
Ceramic and polymeric solid electrolytes for lithium-ion batteries
Fergus, J. W. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.01.076 · Cited by 1,172
Metallic anodes for next generation secondary batteries
Kim, H., Jeong, G., Kim, Y.-U., Kim, J.-H., Park, C.-M., & Sohn, H.-J. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60177c · Cited by 1,010
Ionic Conductivity Enhancement of Polymer Electrolytes with Ceramic Nanowire Fillers
Liu, W., Liu, N., Sun, J., Hsu, P.-C., Li, Y., Lee, H.-W., & Cui, Y. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b00600 · Cited by 1,001
Self-citationHigh Capacity Li Ion Battery Anodes Using Ge Nanowires
Chan, C. K., Zhang, X. F., & Cui, Y. (2008) · Nano Letters · doi:10.1021/nl0727157 · Cited by 911
Self-citationLithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode
Liu, Y., Lin, D., Liang, Z., Zhao, J., Yan, K., & Cui, Y. (2016) · Nature Communications · doi:10.1038/ncomms10992 · Cited by 902
Self-citationChemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes
Yun, Q., He, Y., Lv, W., Zhao, Y., Li, B., Kang, F., & Yang, Q. (2016) · Advanced Materials · doi:10.1002/adma.201601409 · Cited by 870
Derrien, G., Hassoun, J., Panero, S., & Scrosati, B. (2007) · Advanced Materials · doi:10.1002/adma.200700748 · Cited by 868
Liang, Z., Lin, D., Zhao, J., Lu, Z., Liu, Y., Liu, C., Lu, Y., Wang, H., Yan, K., Tao, X., et al. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1518188113 · Cited by 846
Self-citationIn situ NMR observation of the formation of metallic lithium microstructures in lithium batteries
Bhattacharyya, R., Key, B., Chen, H., Best, A. S., Hollenkamp, A. F., & Grey, C. P. (2010) · Nature Materials · doi:10.1038/nmat2764 · Cited by 813
Yan, K., Lee, H.-W., Gao, T., Zheng, G., Yao, H., Wang, H., Lu, Z., Zhou, Y., Liang, Z., Liu, Z., et al. (2014) · Nano Letters · doi:10.1021/nl503125u · Cited by 742
Self-citation7Li MRI of Li batteries reveals location of microstructural lithium
Chandrashekar, S., Trease, N. M., Chang, H. J., Du, L.-S., Grey, C. P., & Jerschow, A. (2012) · Nature Materials · doi:10.1038/nmat3246 · Cited by 499
A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte
Yamaki, J.-I., Tobishima, S.-I., Hayashi, K., Saito, K., Nemoto, Y., & Arakawa, M. (1998) · Journal of Power Sources · doi:10.1016/s0378-7753(98)00067-6 · Cited by 483
Onset of dendritic growth in lithium/polymer cells
Rosso, M., Gobron, T., Brissot, C., Chazalviel, J.-N., & Lascaud, S. (2001) · Journal of Power Sources · doi:10.1016/s0378-7753(01)00734-0 · Cited by 404
Effect of vinylene carbonate as additive to electrolyte for lithium metal anode
Ota, H., Shima, K., Ue, M., & Yamaki, J.-I. (2004) · Electrochimica Acta · doi:10.1016/j.electacta.2003.09.010 · Cited by 382
Chang, H. J., Ilott, A. J., Trease, N. M., Mohammadi, M., Jerschow, A., & Grey, C. P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09385 · Cited by 285
Nanoporous Polymer‐Ceramic Composite Electrolytes for Lithium Metal Batteries
Tu, Z., Kambe, Y., Lu, Y., & Archer, L. A. (2014) · Advanced Energy Materials · doi:10.1002/aenm.201300654 · Cited by 243
Stability Analysis of Electrodeposition across a Structured Electrolyte with Immobilized Anions
Tikekar, M. D., Archer, L. A., & Koch, D. L. (2014) · Journal of The Electrochemical Society · doi:10.1149/2.085405jes · Cited by 226
Electrochemical Deposition of Very Smooth Lithium Using Nonaqueous Electrolytes Containing HF
Kanamura, K., Shiraishi, S., & Takehara, Z. (1996) · Journal of The Electrochemical Society · doi:10.1149/1.1836979 · Cited by 220
Manipulating Crystal Growth and Polymorphism by Confinement in Nanoscale Crystallization Chambers
Hamilton, B. D., Ha, J.-M., Hillmyer, M. A., & Ward, M. D. (2012) · Accounts of Chemical Research · doi:10.1021/ar200147v · Cited by 207
Kim, J.-S., Kim, D. W., Jung, H. T., & Choi, J. W. (2015) · Chemistry of Materials · doi:10.1021/cm503447u · Cited by 199
Over-limiting Current and Control of Dendritic Growth by Surface Conduction in Nanopores
Han, J., Khoo, E., Bai, P., & Bazant, M. Z. (2014) · Scientific Reports · doi:10.1038/srep07056 · Cited by 122
Over-limiting Current and Control of Dendritic Growth by Surface Conduction in Nanopores
Han, J., Khoo, E., Bai, P., & Bazant, M. Z. (2014) · Cited by 107
Cycling behaviour of Li/Li4Ti5O12 cells studied by electrochemical impedance spectroscopy
Schweikert, N., Hahn, H., & Indris, S. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp01889a · Cited by 81
Kang, S. J., Mori, T., Suk, J., Kim, D. W., Kang, Y., Wilcke, W. W., & Kim, H. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta01314j · Cited by 49
The Race of Nanowires: Morphological Instabilities and a Control Strategy
Shin, S., Al-Housseiny, T. T., Kim, B. S., Cho, H. H., & Stone, H. A. (2014) · Nano Letters · doi:10.1021/nl501324t · Cited by 48
Cited by
Advancing Lithium Metal Batteries
Liu, B., Zhang, J.-G., & Xu, W. (2018) · Joule · doi:10.1016/j.joule.2018.03.008 · Cited by 1,647
Sodium Metal Anodes: Emerging Solutions to Dendrite Growth
Lee, B., Paek, E., Mitlin, D., & Lee, S. W. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00642 · Cited by 940
3D Porous Cu Current Collector/Li‐Metal Composite Anode for Stable Lithium‐Metal Batteries
Li, Q., Zhu, S., & Lu, Y. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201606422 · Cited by 854
Artificial Interphases for Highly Stable Lithium Metal Anode
Xu, R., Cheng, X.-B., Yan, C., Zhang, X.-Q., Xiao, Y., Zhao, C.-Z., Huang, J.-Q., & Zhang, Q. (2019) · Matter · doi:10.1016/j.matt.2019.05.016 · Cited by 721
Wood-based nanotechnologies toward sustainability
Jiang, F., Li, T., Li, Y., Zhang, Y., Gong, A., Dai, J., Hitz, E., Luo, W., & Hu, L. (2018) · Advanced Materials · doi:10.1002/adma.201703453 · Cited by 599
Metadata
- Authors
- Liu, W., Lin, D., Pei, A., & Cui, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-11-16
- Volume
- 138
- Issue
- 47
- Pages
- 15443-15450
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2546433560
- Cited by
- 455
- References
- 43
- FWCI
- 26.07
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
