The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Gold Nanoclusters Promote Electrocatalytic Water Oxidation at the Nanocluster/CoSe2 Interface
Abstract
Electrocatalytic water splitting to produce hydrogen comprises the hydrogen and oxygen evolution half reactions (HER and OER), with the latter as the bottleneck process. Thus, enhancing the OER performance and understanding the mechanism are critically important. Herein, we report a strategy for OER enhancement by utilizing gold nanoclusters to form cluster/CoSe 2 composites; the latter exhibit largely enhanced OER activity in alkaline solutions. The Au 25 /CoSe 2 composite affords a current density of 10 mA cm –2 at small overpotential of ∼0.43 V (cf. CoSe 2: ∼0.52 V). The ligand and gold cluster size can also tune the catalytic performance of the composites. Based upon XPS analysis and DFT simulations, we attribute the activity enhancement to electronic interactions between nanocluster and CoSe 2, which favors the formation of the important intermediate (OOH) as well as the desorption of oxygen molecules over Au n /CoSe 2 composites in the process of water oxidation. Such an atomic level understanding may provide some guidelines for design of OER catalysts.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
Low Overpotential in Vacancy-Rich Ultrathin CoSe2 Nanosheets for Water Oxidation
Liu, Y., Cheng, H., Lyu, M., Fan, S., Liu, Q., Zhang, W., Zhi, Y., Wang, C., Xiao, C., Wei, S., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5085157 · Cited by 1,094
Han, L., Yu, X., & Lou, X. W. (. (2016) · Advanced Materials · doi:10.1002/adma.201506315 · Cited by 633
Cited by
Support and Interface Effects in Water‐Splitting Electrocatalysts
Zhang, J., Zhang, Q., & Feng, X. (2019) · Advanced Materials · doi:10.1002/adma.201808167 · Cited by 916
Tang, T., Jiang, W.-J., Niu, S., Liu, N., Luo, H., Chen, Y.-Y., Jin, S.-F., Gao, F., Wan, L.-J., & Hu, J.-S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03507 · Cited by 880
Wan, X., Wu, H. B., Guan, B. Y., Luan, D., & Lou, X. W. (. (2020) · Advanced Materials · doi:10.1002/adma.201901349 · Cited by 410
Tan, L., Yu, J., Wang, C., Wang, H., Liu, X., Gao, H., Xin, L., Liu, D., Hou, W., & Zhan, T. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202200951 · Cited by 345
Wang, L., Li, Z., Wang, K., Dai, Q., Lei, C., Yang, B., Zhang, Q., Lei, L., Leung, M. K. H., & Hou, Y. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104850 · Cited by 196
Metadata
- Authors
- Zhao, S., Jin, R., Abroshan, H., Zeng, C., Zhang, H., House, S. D., Gottlieb, E., Kim, H. J., Yang, J. C., & Jin, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-01-17
- Volume
- 139
- Issue
- 3
- Pages
- 1077-1080
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2568267126
- Cited by
- 349
- References
- 4
- FWCI
- 11.46
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Gold Nanoclusters Promote Electrocatalytic Water Oxidation at the Nanocluster/CoSe2 Interface. https://app.cochat.ai/papers/10.1021/jacs.6b12529
- The paper
- Zhao, S., Jin, R., Abroshan, H., Zeng, C., Zhang, H., House, S. D., Gottlieb, E., Kim, H. J., Yang, J. C., & Jin, R. (2017). Gold Nanoclusters Promote Electrocatalytic Water Oxidation at the Nanocluster/CoSe2 Interface. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b12529
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
