The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Influence of Surface Adsorption on the Oxygen Evolution Reaction on IrO2(110)
Abstract
A catalyst functions by stabilizing reaction intermediates, usually through surface adsorption. In the oxygen evolution reaction (OER), surface oxygen adsorption plays an indispensable role in the electrocatalysis. The relationship between the adsorption energetics and OER kinetics, however, has not yet been experimentally measured. Herein we report an experimental relationship between the adsorption of surface oxygen and the kinetics of the OER on IrO 2 (110) epitaxially grown on a TiO 2 (110) single crystal. The high quality of the IrO 2 film grown using molecular-beam epitaxy affords the ability to extract the surface oxygen adsorption and its impact on the OER. By examining a series of electrolytes, we find that the adsorption energy changes linearly with pH, which we attribute to the electrified interfacial water. We support this hypothesis by showing that an electrolyte salt modification can lead to an adsorption energy shift. The dependence of the adsorption energy on pH has implications for the OER kinetics, but it is not the only factor; the dependence of the OER electrocatalysis on pH stipulates two OER mechanisms, one operating in acidic solution and another operating in alkaline solution. Our work points to the subtle adsorption–kinetics relationship in the OER and highlights the importance of the interfacial electrified interaction in electrocatalyst design.
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Cites
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Cited by
Duan, Y., Yu, Z., Hu, S., Zheng, X., Zhang, C., Ding, H., Hu, B., Fu, Q., Yu, Z., Zheng, X., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909939 · Cited by 625
A General Method to Probe Oxygen Evolution Intermediates at Operating Conditions
Tao, H. B., Xu, Y., Huang, X., Chen, J., Pei, L., Zhang, J., Chen, J. G., & Liu, B. (2019) · Joule · doi:10.1016/j.joule.2019.03.012 · Cited by 587
Ye, S., Shi, Z., Feng, J., Tong, Y., & Li, G. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712549 · Cited by 561
Kuznetsov, D. A., Han, B., Yu, Y., Rao, R. R., Hwang, J., Román-Leshkov, Y., & Shao-Horn, Y. (2018) · Joule · doi:10.1016/j.joule.2017.11.014 · Cited by 452
Towards membrane-electrode assembly systems for CO2 reduction: a modeling study
Weng, L.-C., Bell, A. T., & Weber, A. Z. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00909d · Cited by 452
Metadata
- Authors
- Kuo, D.-Y., Kawasaki, J. K., Nelson, J. N., Kloppenburg, J., Hautier, G., Shen, K. M., Schlom, D. G., & Suntivich, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-02-21
- Volume
- 139
- Issue
- 9
- Pages
- 3473-3479
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2586200100
- Cited by
- 370
- References
- 8
- FWCI
- 9.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kuo, D.-Y., Kawasaki, J. K., Nelson, J. N., Kloppenburg, J., Hautier, G., Shen, K. M., Schlom, D. G., & Suntivich, J. (2017). Influence of Surface Adsorption on the Oxygen Evolution Reaction on IrO2(110). Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b11932
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